Chemistry Heterocyclic Building Blocks Pyridines 1,1'-diphenyl-[4,4'-bipyridine]-1,1'-diium
Ambeed provide 7 derivatives of 1,1'-diphenyl-[4,4'-bipyridine]-1,1'-diium.
These compounds have the same murcko framework: 1,1'-diphenyl-[4,4'-bipyridine]-1,1'-diium.
Substitution Reactions: DPB can undergo nucleophilic aromatic substitution reactions. For example, if you react it with a strong nucleophile, it can replace one or both of the phenyl groups with the nucleophile. The reaction may vary depending on the conditions and the nature of the nucleophile.
Redox Reactions: DPB can participate in redox reactions as the two nitrogen atoms in the bipyridine core can coordinate with metal ions, making it a potential ligand in transition metal complex chemistry.
Protonation/Deprotonation: DPB can be protonated or deprotonated depending on the pH of the solution. This can affect its reactivity and coordination abilities.
Coordination Chemistry: Due to its bipyridine core, DPB can coordinate with various metal ions to form coordination complexes. This can lead to the formation of new compounds with unique properties.
Electrochemical Reactions: DPB can be used in electrochemical studies, such as cyclic voltammetry, to investigate its redox behavior and study its interactions with metal ions.
Cross-Coupling Reactions: DPB can potentially be used in cross-coupling reactions, where it can act as a ligand or substrate to form new carbon-carbon or carbon-heteroatom bonds.
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1,1'-Bis(4-carboxyphenyl)-[4,4'-bipyridine]-1,1'-diium chloride
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1,1'-Bis(4-aminophenyl)-[4,4'-bipyridine]-1,1'-diium chloride
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4,4'-Bipyridinium, 1,1'-bis(4-iodophenyl)-, chloride (1:2)
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1,1'-Bis(4-cyanophenyl)-[4,4'-bipyridine]-1,1'-diium chloride
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1,1'-Bis(4-methoxyphenyl)-[4,4'-bipyridine]-1,1'-diium chloride
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1,1'-Diphenyl-[4,4'-bipyridine]-1,1'-diium chloride
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1,1'-Bis(4-bromophenyl)-[4,4'-bipyridine]-1,1'-diium chloride