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[ CAS No. 3091-32-5 ] {[proInfo.proName]}

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Chemical Structure| 3091-32-5
Chemical Structure| 3091-32-5
Structure of 3091-32-5 * Storage: {[proInfo.prStorage]}
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Product Details of [ 3091-32-5 ]

CAS No. :3091-32-5 MDL No. :MFCD00003817
Formula : C18H33ClSn Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W : 403.62 Pubchem ID :-
Synonyms :

Safety of [ 3091-32-5 ]

Signal Word:Danger Class:6.1
Precautionary Statements:P260-P262-P264-P270-P271-P273-P280-P284-P301+P310+P330-P302+P352+P310-P304+P340+P310-P314-P361+P364-P391-P403+P233-P405-P501 UN#:3146
Hazard Statements:H300+H310+H330-H372-H410 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 3091-32-5 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 3091-32-5 ]

[ 3091-32-5 ] Synthesis Path-Downstream   1~24

  • 1
  • [ 3091-32-5 ]
  • [ 2550-40-5 ]
YieldReaction ConditionsOperation in experiment
80% With sulfur; cesium fluoride In N,N-dimethyl-formamide at 130℃; for 48h;
50% With sulfur; potassium fluoride In water; N,N-dimethyl-formamide at 150℃; for 22h;
  • 2
  • [ 3091-32-5 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
In 1,2-dimethoxyethane; dichloromethane; water 8.b Preparation of O-Tricyclohexylstannyl-3,4-dichlorothiophenylacetoamidoxime-ether STR12 (b) Dimethoxyethane (about 75 ml) was added to the sodium salt from step (a) and the resulting mixture was stirred. Tricyclohexyl tin chloride, 4.8 g (0.01189 moles) was then added. The reaction mixture was refluxed for about 16 hours. The dimethoxyethane was removed by stripping. Water (about 75 ml) and methylene chloride (about 125 ml) were added to the residue. The layers were phase separated. The methylene chloride layer was washed twice with water, dried over magnesium sulfate, filtered and stripped to give the above-identified product, as a viscous amber liquid. Elemental analysis for C26 H40 Cl2 N2 OSSn showed: calculated %C 50.5, %H 6.52, and %N 4.53; found %C 50.93, %H 7.69, and %N 3.68
  • 3
  • [ 103418-56-0 ]
  • [ 3091-32-5 ]
  • [ 103435-46-7 ]
YieldReaction ConditionsOperation in experiment
With triethylamine In dichloromethane 7 2-(2'-Furyl)-4-Tricyclohexylstannyl-5-Oxo-1,3,4-Oxadiazoline 2-(2'-Furyl)-4-Tricyclohexylstannyl-5-Oxo-1,3,4-Oxadiazoline Into a stirred mixture of 3 g (0.02 mole) 2-(2'-furyl)-5-oxo-1,3,4-oxadiazoline and 8 g (0.02 mole) tricyclohexyl tin chloride in methylene chloride, 2 g (0.02 mole) triethylamine in methylene chloride was dropped in. The reaction mixture was stirred about 1 hour at ambient temperature, refluxed about 4.5 hours, and stirred over the weekend. The reaction was refluxed about an additional hour, cooled and extracted with methylene chloride. The methylene chloride extracts were dried and stripped to give the above-identified product as a solid, melting point 159°-163° C. Elemental analysis for C24 H36 N2 O2 Sn showed: calculated %C 55.51, %H 7.0, and %N 5.4; found %C 55.64, %H 7.43, and %N 4.6
  • 4
  • [ 3091-32-5 ]
  • [ 6258-66-8 ]
  • [ 110234-10-1 ]
YieldReaction ConditionsOperation in experiment
With sodium hydroxide In ethanol; dichloromethane; water 2 Preparation of 4-Chlorobenzylthio-tricyclohexylstannane STR7 EXAMPLE 2 Preparation of 4-Chlorobenzylthio-tricyclohexylstannane STR7 A mixture of 2.69 g (0.017 mole) 4-chlorobenzylthiol, 0.68 g (0.017 mole) sodium hydroxide in ethanol (about 75 ml) were stirred until the sodium hydroxide had dissolved. To that mixture, 6.86 g (0.017 mole) tricyclohexyltin chloride was added in one portion. The reaction mixture was refluxed. The progress of the reaction was monitored by following the pH with pH paper. When the pH of the reaction mixture became neutral, the solvent was removed by reduced pressure and a hot water bath. Water (about 50 ml) and methylene chloride (about 150 ml) were added to the residue; the resulting mixture was stirred. The layers were phase separated. The methylene chloride layer was washed three times with water and then dried over magnesium sulfate to yield about 8 g of the above-identified product as a thick opaque liquid. Elemental analysis for C25 H39 ClSSn showed: calculated % C 57.1, % H 7.48, and % N 0; found % C 57.43, % H 7.76, and % N 0.54.
