Chemistry Organic Building Blocks Benzene Compounds 5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthalene
Ambeed provide 6 derivatives of 5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthalene.
These compounds have the same murcko framework: 5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthalene.
Aromatic substitution: If there are suitable functional groups on the molecule (e.g., halogens, alkyl groups), it can undergo electrophilic aromatic substitution reactions, such as halogenation, nitration, sulfonation, etc.
Hydrogenation: Octahydro-1,1'-binaphthalene can undergo catalytic hydrogenation reactions to reduce double bonds. This typically requires the presence of a catalyst such as platinum or palladium.
Oxidation: It can be oxidized under certain conditions to form functional groups like ketones or alcohols. Common oxidizing agents like potassium permanganate (KMnO4) or chromic acid (H2CrO4) might be used.
Alkylation and Acylation: If suitable reaction conditions and reagents are present, it can undergo alkylation and acylation reactions to introduce alkyl or acyl groups.
Grignard Reaction: If there is a suitable electrophilic site, 5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthalene can react with Grignard reagents to form new carbon-carbon bonds.
Diels-Alder Reaction: Under specific conditions and with appropriate dienophiles, it might undergo Diels-Alder reactions to form cyclic compounds.
Reduction: It can be reduced to form saturated or partially saturated derivatives.
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(S)-3,3'-Dibromo-5,5',6,6',7,7',8,8'-octahydro-[1,1'-binaphthalene]-2,2'-diol
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(R)-3,3'-Dibromo-5,5',6,6',7,7',8,8'-octahydro-[1,1'-binaphthalene]-2,2'-diol
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5,5',6,6',7,7',8,8'-Octahydro-[1,1'-binaphthalene]-2,2'-diol
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(1S)-5,5',6,6',7,7',8,8'-Octahydro-[1,1'-Binaphthalene]-2,2'-diamine
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(R)-5,5',6,6',7,7',8,8'-Octahydro[1,1'-binaphthalene]-2,2'-diol
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(S)-5,5,6,6,7,7,8,8-Octahydro-1,1-bi-2-naphthol