Chemistry Heterocyclic Building Blocks Pyridines 4,7-diphenyl-1,10-phenanthroline
Ambeed provide 5 derivatives of 4,7-diphenyl-1,10-phenanthroline.
These compounds have the same murcko framework: 4,7-diphenyl-1,10-phenanthroline.
Halogenation: 4,7-diphenyl-1,10-phenanthroline can undergo halogenation reactions. For example, you can chlorinate or brominate the aromatic rings, replacing hydrogen atoms with chlorine or bromine.
Metal Complexation: This compound can coordinate with various metal ions due to its bidentate chelating properties. It can form stable complexes with metals like copper, iron, and ruthenium. These complexes have applications in various fields, including catalysis and luminescence studies.
Oxidation Reactions: The aromatic rings in 4,7-diphenyl-1,10-phenanthroline can be oxidized by strong oxidizing agents, leading to the formation of various oxidation products.
Substitution Reactions: The aromatic rings can undergo electrophilic aromatic substitution reactions. For instance, you can perform nitration or sulfonation to introduce nitro or sulfo groups onto the phenyl rings.
Cross-Coupling Reactions: 4,7-diphenyl-1,10-phenanthroline can participate in palladium-catalyzed cross-coupling reactions, where it can be functionalized with various organic groups through reactions like Suzuki coupling, Stille coupling, or Heck reaction.
Hydrogenation: The aromatic rings can undergo catalytic hydrogenation reactions under suitable conditions, converting double bonds into saturated single bonds.
Photochemical Reactions: Depending on the substituents and reaction conditions, this compound may undergo photochemical reactions, such as photodimerization or photoisomerization.
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2,9-Dichloro-4,7-diphenyl-1,10-phenanthroline
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Sodium 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline-3,8-disulfonate hydrate
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4,7-Bis(4-bromophenyl)-1,10-phenanthroline
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2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline