Purity | Size | Price | VIP Price | USA Stock *0-1 Day | Global Stock *5-7 Days | Quantity | |||||
{[ item.p_purity ]} | {[ item.pr_size ]} |
{[ getRatePrice(item.pr_usd, 1,1) ]} {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate) ]} |
{[ getRatePrice(item.pr_usd, 1,1) ]} | Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate) ]} {[ getRatePrice(item.pr_usd,1,item.mem_rate) ]} | {[ item.pr_usastock ]} | Inquiry - | {[ item.pr_chinastock ]} | Inquiry - |
* Storage: {[proInfo.prStorage]}
CAS No. : | 1583286-47-8 | MDL No. : | MFCD18729905 |
Formula : | C13H18BFO2 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | - |
M.W : | 236.09 | Pubchem ID : | - |
Synonyms : |
|
Signal Word: | Warning | Class: | |
Precautionary Statements: | P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P330-P363-P501 | UN#: | |
Hazard Statements: | H302-H312-H332 | Packing Group: | |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; 4,4'-di-tert-butyl-2,2'-bipyridine; In hexane;Inert atmosphere; Glovebox; | General procedure: Example 5Experimental MethodsGeneral Procedure for Ligand Studies in Borylation of 3-Fluorotoluene0400] In a nitrogen-filled glovebox, a 3 mL Wheaton vial was charged with [Ir(OMe)cod]2 (3.3 mg, 0.005 mmol, 1 mol %), B2pin2 (127 mg, 0.5 mmol), and dtbpy (2.7 mg, 0.01 mmol, 2 mol %), followed by hexane (1.5 mL). In the case of 2-(aminomethyl)pyridine (1.0 muL, 0.01 mmol, 2 mol %), it was added last. To the resulting solutions, 3-fluorotoluene (111 muL, 1.0 mmol) was added. The vials were capped and removed from of the glovebox. The reaction mixtures were heated at 70 C. for 15 h. The reaction mixtures were cooled to rt, opened to the air, and samples were taken for GC analysis. The results are presented in Table 4 above. [0401] An alternate procedure was employed when using 2-methoxypyridine as the ligand. In a nitrogen-filled glovebox, a 3 mL Wheaton vial was charged with [Ir(OMe)cod]2 (6.6 mg, 0.01 mmol, 1 mol %) and B2pin2 (254 mg, 1.0 mmol), followed THF (1.5 mL). To the resulting solution 3-fluorotoluene (111 muL, 1.0 mmol) was added followed by 2-methoxypyridine (2.1 muL, 0.02 mmol, 2 mol %). The vial was capped and removed from the glovebox. The reaction mixture was heated at 80 C. for 24 h. The reaction mixture was cooled to rt, opened to the air, and a sample was taken for NMR analysis. |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
79% | With pyridine; cesium fluoride; In dimethyl sulfoxide; at 105℃; for 2h;Inert atmosphere; Schlenk technique; | General procedure: An oven-dried Schlenk tube, containing a Teflon-coated magnetic stir bar was charged with CsF (228 mg, 1.5 mmol, 3 equiv), bispinacolatodiboron (254 mg, 1 mmol, 2 equiv), and the appropriate aryl iodide (0.5 mmol). Under an argon atmosphere, freshly distilled DMSO (0.4 mL) and pyridine (0.4 to 1 equiv) were added successively using a syringe. The reaction mixture was heated to 105 C and stirred and stirred for 2 h under argon. |