Chemistry Organometallic Reagents Organoboron 2,7-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9H-fluorene
Hydrolysis: The boron-oxygen bonds in the boron-containing substituents can be hydrolyzed under acidic or basic conditions, leading to the formation of boronic acids or boronates, respectively.
Substitution Reactions: The boron substituents can undergo substitution reactions with various electrophiles, such as halogens (e.g., bromination or chlorination) or nucleophiles (e.g., boronation with boron trifluoride or boronates).
Oxidation Reactions: Boron compounds can be oxidized to form boronic acids or other boron-containing species using oxidizing agents like hydrogen peroxide.
Reduction Reactions: Boron compounds can be reduced to their corresponding boronates or boranes using reducing agents like sodium borohydride.
Coordination Chemistry: Boron-containing compounds can participate in coordination chemistry, forming complexes with various metals or other ligands.
Cross-Coupling Reactions: Apart from Suzuki-Miyaura coupling, other cross-coupling reactions like Stille coupling or Heck reaction can be performed using boron-containing compounds.
Nucleophilic Addition: The boron substituents can act as electrophiles in nucleophilic addition reactions, leading to the formation of new bonds.
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2,2'-(9,9-Didecyl-9H-fluorene-2,7-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
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2,2'-(9,9-Dihexyl-9H-fluorene-2,7-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
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2,2'-(9,9-Dioctyl-9H-fluorene-2,7-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
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2,2'-(9,9-Didodecyl-9H-fluorene-2,7-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
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2,2'-(9,9-Bis(6-bromohexyl)-9H-fluorene-2,7-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
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2,2'-(9,9-Dimethyl-9H-fluorene-2,7-diyl)bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolane)
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2,7-Bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9H-fluorene