Chemistry Heterocyclic Building Blocks Imidazoles 1,3-diphenyl-1H-imidazol-3-ium

1,3-diphenyl-1H-imidazol-3-ium

Ambeed provide 14 derivatives of 1,3-diphenyl-1H-imidazol-3-ium.

These compounds have the same murcko framework: 1,3-diphenyl-1H-imidazol-3-ium.

Nucleophilic Substitution: The imidazolium ring can undergo nucleophilic substitution reactions. Nucleophiles can attack the carbon atoms adjacent to the positively charged nitrogen atom, resulting in the displacement of one of the phenyl groups. Common nucleophiles include hydroxide ions (OH-), alkoxides (RO-), or amines.
Dehydrogenation: The compound can undergo dehydrogenation reactions, where the hydrogen atoms on the carbon atoms within the imidazolium ring are removed. This can be catalyzed by suitable oxidizing agents, resulting in the formation of a diene or even an aromatic imidazole ring.
Reductive Amination: If you have a suitable reducing agent and an amine, you can perform reductive amination to convert the imidazolium into a secondary or tertiary amine. For example, reaction with ammonia or primary amines can lead to the formation of corresponding secondary or tertiary amines.
Alkylation: The imidazolium ring can be alkylated using alkyl halides or alkylating agents. This can result in the addition of alkyl groups to the imidazolium nitrogen or carbon atoms.
Halogenation: The compound can undergo halogenation reactions where halogens (e.g., Cl2, Br2) can add to the double bonds within the imidazolium ring, resulting in the formation of halogenated derivatives.
Reduction: If you want to remove the positive charge from the imidazolium ring, you can perform a reduction reaction using reducing agents like sodium borohydride (NaBH4) or hydrogen gas H2 in the presence of a suitable catalyst.
Acid-Base Reactions: Depending on the conditions and the nature of the surrounding environment, the imidazolium ion can undergo acid-base reactions with other compounds.

Further Reading:
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Conditions to empty

Framework+−

1,1'-diphenyl-4,4',5,5'-tetrahydro-1H,1'H-2,2'-biimidazole 1,2-dimethyl-1H-imidazole 1,3-diphenyl-1H-imidazol-3-ium 1,3-diphenyl-4,5-dihydro-1H-imidazol-3-ium 1-(imidazo[1,2-a]pyridin-3-yl)ethan-1-one 1-(phenylsulfonyl)-1H-imidazole 1-benzyl-1H-imidazole 1-decyl-3-methyl-1H-imidazol-3-ium 1-ethyl-1H-imidazole 1-isopropyl-1H-imidazole 1-phenyl-1H-imidazole-4-carboxylic acid 1-trityl-1H-imidazole 1H-imidazo[4,5-b]pyridine 1H-imidazo[4,5-c]pyridine 1H-imidazol-2-amine 1H-imidazole-2-carboxylic acid 1H-imidazole-4-carbonitrile 1H-imidazole-4-carboxylic acid 2-(pyridin-2-yl)-1H-benzo[d]imidazole 2-bromo-1H-imidazole 2-bromoimidazo[1,2-a]pyridine 2-ethyl-1H-imidazole 2-methyl-1-phenyl-1H-imidazole 2-methylimidazo[1,2-a]pyridine 2-phenyl-1H-benzo[d]imidazole 2-phenyl-1H-imidazole 2-phenylimidazo[1,2-a]pyridine 2-propyl-1H-imidazole 3-bromoimidazo[1,2-a]pyrazine 3-bromoimidazo[1,2-a]pyridine 3-bromoimidazo[1,2-a]pyrimidine 3-iodoimidazo[1,2-a]pyridine 3-methylimidazo[1,2-a]pyridine 4,5,6,7-tetrahydro-3H-imidazo[4,5-c]pyridine 4-(1H-imidazol-1-yl)benzaldehyde 4-bromo-1-phenyl-1H-imidazole 4-methyl-1-phenyl-1H-imidazole 4-methyl-1H-imidazole 4-phenyl-1H-imidazole 5,6,7,8-tetrahydroimidazo[1,2-a]pyrazine 5,6,7,8-tetrahydroimidazo[1,2-a]pyridine 5,6,7,8-tetrahydroimidazo[1,5-a]pyrazine 5-benzyl-1H-imidazole 5-bromoimidazo[1,2-a]pyridine 5-chloro-1H-imidazole 5-fluoro-1H-benzo[d]imidazole 5-iodo-1H-imidazole 5-methylimidazo[1,2-a]pyridine 5-phenyl-1H-imidazole 6,7-dihydro-5H-pyrrolo[1,2-a]imidazole 6-bromoimidazo[1,2-a]pyrazine 6-bromoimidazo[1,2-a]pyridine 6-bromoimidazo[1,2-a]pyrimidine 6-chloroimidazo[1,2-a]pyridine 6-chloroimidazo[1,2-b]pyridazine 7-methylimidazo[1,2-a]pyridine 8-bromoimidazo[1,2-a]pyrazine 8-bromoimidazo[1,2-a]pyridine 8-chloroimidazo[1,2-a]pyrazine 8-chloroimidazo[1,2-a]pyridine 8-fluoroimidazo[1,2-a]pyridine 8-methylimidazo[1,2-a]pyridine ethyl 1H-imidazole-2-carboxylate ethyl 2-(imidazo[1,2-a]pyridin-3-yl)acetate ethyl imidazo[1,2-a]pyridine-2-carboxylate ethyl imidazo[1,2-a]pyridine-3-carboxylate imidazo[1,2-a]pyridin-3-amine imidazo[1,2-a]pyridin-8-amine imidazo[1,2-a]pyridin-8-ol imidazo[1,2-a]pyridine-2-carbaldehyde imidazo[1,2-a]pyridine-2-carboxylic acid imidazo[1,2-a]pyridine-3-carbaldehyde imidazo[1,2-a]pyridine-3-carboxylic acid imidazo[1,2-a]pyridine-7-carboxylic acid imidazo[1,2-a]pyridine-8-carboxylic acid imidazo[1,2-a]pyrimidine-3-carboxylic acid imidazo[1,2-c]pyrimidine imidazo[1,5-a]pyrazine imidazo[2,1-b]thiazole methyl 1H-imidazole-2-carboxylate methyl 1H-imidazole-5-carboxylate methyl imidazo[1,2-a]pyridine-8-carboxylate tert-butyl 1H-imidazole-1-carboxylate

