Home Cart 0 Sign in  

[ CAS No. 13221-94-8 ] {[proInfo.proName]}

,{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]}
Chemical Structure| 13221-94-8
Chemical Structure| 13221-94-8
Structure of 13221-94-8 * Storage: {[proInfo.prStorage]}
Cart0 Add to My Favorites Add to My Favorites Bulk Inquiry Inquiry Add To Cart

Quality Control of [ 13221-94-8 ]

Related Doc. of [ 13221-94-8 ]

Alternatived Products of [ 13221-94-8 ]

Product Details of [ 13221-94-8 ]

CAS No. :13221-94-8 MDL No. :MFCD01846256
Formula : C9H16O2 Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W : 156.22 Pubchem ID :-
Synonyms :

Safety of [ 13221-94-8 ]

Signal Word: Class:N/A
Precautionary Statements: UN#:N/A
Hazard Statements: Packing Group:N/A

Application In Synthesis of [ 13221-94-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 13221-94-8 ]

[ 13221-94-8 ] Synthesis Path-Downstream   1~29

  • 1
  • [ 507-19-7 ]
  • cobalt(II) aceylacetonate [ No CAS ]
  • [ 13221-94-8 ]
  • 2
  • [ 558-17-8 ]
  • [ 123-54-6 ]
  • [ 13221-94-8 ]
YieldReaction ConditionsOperation in experiment
(i) aq. <nBu4N>F, THF, (ii) /BRN= 505950/, CHCl3; Multistep reaction;
  • 3
  • (<i>RS</i>)-3-((<i>SR</i>)-1-hydroxy-ethyl)-4,4-dimethyl-pentan-2-one [ No CAS ]
  • [ 13221-94-8 ]
YieldReaction ConditionsOperation in experiment
With manganese(IV) oxide In benzene
  • 4
  • [ 123-54-6 ]
  • [ 115-11-7 ]
  • [ 13221-94-8 ]
YieldReaction ConditionsOperation in experiment
With perchloric acid In nitromethane
  • 5
  • [ 123-54-6 ]
  • [ 75-65-0 ]
  • [ 13221-94-8 ]
YieldReaction ConditionsOperation in experiment
33% With sulfuric acid In dichloromethane at 23℃; for 16h;
11% With sulfuric acid In nitromethane Cooling;
With perchloric acid In nitromethane at 20℃;
  • 6
  • [ 13221-94-8 ]
  • [ 40898-19-9 ]
YieldReaction ConditionsOperation in experiment
Yield given. Multistep reaction;
  • 7
  • [ 13221-94-8 ]
  • (2RS,4RS)-3-t-butylpentane-2,4-diol [ No CAS ]
  • (2R,3r,4S)-3-t-butylpentane-2,4-diol [ No CAS ]
YieldReaction ConditionsOperation in experiment
With lithium aluminium tetrahydride In diethyl ether for 0.166667h; Heating; Yield given. Yields of byproduct given;
  • 8
  • cobalt(II) aceylacetonate [ No CAS ]
  • [ 558-17-8 ]
  • [ 13221-94-8 ]
YieldReaction ConditionsOperation in experiment
15% In chloroform at 100℃; for 4h;
  • 9
  • [ 123-54-6 ]
  • [ 75-65-0 ]
  • [ 39761-71-2 ]
  • [ 13221-94-8 ]
  • [ 85688-99-9 ]
  • [ 27656-49-1 ]
YieldReaction ConditionsOperation in experiment
1: 14 % Chromat. 2: 12 % Chromat. 3: 30 % Chromat. With perchloric acid In nitromethane for 100h; Further byproducts given;
  • 10
  • [ 75-65-0 ]
  • [ 39761-71-2 ]
  • [ 13221-94-8 ]
  • [ 85688-99-9 ]
  • [ 27656-49-1 ]
YieldReaction ConditionsOperation in experiment
1: 30 % Chromat. 2: 14 % Chromat. 3: 12 % Chromat. With perchloric acid; acetylacetone In nitromethane for 100h; Further byproducts given;
1: 12 % Chromat. 2: 2.5 % Chromat. 3: 69 % Chromat. With perchloric acid; acetylacetone In nitromethane for 6h; Further byproducts given;
YieldReaction ConditionsOperation in experiment
Enol-Gehalt: keiner bei Raumtemperatur;
Spaltung durch starke Saeuren ---> Acetylaceton u. tert. Butyl-Kation;
tert.-Alkylierung von Acetylaceton;
Cyclisierung/p-Toluolsulfonsaeure -> endo-7-Isopropyl-6,8-dioxa-bicyclo(3.2.1)octan;
Rk. mit 2,4-Dinitrophenylhydrazin -> syn-2-(2,4-Dinitro-phenyl-hydrazono)-3-tert.-butyl-pentanon-(4) und entspr. anti-Isomeres;
Rk. mit 4-Nitro-phenylhydrazin -> 3,5-Dimethyl-4-tert.-butyl-1-(4-nitro-phenyl)-pyrazol;
Rk. mit Hydrazin-hydrat -> 3,5-Dimethyl-4-tert.-butyl-pyrazol;
keine Rk. mit 1,2-Dimethyl-hydrazin;
Rk. mit Phenylhydrazin/A.,H2SO4 -> 1-Phenyl-3,5-dimethyl-4-tert.-butyl-pyrazol;
Rk. mit Hydrazinhydrat/A. -> 3,5-Dimethyl-4-tert.-butyl-pyrazol;

