Catalysts Ligands Organocatalysts

Organocatalysts

Organocatalysts are a class of catalysts that are composed of organic molecules and are used to accelerate chemical reactions. Unlike traditional catalysts, which are typically metal-based, organocatalysts rely on the catalytic properties of carbon-based compounds. These catalysts are typically small organic molecules that can facilitate reactions such as asymmetric synthesis, polymerization, and carbon- carbon bond formation. Organocatalysis offers several advantages, including high selectivity, mild reaction conditions, and sustainability, as many organocatalysts are derived from renewable resources and are less toxic than their metal counterparts. One of the key applications of organocatalysts is in the synthesis of chiral molecules, which are important in the pharmaceutical industry for the production of drugs with specific stereochemical configurations. Organocatalysts can also be used in the production of fine chemicals, agrochemicals, and polymers. In recent years, the development of organocatalysts has gained significant attention due to their ability to replace more hazardous or expensive catalysts, leading to more sustainable and cost-effective chemical processes. Furthermore, organocatalysis has become an essential tool in green chemistry, as many reactions involving organocatalysts can proceed under environmentally friendly conditions, such as in the absence of solvents or under mild temperatures. Some well-known classes of organocatalysts include amines, thioureas, and phosphines, each of which has unique catalytic properties that make them suitable for different types of reactions. Overall, organocatalysts represent a powerful and versatile tool in modern chemical synthesis, offering both practical and environmental benefits.
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Chiral Hydrogen-Bonding Organocatalysts (79) Chiral Phosphoric Acids (161) Cinchona Alkaloids (32) MacMillan Imidazolidinone Organocatalysts (15) NHTf (59) Proline-Based Organocatalysts (51) Other Organocatalysts (45)
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(S)-2-Amino-N-benzyl-N,3,3-trimethylbutanamide

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A469839947383-62-298%

(S)-2-Amino-N-benzyl-N,3,3-trimethylbutanamide

$39.00/100mg

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(S)-4-Hydroxy-2,6-bis(2,4,6-tricyclohexylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

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A11478791309446-14-798% 99%ee

(S)-4-Hydroxy-2,6-bis(2,4,6-tricyclohexylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

$59.00/100mg

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1,1,1-Trifluoro-N-[(11bR)-4-oxido-2,6-diphenyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]methanesulfonamide

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A10052661010799-98-097%

1,1,1-Trifluoro-N-[(11bR)-4-oxido-2,6-diphenyldinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl]methanesulfonamide

$123.00/50mg

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1-((1R,2R)-2-Aminocyclohexyl)-3-(3,5-bis(trifluoromethyl)phenyl)thiourea

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A180917860994-58-798%

1-((1R,2R)-2-Aminocyclohexyl)-3-(3,5-bis(trifluoromethyl)phenyl)thiourea

$110.00/100mg

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(11bR)-4-Hydroxy-2,6-di(naphthalen-2-yl)-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

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A682597922711-75-998%

(11bR)-4-Hydroxy-2,6-di(naphthalen-2-yl)-8,9,10,11,12,13,14,15-octahydrodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

$41.00/100mg

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(R)-((1S,2R,4S,5R)-5-ethylquinuclidin-2-yl)(6-methoxyquinolin-4-yl)methanamine trihydrochloride

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A981506931098-92-997%

(R)-((1S,2R,4S,5R)-5-ethylquinuclidin-2-yl)(6-methoxyquinolin-4-yl)methanamine trihydrochloride

$39.00/100mg

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(11BR)-2,6-bis(3,5-dichlorophenyl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

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A6620941191451-24-798%

(11BR)-2,6-bis(3,5-dichlorophenyl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

$158.00/100mg

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(11bR)-2,6-Di([1,1'-biphenyl]-4-yl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

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A1006141699006-54-797%

(11bR)-2,6-Di([1,1'-biphenyl]-4-yl)-4-hydroxydinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

$45.00/50mg

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H-D-β-Pro-OH

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A13387472580-54-295%

H-D-β-Pro-OH

$18.00/250mg

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1-(3,5-Bis(trifluoromethyl)phenyl)-3-((1S,2S)-2-(dimethylamino)cyclohexyl)thiourea

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A751788851477-20-898%

1-(3,5-Bis(trifluoromethyl)phenyl)-3-((1S,2S)-2-(dimethylamino)cyclohexyl)thiourea

$11.00/100mg

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(2R,4S)-tert-Butyl 4-hydroxy-2-(hydroxymethyl)pyrrolidine-1-carboxylate

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A69671877450-03-495%

(2R,4S)-tert-Butyl 4-hydroxy-2-(hydroxymethyl)pyrrolidine-1-carboxylate

$208.00/100mg

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(11bR)-N-(2,6-Di([1,1'-biphenyl]-4-yl)-4-oxidodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)-1,1,1-trifluoromethanesulfonamide

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A10061341071853-94-597%

(11bR)-N-(2,6-Di([1,1'-biphenyl]-4-yl)-4-oxidodinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)-1,1,1-trifluoromethanesulfonamide

$52.00/50mg

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(11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

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A759908791616-55-295%

(11bR)-4-Hydroxy-2,6-bis(triphenylsilyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

$48.00/100mg

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1-((1S,2S)-2-Aminocyclohexyl)-3-(3,5-bis(trifluoromethyl)phenyl)thiourea

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A2170101027476-96-597%

1-((1S,2S)-2-Aminocyclohexyl)-3-(3,5-bis(trifluoromethyl)phenyl)thiourea

$57.00/50mg

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(S)-3,3'-BIs(anthracenyl-9-yl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate

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A610024361342-52-198%

(S)-3,3'-BIs(anthracenyl-9-yl)-1,1'-binapthyl-2,2'-diyl hydrogenphosphate

$79.00/50mg

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(R)-Azetidine-2-carboxylic acid

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A1698437729-30-897%

(R)-Azetidine-2-carboxylic acid

$19.00/250mg

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(2s,5s)-(-)-2-tert-Butyl-3-methyl-5-benzyl-4-imidazolidinone

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A197618346440-54-897% 99%ee

(2s,5s)-(-)-2-tert-Butyl-3-methyl-5-benzyl-4-imidazolidinone

$36.00/100mg

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(S)-3-((3,5-Bis(trifluoromethyl)phenyl)amino)-4-((pyrrolidin-2-ylmethyl)amino)cyclobut-3-ene-1,2-dione

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A9060211356935-80-298%

(S)-3-((3,5-Bis(trifluoromethyl)phenyl)amino)-4-((pyrrolidin-2-ylmethyl)amino)cyclobut-3-ene-1,2-dione

$124.00/50mg

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3-[[3,5-Bis(trifluoromethyl)phenyl]amino]-4-[[(8α,9S)-10,11-dihydro-6'-methoxycinchonan-9-yl]amino]-3-cyclobutene-1,2-dione

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A9721541352957-59-598%

3-[[3,5-Bis(trifluoromethyl)phenyl]amino]-4-[[(8α,9S)-10,11-dihydro-6'-methoxycinchonan-9-yl]amino]-3-cyclobutene-1,2-dione

$133.00/100mg

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(11bR)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

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A623140791616-63-298% 99%ee

(11bR)-4-Hydroxy-2,6-bis(2,4,6-triisopropylphenyl)dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepine 4-oxide

$39.00/100mg

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