Alternatived Products of [ 35093-65-3 ]
Product Details of [ 35093-65-3 ]
CAS No. : | 35093-65-3 |
MDL No. : | MFCD06203286 |
Formula : |
C8H7BrO4
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Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
247.04
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Pubchem ID : | - |
Synonyms : |
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Safety of [ 35093-65-3 ]
Signal Word: | |
Class: | |
Precautionary Statements: | |
UN#: | |
Hazard Statements: | |
Packing Group: | |
Application In Synthesis of [ 35093-65-3 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 35093-65-3 ]
- 1
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[ 35093-65-3 ]
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[ 645-08-9 ]
- 2
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2-acetoxy-6-bromo-3-methoxy-benzoic acid methyl ester
[ No CAS ]
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[ 35093-65-3 ]
- 3
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[ 20035-41-0 ]
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[ 35093-65-3 ]
- 5
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[ 64-17-5 ]
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[ 35093-65-3 ]
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[ 143-33-9 ]
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copper (I)-cyanide
[ No CAS ]
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[ 645-08-9 ]
- 6
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[ 500798-31-2 ]
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[ 35093-65-3 ]
- 7
-
[ 35093-65-3 ]
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[ 1219130-61-6 ]
Yield | Reaction Conditions | Operation in experiment |
|
With diphenylphosphoranyl azide; triethylamine; In toluene; at 20 - 80℃; for 5.0h;Inert atmosphere; |
Example 30: 4-Bromo-7-methoxybenzo[d]oxazol-2(3H)-one:<strong>[35093-65-3]6-Bromo-2-hydroxy-3-methoxybenzoic acid</strong> (3.00 g) was dissolved in toluene (120 mL) under an argon gas atmosphere, followed by the addition of diphenylphosphoryl azide (2.89 mL) and triethylamine (1.97 mL) to the resultant solution at ordinary temperature and the stirring of the mixture at 80C for 5 hours. The solvent was distilled off under reduced pressure and the resultant residue was then washed with ethyl acetate to give a desired compound (597 mg) as white solid. 1H NMR (DMSO-d6, 400 MHz): delta 3.87 (3H, s), 6.79 (1H, d, J = 9.2 Hz), 7.25 (1H, d, J = 9.2 Hz), 12.10 (1H, s). EIMS (+): 243 [M]+. |
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With diphenylphosphoranyl azide; triethylamine; In toluene; at 20 - 80℃;Inert atmosphere; |
Example 45 4-Bromo-7-methoxybenzo[d]oxazol-2(3H)-one <strong>[35093-65-3]6-Bromo-2-hydroxy-3-methoxybenzoic acid</strong> (3.00 g) was dissolved in toluene (120 mL) under an argon gas atmosphere, there were then added, to the solution, diphenylphosphoryl azide (2.89 mL) and triethylamine (1.97 mL) at ordinary temperature and then the resulting mixture was stirred at 80 C. for 5 hours. After the solvent was distilled off under reduced pressure, the resulting residue was washed with ethyl acetate to give a desired product (597 mg) as a white solid. 1H NMR (DMSO-d6, 400 MHz): delta 3.87 (3H, s), 6.79 (1H, d, J=9.2 Hz), 7.25 (1H, d, J=9.2 Hz), 12.10 (1H, s). EIMS (+): 243 [M]+. |