  • 13
  • [ 6829-40-9 ]
  • [ 13221-94-8 ]
  • [ 28991-95-9 ]
YieldReaction ConditionsOperation in experiment
60% With acetic acid for 2h; Heating;
  • 14
  • [ 13221-94-8 ]
  • [ 1187-42-4 ]
  • 6-tert-butyl-2,3-dicyano-5,7-dimethyl-6H-1,4-diazepine [ No CAS ]
YieldReaction ConditionsOperation in experiment
8% With oxalic acid In benzene Heating;
  • 15
  • [ 13221-94-8 ]
  • 6-tert-butyl-2,3-dicyano-5-[4-(diethylamino)styryl]-7-methyl-6H-1,4-diazepine [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: 8 percent / oxalic acid / benzene / Heating 2: 16 percent / piperidine / benzene / 66 h / Heating
  • 16
  • [ 13221-94-8 ]
  • [ 173972-05-9 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: 60 percent / acetic acid / 2 h / Heating 2: 88 percent / sodium benzyloxide / 1.58 h / 20 - 250 °C
  • 17
  • [ 13221-94-8 ]
  • [ 173972-07-1 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 3 steps 1: 60 percent / acetic acid / 2 h / Heating 2: 88 percent / sodium benzyloxide / 1.58 h / 20 - 250 °C 3: 88 percent / acetic acid; acetic anhydride / 3 h / 20 °C
  • 18
  • [ 13221-94-8 ]
  • [ 544434-63-1 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 5 steps 1: 60 percent / acetic acid / 2 h / Heating 2: 88 percent / sodium benzyloxide / 1.58 h / 20 - 250 °C 3: 88 percent / acetic acid; acetic anhydride / 3 h / 20 °C 4: 72 percent / acetic acid / propan-2-ol / 16 h / Heating 5: 98 percent / hydrogen; triethylamine / palladium-charcoal / tetrahydrofuran; methanol / 16 h / 2068.59 Torr
  • 19
  • [ 13221-94-8 ]
  • C36H43N3O [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 6 steps 1.1: 60 percent / acetic acid / 2 h / Heating 2.1: 88 percent / sodium benzyloxide / 1.58 h / 20 - 250 °C 3.1: 88 percent / acetic acid; acetic anhydride / 3 h / 20 °C 4.1: 72 percent / acetic acid / propan-2-ol / 16 h / Heating 5.1: 98 percent / hydrogen; triethylamine / palladium-charcoal / tetrahydrofuran; methanol / 16 h / 2068.59 Torr 6.1: TFA / CH2Cl2 / 2 h 6.2: 4.9 percent / DDQ / CH2Cl2 / 1 h
  • 20
  • [ 13221-94-8 ]
  • 9,18-di-tert-butyl-13,14-diethyl-8,19-dimethyl-21-carbabenzo[b]porphyrin [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 6 steps 1.1: 60 percent / acetic acid / 2 h / Heating 2.1: 88 percent / sodium benzyloxide / 1.58 h / 20 - 250 °C 3.1: 88 percent / acetic acid; acetic anhydride / 3 h / 20 °C 4.1: 72 percent / acetic acid / propan-2-ol / 16 h / Heating 5.1: 98 percent / hydrogen; triethylamine / palladium-charcoal / tetrahydrofuran; methanol / 16 h / 2068.59 Torr 6.1: TFA / CH2Cl2 6.2: 18 percent / DDQ / CH2Cl2
  • 21
  • [ 13221-94-8 ]
  • 9,18-di-tert-butyl-13,14-diethyl-8,19-dimethyloxypyriporphyrin [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 6 steps 1.1: 60 percent / acetic acid / 2 h / Heating 2.1: 88 percent / sodium benzyloxide / 1.58 h / 20 - 250 °C 3.1: 88 percent / acetic acid; acetic anhydride / 3 h / 20 °C 4.1: 72 percent / acetic acid / propan-2-ol / 16 h / Heating 5.1: 98 percent / hydrogen; triethylamine / palladium-charcoal / tetrahydrofuran; methanol / 16 h / 2068.59 Torr 6.1: TFA / CH2Cl2 / 16 h 6.2: 25 percent / DDQ / CH2Cl2 / 1 h
