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[ CAS No. 35093-65-3 ] {[proInfo.proName]}

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Chemical Structure| 35093-65-3
Chemical Structure| 35093-65-3
Structure of 35093-65-3 * Storage: {[proInfo.prStorage]}
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Product Details of [ 35093-65-3 ]

CAS No. :35093-65-3 MDL No. :MFCD06203286
Formula : C8H7BrO4 Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W : 247.04 Pubchem ID :-
Synonyms :

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Application In Synthesis of [ 35093-65-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 35093-65-3 ]

[ 35093-65-3 ] Synthesis Path-Downstream   1~7

  • 1
  • [ 35093-65-3 ]
  • [ 645-08-9 ]
  • 2
  • 2-acetoxy-6-bromo-3-methoxy-benzoic acid methyl ester [ No CAS ]
  • [ 35093-65-3 ]
  • 3
  • [ 20035-41-0 ]
  • [ 35093-65-3 ]
  • 5
  • [ 64-17-5 ]
  • [ 35093-65-3 ]
  • [ 143-33-9 ]
  • copper (I)-cyanide [ No CAS ]
  • [ 645-08-9 ]
  • 6
  • [ 500798-31-2 ]
  • [ 35093-65-3 ]
  • 7
  • [ 35093-65-3 ]
  • [ 1219130-61-6 ]
YieldReaction ConditionsOperation in experiment
With diphenylphosphoranyl azide; triethylamine; In toluene; at 20 - 80℃; for 5.0h;Inert atmosphere; Example 30: 4-Bromo-7-methoxybenzo[d]oxazol-2(3H)-one:<strong>[35093-65-3]6-Bromo-2-hydroxy-3-methoxybenzoic acid</strong> (3.00 g) was dissolved in toluene (120 mL) under an argon gas atmosphere, followed by the addition of diphenylphosphoryl azide (2.89 mL) and triethylamine (1.97 mL) to the resultant solution at ordinary temperature and the stirring of the mixture at 80C for 5 hours. The solvent was distilled off under reduced pressure and the resultant residue was then washed with ethyl acetate to give a desired compound (597 mg) as white solid. 1H NMR (DMSO-d6, 400 MHz): delta 3.87 (3H, s), 6.79 (1H, d, J = 9.2 Hz), 7.25 (1H, d, J = 9.2 Hz), 12.10 (1H, s). EIMS (+): 243 [M]+.
With diphenylphosphoranyl azide; triethylamine; In toluene; at 20 - 80℃;Inert atmosphere; Example 45 4-Bromo-7-methoxybenzo[d]oxazol-2(3H)-one <strong>[35093-65-3]6-Bromo-2-hydroxy-3-methoxybenzoic acid</strong> (3.00 g) was dissolved in toluene (120 mL) under an argon gas atmosphere, there were then added, to the solution, diphenylphosphoryl azide (2.89 mL) and triethylamine (1.97 mL) at ordinary temperature and then the resulting mixture was stirred at 80 C. for 5 hours. After the solvent was distilled off under reduced pressure, the resulting residue was washed with ethyl acetate to give a desired product (597 mg) as a white solid. 1H NMR (DMSO-d6, 400 MHz): delta 3.87 (3H, s), 6.79 (1H, d, J=9.2 Hz), 7.25 (1H, d, J=9.2 Hz), 12.10 (1H, s). EIMS (+): 243 [M]+.
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