Alternatived Products of [ 354153-47-2 ]
Product Details of [ 354153-47-2 ]
CAS No. : | 354153-47-2 |
MDL No. : | MFCD21880869 |
Formula : |
C11H16O2
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Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
180.24
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Pubchem ID : | - |
Synonyms : |
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Safety of [ 354153-47-2 ]
Signal Word: | |
Class: | |
Precautionary Statements: | |
UN#: | |
Hazard Statements: | |
Packing Group: | |
Application In Synthesis of [ 354153-47-2 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 354153-47-2 ]
- 1
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[ 769-25-5 ]
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[ 354153-47-2 ]
Yield | Reaction Conditions | Operation in experiment |
91% |
Stage #1: 2,4,6-trimethylstyrene With water; cyclopropane-1,1-dicarbonyl peroxide In chloroform at 40℃; for 24h;
Stage #2: With water; sodium hydroxide at 60℃; for 4h; |
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84% |
With 1,4-diaza-bicyclo[2.2.2]octane; potassium dioxotetrahydroxoosmate(VI); potassium carbonate In water; <i>tert</i>-butyl alcohol at 0℃; |
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With Quinuclidine; osmium(VIII) oxide; <i>tert</i>-butyl alcohol In acetone at 25℃; for 12h; |
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With tert.-butylhydroperoxide; water; iodine at 90℃; for 24h; Sealed tube; |
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Reference:
[1]Griffith, James C.; Jones, Kevin M.; Picon, Sylvain; Rawling, Michael J.; Kariuki, Benson M.; Campbell, Matthew; Tomkinson, Nicholas C. O.
[Journal of the American Chemical Society, 2010, vol. 132, # 41, p. 14409 - 14411]
[2]Bandini, Marco; Cozzi, Pier Giorgio; Gazzano, Massimo; Umani-Ronchi, Achille
[European Journal of Organic Chemistry, 2001, # 10, p. 1937 - 1942]
[3]Nicolaou; Snyder, Scott A.; Longbottom, Deborah A.; Nalbandian, Annie Z.; Huang, Xianhai
[Chemistry - A European Journal, 2004, vol. 10, # 22, p. 5581 - 5606]
[4]Gao, Xiaofang; Lin, Jiani; Zhang, Li; Lou, Xinyao; Guo, Guanghui; Peng, Na; Xu, Huan; Liu, Yi
[Journal of Organic Chemistry, 2021, vol. 86, # 21, p. 15469 - 15480]
- 2
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[ 29684-56-8 ]
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[ 354153-47-2 ]
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2,2-dioxo-4-(2,4,6-trimethyl-phenyl)-2λ6-[1,2,3]oxathiazolidine-3-carboxylic acid methyl ester
[ No CAS ]
- 3
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[ 29684-56-8 ]
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[ 354153-47-2 ]
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(S)-2,2-Dioxo-4-(2,4,6-trimethyl-phenyl)-2λ6-[1,2,3]oxathiazolidine-3-carboxylic acid methyl ester
[ No CAS ]
- 4
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[ 354153-47-2 ]
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[ 924265-80-5 ]
Yield | Reaction Conditions | Operation in experiment |
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Multi-step reaction with 4 steps
1: 59 percent / CH3CN; trifluoromethanesulfonic acid / -40 - 25 °C
2: 71 percent / pyridine / CH2Cl2 / 18.5 h / 0 °C
3: NaOH / methanol / 20 °C
4: 98percent H2SO4 / H2O / Heating |
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