  • 5
  • [ 2664-63-3 ]
  • [ 3091-32-5 ]
  • [ 68974-04-9 ]
YieldReaction ConditionsOperation in experiment
In tetrahydrofuran; water; benzene 1 4,4'-bis-(Tricyclohexylstannoxy)-diphenylsulfide EXAMPLE 1 4,4'-bis-(Tricyclohexylstannoxy)-diphenylsulfide A 200 milliliter flask was charged with 1.5 grams (0.060 mole) of sodium hydride, 50 milliliters of tetrahydrofuran, and 5.0 grams (0.023 mole) of 4,4'-thiodiphenol. To this was added in dropwise manner 18.1 grams (0.045 mole) of tricyclohexyl tin chloride dissolved in 30 milliliters of tetrahydrofuran. The mixture was stirred overnight at ambient temperature. The solvent was evaporated and the residue treated with 100 milliliters benzene and 50 milliliters water. The benzene solution was separated from the aqueous layer and the solvent evaporated to yield 18.5 grams of a colorless solid, with melting point 123°-126° C. Analysis by nuclear magnetic resonance (NMR) and mass spectrometry (MS) showed the structure to be that of the title compound.
  • 6
  • [ 7790-99-0 ]
  • [ 1449-55-4 ]
  • [ 3091-32-5 ]
YieldReaction ConditionsOperation in experiment
69.5% In tetrachloromethane N2; molar ratio = 1:1; stirring for 2 h;; removal of volatiles afforded a solid residue; recrstn. from petrol ether (40-60 ° C);
  • 7
  • [ 13200-85-6 ]
  • [ 3091-32-5 ]
  • tricyclohexyltin(IV)-N-formyl-L-phenylalanine [ No CAS ]
YieldReaction ConditionsOperation in experiment
67% With triethylamine In ethanol byproducts: triethylamine hydrochloride; peptide dissolved in abs. ethanol, added to the tin-compd., refluxed on a water bath, 2h, anhyd. triethylamine added, refluxed, 2-4h, pptn.; cooled, filtered, washed (abs. ethanol), dried (vac.), recrystn. (abs.ethanol), elem. anal.;
  • 8
  • [ 7646-78-8 ]
  • [ 1449-55-4 ]
  • [ 542-18-7 ]
  • [ 3342-69-6 ]
  • [ 3091-32-5 ]
  • tin(ll) chloride [ No CAS ]
YieldReaction ConditionsOperation in experiment
In dimethyl sulfoxide different ratios of educts, 100 and 200°C, 1-120 h;
In dimethyl sulfoxide different ratios of educts, 100 and 200°C, 1-120 h;
  • 9
  • [ 7646-78-8 ]
  • [ 1449-55-4 ]
  • [ 3091-32-5 ]
YieldReaction ConditionsOperation in experiment
In benzene 2h, reflux;
In benzene 2h, reflux;
  • 10
  • [ 75-77-4 ]
  • [ 13121-70-5 ]
  • [ 3091-32-5 ]
YieldReaction ConditionsOperation in experiment
73% for 18h; Reflux; In a 500 mL three-necked flask, trimethylsilyl chloride (170 g, 109 mmol) was added to tricyclohexyltin hydroxide (80 g, 133 mmol) and heated at reflux during 18 hours. After distillation of trimethylsilyl chloride in excess and hexamethyldisiloxane under reduced pressure, the crude product was recrystallized in petroleum ether. White needles were obtained (39.82 g, 79.6 mmol).Yield: 73%1H NMR (CDCl3) δ: 2.1-1.31 (33H, ma)13C NMR (CDCl3) δ: 34.25; 31.56; 29.27; 27.22.119Sn NMR (CDCl3) δ: 70.3 ppm