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aminoimidazole-carboxylate benzyl-imidazole benzyl-methyl-imidazole biimidazole bromo-imidazole bromo-imidazopyridine bromo-methyl-imidazole bromoimidazo bromoimidazole carboxylate chloro-imidazopyridine chloroimidazo dibromoimidazo dichloroimidazo dihydroimidazo dimethyl-imidazol dimethylimidazo dimethylimidazolium dioxaborolane-imidazole ethyl-imidazole fluoroimidazo hydroxy-imidazopyridine imidazol-amine imidazol-ethanol imidazol-hydrochloride imidazol-ium imidazol-methanamine imidazol-methanol imidazol-nitrile imidazol-pyridine imidazole-carboxylate imidazole-carboxylic acid imidazolyl-pyrimidine imidazopyrazine imidazopyridazine imidazopyridin-amine imidazopyridin-one imidazopyridine imidazopyridine-carbonitrile imidazopyridine-carboxylate imidazopyridine-carboxylic acid imidazopyrimidine imidazoquinoline imidazothiazole iodoimidazo iodomethyl-imidazole isopropyl-imidazole methoxyimidazo methyl-imidazopyridine methyl-nitro-imidazole methylimidazo methylimidazole methylimidazolium nitro-imidazole-carboxylate nitroimidazole phenylimidazo phenylimidazole piperidin-imidazolyl pyrroloimidazole tetrahydroimidazo thienoimidazol trifluoromethyl-imidazo trifluoromethyl-imidazole trifluoromethyl-imidazopyridine

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Aliphatic Heterocycles Aromatic Heterocycles Dioxolanes Indazoles Other Aliphatic Heterocycles Other Aromatic Heterocycles Piperazines Piperidines Pyrazines Pyrazoles Pyridines Pyrimidines Pyrrolidines Spiroes Tetrahydropyrans Thiophenes Thiophenols Triazines Triazoles

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Alcohols Aldehydes Aliphatic Chain Hydrocarbons Aliphatic Cyclic Hydrocarbons Alkenyls Alkynyls Amides Amines Aryls Benzyl bromides Benzyl Chlorides Bromides Carboxylic Acids Chiral Building Blocks Chlorides Esters Ethers Fluorinated Building Blocks Hydrazines Iodides Ketones Nitriles Nitroes Organoboron Oximes Phenols Phosphoruses Sulfamides Sulfides Sulfonates Sulfones Sulfonic Acids Sulfonyl Chlorides Sulfoxides Thioureas Trifluoromethyls Ureas

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