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[ CAS No. 107428-05-7 ] {[proInfo.proName]}

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Chemical Structure| 107428-05-7
Chemical Structure| 107428-05-7
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Product Details of [ 107428-05-7 ]

CAS No. :107428-05-7 MDL No. :
Formula : C13H16O4 Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W : 236.26 Pubchem ID :-
Synonyms :

Safety of [ 107428-05-7 ]

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Precautionary Statements: UN#:
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Application In Synthesis of [ 107428-05-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 107428-05-7 ]

[ 107428-05-7 ] Synthesis Path-Downstream   1~24

  • 1
  • [ 107428-05-7 ]
  • [ 16356-02-8 ]
  • 5,6-bis-methoxymethyl-4,7-dimethyl-indan-2,2-dicarboxylic acid dimethyl ester [ No CAS ]
YieldReaction ConditionsOperation in experiment
94% With 1,2-bis-(diphenylphosphino)ethane In benzene at 20℃; for 0.5h;
94% With 1,2-bis-(diphenylphosphino)ethane In benzene at 20℃; for 0.5h;
  • 2
  • [ 107428-05-7 ]
  • [ 1548-13-6 ]
  • dimethyl 1,4-dimethyl-3-oxo-2-(4-trifluoromethylphenyl)-5H-2,3,6,7-tetrahydrocyclopenta[c]pyridine-6,6-dicarboxylate [ No CAS ]
YieldReaction ConditionsOperation in experiment
84% With bis(1,5-cyclooctadiene)nickel (0); 1,3-bis(2,6-diisopropylphenyl)dihydroimidazol-2-ylidene In toluene at 80℃; for 0.5h;
72% With bis(1,5-cyclooctadiene)diiridium(I) dichloride; (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl In 1,2-Dichloropropane for 24h; Inert atmosphere; Reflux;
  • 3
  • [ 455-18-5 ]
  • [ 107428-05-7 ]
  • dimethyl 1,4-dimethyl-3-(4-(trifluoromethyl)phenyl)-5H-cyclopenta[c]pyridine-6,6(7H)-dicarboxylate [ No CAS ]
YieldReaction ConditionsOperation in experiment
98% With bis(1,5-cyclooctadiene)nickel (0); 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In toluene at 20℃; for 3h; Inert atmosphere;
94% With bis(1,5-cyclooctadiene)nickel (0); 1,3-bis(2,6-diisopropylphenyl)dihydroimidazol-2-ylidene In toluene at 20℃; for 2h;
  • 4
  • [ 52784-31-3 ]
  • [ 107428-05-7 ]
  • dimethyl 2,7-dimethyl-5-phenylbicyclo[6.3.0]undeca-1,7-dien-3-one-10,10-dicarboxylate [ No CAS ]
  • 5
  • [ 55756-24-6 ]
  • [ 107428-05-7 ]
  • 4,7-dimethyl-5-tridecafluorohexylindane-2,2-dicarboxylic acid dimethyl ester [ No CAS ]
YieldReaction ConditionsOperation in experiment
85% With (R)-(+)-2,2'-bis(diphenylphosphanyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl In 1,2-dichloro-ethane at 20℃; for 3h;
  • 6
  • [ 107428-05-7 ]
  • [ 1817-57-8 ]
  • 5-acetyl-4,7-dimethyl-6-phenylindan-2,2-dicarboxylic acid dimethyl ester [ No CAS ]
YieldReaction ConditionsOperation in experiment
99% With hydrogen In dichloromethane at 20℃; for 3h;
99% With bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; 2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl; hydrogen In dichloromethane at 20℃; for 3h; Inert atmosphere; optical yield given as %de;
  • 7
  • [ 107428-05-7 ]
  • [ 611-70-1 ]
  • 3-ethylidene-4-[1-(2-isobutyrylphenyl)ethylidene]cyclopentane-1,1-dicarboxylic acid dimethyl ester [ No CAS ]
YieldReaction ConditionsOperation in experiment
82% With hydrogen In dichloromethane at 20℃; for 3h;
  • 8
  • [ 107428-05-7 ]
  • [ 609-09-6 ]
  • 3-acetyl-4-(2,2-bisethoxycarbonyl-1-methylvinyl)cyclopent-3-ene-1,1-dicarboxylic acid dimethyl ester [ No CAS ]
  • 9
  • [ 52784-31-3 ]
  • [ 107428-05-7 ]
  • [ 880551-35-9 ]
  • 10
  • [ 56309-56-9 ]
  • [ 107428-05-7 ]
  • dimethyl (+)-2-(2-isopropylphenyl)-1,4-dimethyl-3-oxo-5H-2,3,6,7-tetrahydrocyclopenta[c]-pyridine-6,6-dicarboxylate [ No CAS ]
  • dimethyl (-)-2-(2-isopropylphenyl)-1,4-dimethyl-3-oxo-5H-2,3,6,7-tetrahydrocyclopenta[c]-pyridine-6,6-dicarboxylate [ No CAS ]
YieldReaction ConditionsOperation in experiment
With bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl In dichloromethane at 20℃; for 1h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;
With bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; 2,2′-bis(diphenylphosphanyl)-5,5′-6,6′-7,7′,8,8′-octahydro-1,1′-binaphthyl In dichloromethane at 20℃; for 1h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;
With bis(1,5-cyclooctadiene)diiridium(I) dichloride; (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl In benzene at 0℃; for 1h; Inert atmosphere; Reflux; optical yield given as %ee; enantioselective reaction;
4 % ee With chloro(1,5-cyclooctadiene)rhodium(I) dimer; C50H56O4P(1-)*Ag(1+); 1,4-di(diphenylphosphino)-butane In dichloromethane at 80℃; for 15h; Inert atmosphere; Overall yield = 75 %; Overall yield = 60 mg; enantioselective reaction;