67% In neat (no solvent) byproducts: hexamethyldisiloxane; N2-atmosphere; refluxing (12 h); distg., recrystn. (petroleum ether);
  • 11
  • [ 1073-67-2 ]
  • [ 3091-32-5 ]
  • [ 2413-03-8 ]
YieldReaction ConditionsOperation in experiment
75% With ammonium chloride; magnesium In tetrahydrofuran; diethyl ether N2-atmosphere; refluxing (30 min), Sn-compd. soln. (Et2O) addn., refluxing (4 h), NH4Cl satd. soln. addn.; recrystn. (EtOH); elem. anal.;
  • 12
  • [ 1118-15-6 ]
  • [ 3091-32-5 ]
  • [ 156116-72-2 ]
YieldReaction ConditionsOperation in experiment
95% With triethylamine In diethyl ether byproducts: triethylamine hydrochloride; stirring at room temperature, dropwise addn. of triethylamine; filtn., evapn., recrystn. (acetonitrile), elem. anal.;
  • 13
  • [ 3091-32-5 ]
  • [ 25112-68-9 ]
  • [ 112379-61-0 ]
YieldReaction ConditionsOperation in experiment
85% In ethanol byproducts: sodium chloride; to soln. of Sn-compd. in abs. alc. was added ligand, mixt. refluxed for 3-4 h, concd. to half the vol., mixt. cooled, NaCl filtered, benzene added, mixt. refluxed for 2 h (trap), NaCl filtered, repetition of procedure until NaCl is completely removed; solvents were removed completely, residue dried in vacuo; complex recrystd. from ethanol; elem. anal.;
  • 14
  • [ 127892-62-0 ]
  • [ 3091-32-5 ]
  • [ 355005-38-8 ]
YieldReaction ConditionsOperation in experiment
36% With potassium hydroxide In toluene byproducts: KCl; under dry Ar, 1 equiv. of KOH and pyrazole-compd. were stirred in toluene for 4 h at room temp., 1 equiv. of Sn-compd. was added, stirring overnight at room temp.; solvent was removed in vac., solid was recrystd. from CH2Cl2/petroleum ether (1:3, v/v), dried in vac., elem. anal.;
  • 15
  • [ 3091-32-5 ]
  • [ 1119-51-3 ]
  • [ 160593-99-7 ]
YieldReaction ConditionsOperation in experiment
81% With ammonium chloride; magnesium In diethyl ether N2-atmosphere; refluxing (30 min), Sn-compd. soln. addn., refluxing (4 h), NH4Cl satd. soln. addn.; recrystn. (EtOH); elem. anal.;
  • 16
  • [ 106-37-6 ]
  • [ 3091-32-5 ]
  • [ 96868-33-6 ]
YieldReaction ConditionsOperation in experiment
65% With Mg In tetrahydrofuran the mixt. of dibromide and Mg in THF was refluxed for 30 min, cooled to room temp., the soln. of (C6H11)3SnCl in THF was added, refluxed for 1 h(N2); hydrolyzed with a satd. soln. of NH4Cl, extd. with petroleum ether, dried with MgSO4, evapd., recrystd. from petroleum ether; elem. anal.;
  • 17
  • [ 3091-32-5 ]
  • [ 4101-68-2 ]
  • [ 476014-52-5 ]
YieldReaction ConditionsOperation in experiment
