Chemistry Heterocyclic Building Blocks Pyridines 2,2':6',2''-terpyridine
Ambeed provide 15 derivatives of 2,2':6',2''-terpyridine.
These compounds have the same murcko framework: 2,2':6',2''-terpyridine.
Metal Complex Formation: One of the primary uses of terpyridine is its ability to form stable coordination complexes with metal ions, particularly transition metals. The resulting complexes can have interesting and potentially useful properties. For example, terpyridine complexes of ruthenium and other metals are known for their luminescent properties.
Catalysis: Terpyridine-based ligands can be used in catalytic reactions, especially in various metal-catalyzed reactions. The terpyridine ligand can influence the reactivity of the metal center and direct the outcome of the catalytic process.
Photophysical Properties: Terpyridine-based complexes are often studied for their photophysical properties, including luminescence. These complexes can be used in the development of materials for OLEDs (organic light-emitting diodes), sensors, and other optoelectronic devices.
Electron Transfer Reactions: Terpyridine complexes can be involved in electron transfer reactions. The metal center can facilitate electron transfer processes, making these complexes of interest in various redox chemistry studies.
Ligand Exchange Reactions: Terpyridine complexes can undergo ligand exchange reactions, where one or more of the pyridine groups are replaced with other ligands. These reactions are essential for modifying the properties of the complexes and tailoring them for specific applications.
Catenanes and Rotaxanes: Terpyridine-based ligands have been used in the synthesis of mechanically interlocked molecules, such as catenanes and rotaxanes. These molecules have unique topological structures and have been explored for their potential applications in nanotechnology and materials science.
Crystal Engineering: Terpyridine complexes are often used in crystal engineering to create solid-state structures with specific properties. This can be important in the development of materials with desired properties.
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[2,2':6',2''-Terpyridine]-4'-carboxylic acid
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[2,2':6',2''-Terpyridine]-4,4',4''-tricarboxylic acid
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5,5''-Bis(bromomethyl)-2,2':6',2''-terpyridine
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4,4',4''-Tri-tert-butyl-2,2':6',2''-terpyridine
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Ethyl [2,2':6',2''-terpyridine]-4'-carboxylate
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[2,2':6',2''-Terpyridine]-4'-carbaldehyde
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Trimethyl [2,2':6',2''-terpyridine]-4,4',4''-tricarboxylate