Alternatived Products of [ 108861-20-7 ]
Product Details of [ 108861-20-7 ]
CAS No. : | 108861-20-7 |
MDL No. : | MFCD02063876 |
Formula : |
C28H24F12N4P2
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Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
706.45
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Pubchem ID : | - |
Synonyms : |
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Safety of [ 108861-20-7 ]
Signal Word: | |
Class: | N/A |
Precautionary Statements: | |
UN#: | N/A |
Hazard Statements: | |
Packing Group: | N/A |
Application In Synthesis of [ 108861-20-7 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 108861-20-7 ]
- 1
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[ 623-24-5 ]
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[ 553-26-4 ]
-
[ 108861-20-7 ]
Yield | Reaction Conditions | Operation in experiment |
98% |
Stage #1: 1,4-bis(bromomethyl)benzene; 4,4'-bipyridine In acetonitrile
Stage #2: With ammonium hexafluorophosphate In water |
|
96% |
With ammonium hexafluorophosphate In chloroform; acetonitrile for 5h; Heating; |
|
45% |
Stage #1: 1,4-bis(bromomethyl)benzene; 4,4'-bipyridine In acetonitrile at 60℃; for 8h; Sealed tube;
Stage #2: With ammonium hexafluorophosphate In water |
|
|
With ammonium hexafluorophosphate In acetonitrile Heating; |
|
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Stage #1: 1,4-bis(bromomethyl)benzene; 4,4'-bipyridine In acetonitrile Reflux;
Stage #2: With ammonium hexafluorophosphate |
|
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Stage #1: 1,4-bis(bromomethyl)benzene; 4,4'-bipyridine In acetonitrile for 24h; Reflux;
Stage #2: With ammonium hexafluorophosphate In water |
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Reference:
[1]Anamimoghadam, Ommid; Cooper, James A.; Nguyen, Minh T.; Guo, Qing-Hui; Mosca, Lorenzo; Roy, Indranil; Sun, Junling; Stern, Charlotte L.; Redfern, Louis; Farha, Omar K.; Stoddart, J. Fraser
[Angewandte Chemie - International Edition, 2019, vol. 58, # 39, p. 13778 - 13783][Angew. Chem., 2019, vol. 131, p. 13916 - 13921,6]
[2]Gunter, Maxwell J.; Hockless, David C. R.; Johnston, Martin R.; Skelton, Brian W.; White, Allan H.
[Journal of the American Chemical Society, 1994, vol. 116, # 11, p. 4810 - 4823]
[3]Tang, Bo; Yang, Hong-Mei; Hu, Wen-Jing; Ma, Ming-Liang; Liu, Yahu A.; Li, Jiu-Sheng; Jiang, Biao; Wen, Ke
[European Journal of Organic Chemistry, 2014, vol. 2014, # 31, p. 6925 - 6934]
[4]Alvaro, Mercedes; Ferrer, Bele̿n; Forne̿s, Vicente; Garci̿a, Hermenegildo; Scaiano
[Journal of Physical Chemistry B, 2002, vol. 106, # 26, p. 6815 - 6820]
[5]Lu, Xiaoyong; Samanta, Soumen K.; Zavalij, Peter Y.; Isaacs, Lyle
[Angewandte Chemie - International Edition, 2018, vol. 57, # 27, p. 8073 - 8078][Angew. Chem., 2018, vol. 130, p. 8205 - 8210,6]
[6]Cheng, Lin; Zhang, Haiyang; Dong, Yunhong; Zhao, Yanxia; Yu, Yang; Cao, Liping
[Chemical Communications, 2019, vol. 55, # 16, p. 2372 - 2375]
- 2
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[ 34373-96-1 ]
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[ 108861-20-7 ]
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C44H36N4(4+)*4F6P(1-)
[ No CAS ]
- 3
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[ 17455-25-3 ]
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[ 108861-20-7 ]
-
[ 100094-00-6 ]
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C66H54N4(4+)*4F6P(1-)*C28H40O10
[ No CAS ]
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C66H54N4(4+)*4F6P(1-)*2C28H40O10
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
1: 28%
2: 4% |
Stage #1: [2,17]dibenzo-30-crown-10; 1,1-[1,4-phenylenebis(methylene)]bis-4,4'-pyridylpiridinium bis(hexafluorophosphate); 5′-(bromomethyl)-1,1′:3′,1″-terphenyl In dichloromethane; acetone; acetonitrile at 20℃; for 672h;
Stage #2: In dichloromethane at 20℃; for 0.5h;
Stage #3: With potassium hexafluorophosphate In acetonitrile |
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