  • 11
  • [ 872-36-6 ]
  • [ 107428-05-7 ]
  • [ 1131477-17-2 ]
  • 12
  • [ 13031-04-4 ]
  • [ 107428-05-7 ]
  • [ 1173788-18-5 ]
  • 13
  • [ 20201-24-5 ]
  • [ 107428-05-7 ]
  • [ 1173788-05-0 ]
YieldReaction ConditionsOperation in experiment
87% With bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; 2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl; hydrogen In dichloromethane at 20℃; for 3h; Inert atmosphere;
  • 14
  • [ 2247-91-8 ]
  • [ 107428-05-7 ]
  • [ 1173997-03-9 ]
YieldReaction ConditionsOperation in experiment
22% With bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; hydrogen; 2,2'-bis(diphenylphosphino)biphenyl In dichloromethane at 20℃; for 3h; Inert atmosphere;
  • 15
  • [ 107428-05-7 ]
  • [ 27584-70-9 ]
  • [ 1301254-61-4 ]
  • 16
  • [ 1530-88-7 ]
  • [ 107428-05-7 ]
  • [ 1323947-44-9 ]
YieldReaction ConditionsOperation in experiment
93% With bis(1,5-cyclooctadiene)nickel(0); 1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene In toluene at 20℃; for 0.5h; Inert atmosphere; regioselective reaction;
91% With 1,1'-bis-(diphenylphosphino)ferrocene; bis(1,5-cyclooctadiene)diiridium(I) dichloride In benzene for 24h; Inert atmosphere; Reflux;
90% With 2,6-bis(2,4,6-trimethylphenyliminomethyl)pyridine; iron(II) chloride; zinc In benzene at 70℃; for 6h; Inert atmosphere; regioselective reaction;
85% With 1,3-bis-(diphenylphosphino)propane; ferrous iodide; zinc In tetrahydrofuran at 20℃; for 24h; Inert atmosphere;
81% With tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) hexafluorophosphate at 20℃; for 0.25h; Sealed tube; Inert atmosphere;

  • 17
  • [ 1530-89-8 ]
  • [ 107428-05-7 ]
  • [ 1323947-52-9 ]
YieldReaction ConditionsOperation in experiment
99% With 1,1'-bis-(diphenylphosphino)ferrocene; bis(1,5-cyclooctadiene)diiridium(I) dichloride In benzene for 1h; Inert atmosphere; Reflux;
97% With bis(1,5-cyclooctadiene)nickel(0); 1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene In toluene at 20℃; for 0.5h; Inert atmosphere; regioselective reaction;
95% With 1,3-bis-(diphenylphosphino)propane; ferrous iodide; zinc In tetrahydrofuran at 20℃; for 24h; Inert atmosphere;
91% With tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) hexafluorophosphate at 20℃; for 0.0833333h; Sealed tube; Inert atmosphere;
67% With 2,6-bis(2,4,6-trimethylphenyliminomethyl)pyridine; iron(II) chloride; zinc In benzene at 70℃; for 5h; Inert atmosphere; regioselective reaction;