61% With Mg In tetrahydrofuran the mixt. of dibromide and Mg in THF was refluxed for 30 min, cooled to room temp., the soln. of (C6H11)3SnCl in THF was added, refluxed for 1 h(N2); hydrolyzed with a satd. soln. of NH4Cl, extd. with petroleum ether, dried with MgSO4, evapd., recrystd. from petroleum ether; elem. anal.;
  • 18
  • [ 111-24-0 ]
  • [ 3091-32-5 ]
  • [ 476014-50-3 ]
YieldReaction ConditionsOperation in experiment
61% With Mg In tetrahydrofuran the mixt. of dibromide and Mg in THF was refluxed for 30 min, cooled to room temp., the soln. of (C6H11)3SnCl in THF was added, refluxed for 1 h(N2); hydrolyzed with a satd. soln. of NH4Cl, extd. with petroleum ether, dried with MgSO4, evapd., recrystd. from petroleum ether; elem. anal.;
  • 19
  • [ 3091-32-5 ]
  • [ 623-25-6 ]
  • [ 476014-54-7 ]
YieldReaction ConditionsOperation in experiment
78% With Mg In tetrahydrofuran Mg was slowly aded to a THF-soln. of dichloride and tin-compound (N2); hydrolyzed with a satd. soln. of NH4Cl, extd. with petroleum ether, dried with MgSO4, evapd., recrystd. from petroleum ether; elem. anal.;
  • 20
  • [ 110-52-1 ]
  • [ 3091-32-5 ]
  • [ 476014-49-0 ]
YieldReaction ConditionsOperation in experiment
71% With Mg In tetrahydrofuran the mixt. of dibromide and Mg in THF was refluxed for 30 min, cooled to room temp., the soln. of (C6H11)3SnCl in THF was added, refluxed for 1 h(N2); hydrolyzed with a satd. soln. of NH4Cl, extd. with petroleum ether, dried with MgSO4, evapd., recrystd. from petroleum ether; elem. anal.;
  • 21
  • [ 3091-32-5 ]
  • [ 95-50-1 ]
  • [ 476014-53-6 ]
YieldReaction ConditionsOperation in experiment
69% With Mg In tetrahydrofuran the mixt. of dibromide and Mg in THF was refluxed for 30 min, cooled to room temp., the soln. of (C6H11)3SnCl in THF was added, refluxed for 1 h(N2); hydrolyzed with a satd. soln. of NH4Cl, extd. with petroleum ether, dried with MgSO4, evapd., recrystd. from petroleum ether; elem. anal.;
  • 22
  • [ 5162-44-7 ]
  • [ 3091-32-5 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
78% With ammonium chloride; magnesium In diethyl ether N2-atmosphere; refluxing (30 min), Sn-compd. soln. addn., refluxing (4 h), NH4Cl satd. soln. addn.; recrystn. (EtOH); elem. anal.;
  • 23
  • [ 1378810-76-4 ]
  • [ 3091-32-5 ]
  • [ CAS Unavailable ]
YieldReaction ConditionsOperation in experiment
74% With ammonium chloride; magnesium In diethyl ether N2-atmosphere; refluxing (30 min), Sn-compd. soln. addn., refluxing (4 h), NH4Cl satd. soln. addn.; recrystn. (EtOH); elem. anal.;
  • 24
  • [ 502-50-1 ]
  • [ 3091-32-5 ]
  • bis(tricyclohexyltin)-4-oxoheptanedioate [ No CAS ]
YieldReaction ConditionsOperation in experiment
46% With KOH In isopropyl alcohol 4-ketopimelic acid, KOH (19% excess) and (cyclohexyl)3SnCl were refluxedin isopropanol for 2 h; cooled; filtered; solvent evapd.; elem. anal.;
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