Home Cart 0 Sign in  

[ CAS No. 14680-77-4 ] {[proInfo.proName]}

,{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]}
Chemical Structure| 14680-77-4
Chemical Structure| 14680-77-4
Structure of 14680-77-4 * Storage: {[proInfo.prStorage]}
Cart0 Add to My Favorites Add to My Favorites Bulk Inquiry Inquiry Add To Cart

Quality Control of [ 14680-77-4 ]

Related Doc. of [ 14680-77-4 ]

Alternatived Products of [ 14680-77-4 ]

Product Details of [ 14680-77-4 ]

CAS No. :14680-77-4 MDL No. :MFCD00043105
Formula : C24H16BCl4K Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W : 496.11 Pubchem ID :-
Synonyms :

Safety of [ 14680-77-4 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P264-P271-P261-P280-P302+P352-P304+P340-P305+P351+P338-P312-P362-P403+P233-P501 UN#:N/A
Hazard Statements:H315-H319-H335 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 14680-77-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 14680-77-4 ]

[ 14680-77-4 ] Synthesis Path-Downstream   1~30

  • 1
  • [ 14680-77-4 ]
  • [ 22059-60-5 ]
  • disopyramide tetrakis-(4-chlorophenyl)borate [ No CAS ]
YieldReaction ConditionsOperation in experiment
In ethanol; water
  • 2
  • [ 14680-77-4 ]
  • hexadecanamidine, tetrafluoroborate salt [ No CAS ]
  • hexadecanamidine, salt with tetrakis(4-chlorophenyl)borate [ No CAS ]
YieldReaction ConditionsOperation in experiment
97% In methanol; water for 0.5h;
  • 3
  • [ 14842-08-1 ]
  • [ 14680-77-4 ]
  • tetraphenylarsonium tetrakis-(4-chlorophenyl)borate [ No CAS ]
  • 4
  • [ 12089-15-5 ]
  • (C2H5)4N(1+)*(CH3)5C5Rh(CN)3(1-)*H2O=(C2H5)4N[(CH3)5C5Rh(CN)3]*H2O [ No CAS ]
  • [ 14680-77-4 ]
  • (Et4N)3K[(CH3)5C5Rh(μ-CN)3]4[Mo(CO)3]4 [ No CAS ]
YieldReaction ConditionsOperation in experiment
63% In acetonitrile byproducts: C6H3Me3; pptn. on Et2O addn.; elem. anal.;
  • 6
  • rubidium chloride [ No CAS ]
  • [ 14680-77-4 ]
  • [ 110019-20-0 ]
YieldReaction ConditionsOperation in experiment
In ethanol; water pptn. on mixing ethanolic K-salt soln. and 100 fold aq. K-salt soln.; recrystn. from acetone;
  • 7
  • Fe4S4I[(CH3)3C6H2NC]9*(C2H5)2O [ No CAS ]
  • [ 14680-77-4 ]
  • [Fe4S4(CNC6H2(CH3)3)9]2(2+)*2B(C6H4Cl)4(1-)=[Fe4S4(CNC6H2(CH3)3)9]2[B(C6H4Cl)4]2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
65% In not given under Ar;
  • 8
  • [ 81293-80-3 ]
  • [ 14680-77-4 ]
  • K4[Cu(II) 5,10,15,20-tetrakis(benzo-15-crown-5)porphyrin]2(4+) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In benzonitrile K compd. added to soln. of Cu porphyrin at room temp.; not isolated; monitored by UV-vis spectra;
  • 9
  • [ 81642-65-1 ]
  • [ 14680-77-4 ]
  • K4[VO(5,10,15,20-tetrakis(benzo-15-crown-5)porphyrin)]2(4+) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In benzonitrile K compd. added to soln. of VO porphyrin at room temp.; not isolated; monitored by UV-vis spectra;
  • 10
  • [ 97374-53-3 ]
  • [ 14680-77-4 ]
  • K4[Ni(II) 5,10,15,20-tetrakis(benzo-15-crown-5)porphyrin]2(4+) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In benzonitrile K compd. added to soln. of Ni porphyrin at room temp.; not isolated; monitored by UV-vis spectra;
  • 11
  • [ 797750-55-1 ]
  • [ 14680-77-4 ]
  • K4[Pd(II) 5,10,15,20-tetrakis(benzo-15-crown-5)porphyrin]2(4+) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In benzonitrile K compd. added to soln. of Pd porphyrin at room temp.; not isolated; monitored by UV-vis spectra;