  • 22
  • [ 13221-94-8 ]
  • [ 544434-53-9 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 4 steps 1: 60 percent / acetic acid / 2 h / Heating 2: 88 percent / sodium benzyloxide / 1.58 h / 20 - 250 °C 3: 88 percent / acetic acid; acetic anhydride / 3 h / 20 °C 4: 72 percent / acetic acid / propan-2-ol / 16 h / Heating
  • 23
  • [ 13221-94-8 ]
  • bis(hexamethyldisilylamido)mercury(II) [ No CAS ]
  • HgCH2COHC(C(CH3)3)COCH2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
several days;
  • 24
  • [ 13221-94-8 ]
  • bis(hexamethyldisilylamido)mercury(II) [ No CAS ]
  • [ 113568-55-1 ]
YieldReaction ConditionsOperation in experiment
98% N2 atmosphere, pptn. (4 h); repptn. on addn. of pentane to CHCl3 soln., drying (vacuum); elem. anal.;
  • 25
  • [ 1641-40-3 ]
  • [ 13221-94-8 ]
  • 4-tert-butyl-2,5-dimethyl-7,7-bis(trifluoromethyl)-1,1-ophenylenedioxa-2,6,8-trioxa-1-phosphabicyclo[4.3.21,5]octane [ No CAS ]
  • 3,3,7,7-tetrakis(trifluoromethyl)-1,1-o-phenylenedioxa-5-(1-tert-butyl-2-oxopropyl)-2,6,8-trioxa-1-phosphabicyclo[4.3.21,5]octane [ No CAS ]
YieldReaction ConditionsOperation in experiment
20% With chloro-trimethyl-silane; triethylamine In benzene for 64h; Reflux;
  • 26
  • [ 1641-40-3 ]
  • [ 13221-94-8 ]
  • C15H19O4P [ No CAS ]
YieldReaction ConditionsOperation in experiment
With triethylamine; zinc(II) chloride In toluene for 22h; Reflux;
  • 27
  • [ 1641-40-3 ]
  • [ 13221-94-8 ]
  • C15H19O4P [ No CAS ]
  • 4-(1,3,2-benzodioxaphosphol-2-yloxy)-3-tert-butylpent-3-en-2-one [ No CAS ]
YieldReaction ConditionsOperation in experiment
1: 80% 2: 20% With chloro-trimethyl-silane; triethylamine In benzene for 64h; Reflux;
  • 28
  • [ 1641-40-3 ]
  • [ 13221-94-8 ]
  • 3,3,7,7-tetrakis(trifluoromethyl)-1,1-o-phenylenedioxa-5-(1-tert-butyl-2-oxopropyl)-2,6,8-trioxa-1-phosphabicyclo[4.3.21,5]octane [ No CAS ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: triethylamine; zinc(II) chloride / toluene / 22 h / Reflux 2: tetrachloromethane / 8 h / -40 - 20 °C / Inert atmosphere
  • 29
  • [ 13221-94-8 ]
  • C44H32Cl2Ir2N2 [ No CAS ]
  • C53H47IrN2O2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
70% With potassium carbonate In 1,2-dimethoxyethane at 120℃; for 24h; Inert atmosphere; 6.2 Step 2 Weigh the bridging ligand B086 (8.57mmol, 14g) in orange-red powder form,Add 4.02g ligand 3-tert-butylpentane-2,4-dione C086,Then add 400 mL of ethylene glycol ether and 11.85 g of potassium carbonate to the system. Under nitrogen protection, stir at 120°C for 24 hours, filter with suction, wash with alcohol, dry, and use dichloromethane as solvent.Using silica gel column chromatography, the filtrate was concentrated and the solid was precipitated to obtain the final red compound K086 (11.3g, yield 70%);
Same Skeleton Products
Historical Records