  • 18
  • [ 2451-91-4 ]
  • [ 107428-05-7 ]
  • [ 1323947-54-1 ]
YieldReaction ConditionsOperation in experiment
88% With bis(1,5-cyclooctadiene)nickel(0); 1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene In toluene at 20℃; for 0.5h; Inert atmosphere; regioselective reaction;
82% With 1,1'-bis-(diphenylphosphino)ferrocene; bis(1,5-cyclooctadiene)diiridium(I) dichloride In benzene for 1h; Inert atmosphere; Reflux;
With 1,3-bis-(diphenylphosphino)propane; ferrous iodide; zinc In tetrahydrofuran at 20℃; for 24h; Inert atmosphere;
  • 19
  • [ 56309-56-9 ]
  • [ 107428-05-7 ]
  • dimethyl (-)-2-(2-isopropylphenyl)-1,4-dimethyl-3-oxo-5H-2,3,6,7-tetrahydrocyclopenta[c]-pyridine-6,6-dicarboxylate [ No CAS ]
YieldReaction ConditionsOperation in experiment
51% With bis(1,5-cyclooctadiene)diiridium(I) dichloride; (R)-(+)-2,2'-bis(diphenylphosphanyl)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl In benzene at 0℃; for 1h; Inert atmosphere; Reflux; optical yield given as %ee; enantioselective reaction;
  • 20
  • [ 56309-56-9 ]
  • [ 107428-05-7 ]
  • [ 1450907-28-4 ]
YieldReaction ConditionsOperation in experiment
With silver tetrafluoroborate; chloro(1,5-cyclooctadiene)rhodium(I) dimer; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In dichloromethane at 20℃; for 18h; Inert atmosphere;
  • 21
  • [ 111-12-6 ]
  • [ 107428-05-7 ]
  • trimethyl 4,7-dimethyl-6-pentyl-1H-indene-2,2,5(3H)-tricarboxylate [ No CAS ]
YieldReaction ConditionsOperation in experiment
83% With bis(1,5-cyclooctadiene)diiridium(I) dichloride; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; In benzene; for 2h;Reflux; Inert atmosphere; General procedure: Representative procedure for the [222] cycloaddition of diyne 1a with alkynyl ester 4.Aflask was charged with [Ir(cod)Cl]2(7.0 mg, 0.01 mmol) and rac-BINAP (12.2 mg, 0.02 mmol). The flask was evacuated and filled with argon. To the flask were added benzene (5 mL) and methyl 2-undecynoate (4c) (444 mg, 2.3 mmol). Diyne1a(234 mg, 1.0 mmol) was added to the reaction mixture. The mixture was stirred under reflux for 2 h. The progress of the reaction was monitored by GLC. After the reaction was complete, the solvent was evaporated invacuo. Column chromatography of the residue gave 5ac(n-hexane/AcOEt 85:15, 378 mg, 0.87 mmol, 88% yield).
  • 22
  • [ 4891-38-7 ]
  • [ 107428-05-7 ]
  • trimethyl 4,7-dimethyl-6-phenyl-1H-indene-2,2,5(3H)-tricarboxylate [ No CAS ]
YieldReaction ConditionsOperation in experiment
76% With bis(1,5-cyclooctadiene)diiridium(I) dichloride; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl In benzene for 16h; Reflux; Inert atmosphere; 4.3. Reaction of diyne 1a with alkynyl ester 4 General procedure: Representative procedure for the [222] cycloaddition of diyne 1a with alkynyl ester 4.Aflask was charged with [Ir(cod)Cl]2(7.0 mg, 0.01 mmol) and rac-BINAP (12.2 mg, 0.02 mmol). The flask was evacuated and filled with argon. To the flask were added benzene (5 mL) and methyl 2-undecynoate (4c) (444 mg, 2.3 mmol). Diyne1a(234 mg, 1.0 mmol) was added to the reaction mixture. The mixture was stirred under reflux for 2 h. The progress of the reaction was monitored by GLC. After the reaction was complete, the solvent was evaporated invacuo. Column chromatography of the residue gave 5ac(n-hexane/AcOEt 85:15, 378 mg, 0.87 mmol, 88% yield).
  • 23
  • [ 36122-35-7 ]
  • [ 107428-05-7 ]
  • dimethyl 4,7-dimethyl-5-phenylindane-2,2-dicarboxylate [ No CAS ]
  • 24
  • [ 60710-39-6 ]
  • [ 107428-05-7 ]
  • dimethyl 4,4a,9-trimethyl-7-oxo-1,3,4a,7-tetrahydro-2H-cyclopenta[b]naphthalene-2,2-dicarboxylate [ No CAS ]
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