  • 12
  • [ 797750-56-2 ]
  • [ 14680-77-4 ]
  • K4[Ag(II) 5,10,15,20-tetrakis(benzo-15-crown-5)porphyrin]2(4+) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In benzonitrile K compd. added to soln. of Ag porphyrin at room temp.; not isolated; monitored by UV-vis spectra;
  • 13
  • [ 81293-84-7 ]
  • [ 14680-77-4 ]
  • K4[Co(II) 5,10,15,20-tetrakis(benzo-15-crown-5)porphyrin]2(4+) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In benzonitrile K compd. added to soln. of Co porphyrin at room temp.; not isolated; monitored by UV-vis spectra;
  • 14
  • [ 81315-54-0 ]
  • [ 14680-77-4 ]
  • K4[Zn(II) 5,10,15,20-tetrakis(benzo-15-crown-5)porphyrin]2(4+) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In benzonitrile K compd. added to soln. of Zn porphyrin at room temp.; not isolated; monitored by UV-vis spectra;
  • 15
  • [ 69377-34-0 ]
  • [ 14680-77-4 ]
  • p-chlorophenyl(tetraphenylporphynato) indium [ No CAS ]
  • (tetraphenylporphinato) indium (tetrakis(p-chlorphenyl)borate) [ No CAS ]
  • [ 98-80-6 ]
YieldReaction ConditionsOperation in experiment
With 4-morpholinoethanesulfonate In water; chlorobenzene byproducts: KOH; two-phase reaction of chlorobenzene soln. of In-tetraphenylporphyrinato complex with potassium tetrakis(p-chlorophenyl)borate at pH 6.0 bufferedby 4-morpholinoethanesulfonate soln.;
  • 16
  • [ 110717-82-3 ]
  • [ 14680-77-4 ]
  • K4[zinc 4,5,4',5',4'',5'',4''',5'''-tetrakis(1,4,7,10,13-pentaoxatrideca-methylene)phthalocyanine)]2(4+) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In benzonitrile identified by UV spectroscopy;
  • 17
  • [ 54653-25-7 ]
  • [ 14680-77-4 ]
  • [ 1332896-01-1 ]
YieldReaction ConditionsOperation in experiment
56% With 18-crown-6 ether; acetylacetonato(1,5-cyclooctadiene)rhodium(I); 6,6′-[(3,3′-di-tert-butyl-5,5′-dimethoxy-1,1′-biphenyl-2,2′-diyl)bis(oxy)]bis(di-benzo[d,f][1,3,2]dioxaphosphepin) In water; toluene at 100℃; for 20h; Inert atmosphere; regioselective reaction;
56% With acetylacetonato(1,5-cyclooctadiene)rhodium(I); 18-crown-6 ether; 6,6′-[(3,3′-di-tert-butyl-5,5′-dimethoxy-1,1′-biphenyl-2,2′-diyl)bis(oxy)]bis(di-benzo[d,f][1,3,2]dioxaphosphepin) In water; toluene at 100℃; for 20h; Inert atmosphere; 8 General Procedure for the Isomerization-Conjugate Addition Reaction of Arylborates General procedure: An oven-dried 20 mL crimp top vial was charged with acetylacetonato(1,5-cyclooctadiene)rhodium(I) (1.5 mol %), Biphephos (1.5 mol %), arylborate salt (2.0 equiv.) and stir bar, sealed with a Teflon septum and evacuated-purged with argon three times. Subsequently, toluene (3 mL/mmol ester), olefinic ester 1 (0.5-1.0 mmol) and water (150 μL/mmol ester) were added via hypodermic syringe, and the reaction mixture was stirred for 20 h at 100° C. After cooling to r.t. (=21° C.), the solvent was removed in vacuo and ester 3 was obtained after flash column chromatography (SiO2, ethyl acetate-hexane or diethyl ether-hexane).
  • 18
  • cobalt(II) chloride hexahydrate [ No CAS ]
  • {Et3NH}2{3,5-di-t-butylcatecholate} [ No CAS ]
  • [ 14680-77-4 ]
  • [ 155019-98-0 ]
  • [ 1218900-85-6 ]
YieldReaction ConditionsOperation in experiment
61% With [Fe(Cp)2][BF4]
  • 19
  • fac-[Re(CO)3(1,10-phenanthroline)(CN)] [ No CAS ]
  • [ 14680-77-4 ]
