Alternatived Products of [ 29710-58-5 ]
Product Details of [ 29710-58-5 ]
CAS No. : | 29710-58-5 |
MDL No. : | MFCD04613028 |
Formula : |
C10H9ClO6S
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Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
292.69
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Pubchem ID : | - |
Synonyms : |
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Safety of [ 29710-58-5 ]
Signal Word: | |
Class: | |
Precautionary Statements: | |
UN#: | |
Hazard Statements: | |
Packing Group: | |
Application In Synthesis of [ 29710-58-5 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 29710-58-5 ]
- 1
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[ 99-05-8 ]
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[ 29710-58-5 ]
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[ 1013296-47-3 ]
Yield | Reaction Conditions | Operation in experiment |
85.7% |
With pyridine In methanol at 10 - 23℃; for 1h; |
3
A 213.4 g portion of the crystals were added to 2, 500 ml methanol solution of 100.0 g m-aminobenzoic acid, and the liquid temperature was kept at 10°C. A 59.0 ml portion of pyridine was added thereto, and the liquid temperature was increased to 23°C. After stirring at this temperature for 1 hour, the thus precipitated crystals were collected by filtration and washed twice with 2, 500 ml of ion exchange water. After drying at 70°C, 246.1 g of white crystals were obtained (yield 85.7%). |
- 2
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[ 363-81-5 ]
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[ 29710-58-5 ]
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5-[N-(2,4,6-trifluorophenyl)sulfamoyl]-isophthalic acid dimethyl ester
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
78.6% |
With pyridine; hydrogenchloride; In 1,1-dichloroethane; |
(a) 5-[N-(2,4,6-Trifluorophenyl)sulfamoyl]-isophthalic acid dimethyl ester 2.94 g (20 mmol) of <strong>[363-81-5]2,4,6-trifluoroaniline</strong> is dissolved in 50 ml of dichloroethane with exclusion of moisture, 3.16 g (40 mmol) of pyridine is added and the solution is cooled to 0 C. With this temperature being maintained, a solution of 5.85 g (20 mmol) of 5-chlorosulfonylisophthalic acid dimethyl ester in 50 ml of dichloroethane is instilled. It is stirred for 30 more minutes at 0 C. and 5 more hours at room temperature. The suspension is shaken out three times with 2N hydrochloric acid and twice with water, the organic phase is dried on sodium sulfate, filtered, concentrated by evaporation and the residue is chromatographed on silica gel 60 (Merck) with ethyl acetate/hexane. The fractions, concentrated by evaporation, of corresponding polarity yield 6.34 g (15.72 mmol)=78.6% of the theoretical yield is obtained as a partially crystalline product. |