  • [Re(CO)3(1,10-phenanthroline){CNB(C6H4Cl)3}] [ No CAS ]
YieldReaction ConditionsOperation in experiment
56% With hydrogenchloride In methanol; water at 20℃;
  • 20
  • C30H16ClF4IrN4 [ No CAS ]
  • [ 7732-18-5 ]
  • [ 14680-77-4 ]
  • {Ir(F2ppy)2(CNC6H4Cl-4)(CNBPh3)}*0.5H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
50% Stage #1: C30H16ClF4IrN4; water With hydrogenchloride In methanol for 0.5h; Stage #2: potassium tetrakis(4-chlorophenyl)borate In water
  • 21
  • C30H16ClF4IrN4 [ No CAS ]
  • [ 7732-18-5 ]
  • [ 14680-77-4 ]
  • {Ir(F2ppy)2(CNC6H4Cl-4)[CNB(C6H4Cl-4)3]*H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
57% Stage #1: C30H16ClF4IrN4; water With hydrogenchloride In methanol; water for 0.5h; Stage #2: potassium tetrakis(4-chlorophenyl)borate In methanol
  • 22
  • [ 60-29-7 ]
  • [Ir(biqb)(ppy)(CN)]*0.5H2O [ No CAS ]
  • [ 14680-77-4 ]
  • {Ir(biqb)(ppy)[CNB(C6H4Cl-4)3]*0.5Et2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
67% Stage #1: [Ir(biqb)(ppy)(CN)]*0.5H2O With hydrogenchloride In methanol; water for 0.5h; Stage #2: diethyl ether; potassium tetrakis(4-chlorophenyl)borate In methanol; water
  • 23
  • [ 75-09-2 ]
  • C30H20ClIrN4 [ No CAS ]
  • [ 14680-77-4 ]
  • {Ir(ppy)2(CNC6H4Cl-4)[CNB(C6H4Cl-4)3]*0.5CH2Cl2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
46% Stage #1: C30H20ClIrN4 With hydrogenchloride In methanol; water for 0.5h; Stage #2: dichloromethane; potassium tetrakis(4-chlorophenyl)borate In methanol; water
  • 24
  • [ 75-09-2 ]
  • C41H31IrN3P [ No CAS ]
  • [ 14680-77-4 ]
  • {Ir(ppy)2(PPh3)[CNB(C6H4Cl-4)3]*0.5CH2Cl2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
66% Stage #1: C41H31IrN3P With hydrogenchloride In methanol; water for 0.5h; Stage #2: dichloromethane; potassium tetrakis(4-chlorophenyl)borate In methanol; water
  • 25
  • 4C57H36N10*12CF3O3S(1-)*6Cd(2+) [ No CAS ]
  • [ 14680-77-4 ]
  • C24H16BCl4(1-)*K(1+)*4C57H36N10*12CF3O3S(1-)*6Cd(2+) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In acetonitrile at 24.84℃;
  • 26
  • 4C57H36N10*6Zn(2+) [ No CAS ]
  • [ 14680-77-4 ]
  • 4C57H36N10*6Zn(2+)*C24H16BCl4(1-)*K(1+) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In acetonitrile at 24.84℃;
  • 27
  • 4C58H37N9O*6Zn(2+)*12CF3O3S(1-) [ No CAS ]
  • [ 14680-77-4 ]
  • 4C58H37N9O*6Zn(2+)*12CF3O3S(1-)*C24H16BCl4(1-)*K(1+) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In [D3]acetonitrile at 24.84℃;
  • 28
  • [ 1445-45-0 ]
  • [ 14680-77-4 ]
  • [ 111-46-6 ]
  • [ 112-27-6 ]
  • C24H16BCl4(1-)*C18H34O10*K(1+) [ No CAS ]
YieldReaction ConditionsOperation in experiment
55% With 2,2,3,3,3-pentafluoropropanoic anhydride Schlenk technique; Inert atmosphere;
  • 29
  • [ 14680-77-4 ]
  • [ 2050-68-2 ]
YieldReaction ConditionsOperation in experiment
85% With 4-acetylamino-2,2,6,6-tetramethylpiperidine-1-oxoammonium tetrafluoroborate In acetonitrile at 60℃; for 18h;
68% With 6C50H46N6O4*4Zn(2+)*8C2F6NO4S2(1-); chloranil; fullerene-C<SUB>6</SUB><SUB>0</SUB> In acetonitrile at 90℃; for 40h; Inert atmosphere; Schlenk technique; Glovebox;
  • 30
  • [ 14680-77-4 ]
  • [ 108-90-7 ]
YieldReaction ConditionsOperation in experiment
With bis((1,1,1-trifluoro-N-(trifluoromethyl)sulfonyl)methylsulfonamido)zinc; C38H40N4O4 In acetonitrile at 90℃; for 40h; Inert atmosphere; Schlenk technique; Glovebox;
Same Skeleton Products
Historical Records