[ CAS No. 3582-71-6 ] {[proInfo.proName]}

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Quality Control of [ 3582-71-6 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 3582-71-6 ]

SDS Specification

Alternatived Products of [ 3582-71-6 ]

Product Details of [ 3582-71-6 ]

CAS No. :	3582-71-6	MDL No. :	MFCD00045147
Formula :	C₆H₁₈Cl₂O₂Si₃	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	-
M.W :	277.37	Pubchem ID :	-
Synonyms :

Safety of [ 3582-71-6 ]

Signal Word:	Danger	Class:	8
Precautionary Statements:	P260-P264-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P321-P363-P405-P501	UN#:	2987
Hazard Statements:	H314	Packing Group:	Ⅱ
GHS Pictogram:

Application In Synthesis of [ 3582-71-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Upstream synthesis route of [ 3582-71-6 ]
Downstream synthetic route of [ 3582-71-6 ]

[ 3582-71-6 ] Synthesis Path-Upstream 1~5

1
[ 75-78-5 ]
[ 2401-73-2 ]
[ 3582-71-6 ]
[ 2474-02-4 ]
[ 14741-59-4 ]
[ 16106-81-3 ]

Reference： [1] C. A., 1945, p. 4890
[2] C. A., 1947, p. 5544
[3] Journal of the American Chemical Society, [4] Journal of the American Chemical Society, 1946, vol. 68, p. 358 - 363
[5] , Gmelin Handbook: Si: MVol.C, 104, page 286 - 288,
[6] C. A., 1945, p. 4890
[7] Patent: US2421653, 1944, ,
[8] , Gmelin Handbook: Si: MVol.C, 104, page 286 - 288,
[9] Patent: US2381366, 1942, ,
[10] Patent: US2381366, 1942, ,

2
[ 75-78-5 ]
[ 2401-73-2 ]
[ 3582-71-6 ]

Reference： [1] Doklady Chemistry, 2013, vol. 451, # 2, p. 203 - 206[2] Dokl. Akad. Nauk, 2013, vol. 451, # 5, p. 528 - 532
[3] Doklady Chemistry, 2013, vol. 450, # 1, p. 135 - 138[4] Dokl. Akad. Nauk, 2013, vol. 450, # 3, p. 295 - 298,4
[5] Journal of Organometallic Chemistry, 1994, vol. 471, # 1-2, p. 87 - 96

3
[ 75-78-5 ]
[ 2401-73-2 ]
[ 3582-71-6 ]
[ 2474-02-4 ]

Reference： [1] Doklady Chemistry, 2013, vol. 451, # 2, p. 203 - 206[2] Dokl. Akad. Nauk, 2013, vol. 451, # 5, p. 528 - 532

4
[ 67-68-5 ]
[ 75-78-5 ]
[ 2373-51-5 ]
[ 2401-73-2 ]
[ 3582-71-6 ]

Reference： [1] Doklady Chemistry, 2013, vol. 451, # 2, p. 203 - 206[2] Dokl. Akad. Nauk, 2013, vol. 451, # 5, p. 528 - 532

5
[ 556-67-2 ]
[ 2401-73-2 ]
[ 3582-71-6 ]
[ 2474-02-4 ]
[ 14741-59-4 ]
[ 16106-81-3 ]

Reference： [1] C. A., 1954, p. 7050
[2] , Gmelin Handbook: Si: MVol.C, 104, page 286 - 288,
[3] C. A., 1954, p. 7050

[ 3582-71-6 ] Synthesis Path-Downstream 1~7

1
[ 3582-71-6 ]
[ 5536-61-8 ]
[ 1873-78-5 ]

Reference： [1]Journal of general chemistry of the USSR,1965,vol. 35,p. 758
Zhurnal Obshchei Khimii,1965,vol. 35,p. 756

2
[ 1066-35-9 ]
[ 541-05-9 ]
[ 3582-71-6 ]
[ 995-83-5 ]
[ 5895-30-7 ]

Yield	Reaction Conditions	Operation in experiment
1: 80.3% 2: 5.5% 3: 5.2%	With water for 1h; Ambient temperature;

Reference： [1]Yoshino, Koji; Kawamata, Akira; Uchida, Hiroaki; Kabe, Yoshio [Chemistry Letters, 1990, # 11, p. 2133 - 2136]

3
[ 75-78-5 ]
[ 3582-71-6 ]
[ 556-67-2 ]
[ 541-02-6 ]
[ 540-97-6 ]

Yield	Reaction Conditions	Operation in experiment
	With sodium nitrate at 0℃; for 2h; Yield given; Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts;

Reference： [1]Voronkov, M. G.; Tsyrendorzhieva, I. P.; Ivanova, N. P.; Dubinskaya, E. I. [Russian Journal of General Chemistry, 1998, vol. 68, # 4, p. 658 - 659][Zhurnal Obshchei Khimii, 1998, vol. 68, # 4, p. 699 - 700]

4
[ 3582-71-6 ]
[ 1128-76-3 ]
3-(7-ethoxy-2,2,4,4,6,6-hexamethyl-1,3,5-trioxa-2,4,6-trisilacyclohept-7-yl)chlorobenzene [ No CAS ]

Reference： [1]Tetrahedron,2006,vol. 62,p. 3103 - 3111

5
[ 3582-71-6 ]
[ 10259-22-0 ]
3-(7-ethoxy-2,2,4,4,6,6-hexamethyl-1,3,5-trioxa-2,4,6-trisilacyclohept-7-yl)-methoxybenzene [ No CAS ]

Reference： [1]Tetrahedron,2006,vol. 62,p. 3103 - 3111

6
[ 1189-93-1 ]
[ 3582-71-6 ]

Yield	Reaction Conditions	Operation in experiment
80%	With trichloroisocyanuric acid In tetrahydrofuran at -20℃; for 0.25h; Inert atmosphere; Schlenk technique;	Chlorination procedure 3 for complete chlorination General procedure: Chlorination where all Si-H bonds had to be chlorinated were performed in THF, TCCA was used in excess (1 eq. TCCA / 1 eq.siloxane). A flask was filled with educt and THF and cooled down to -20°C (20 mlTHF/g educt). TCCA was added in small portions, under intense stirring. After TCCAa ddition was completed, stirring was continued for 15 minutes, afterwards, the cooling bath was removed and the solution was allowed to come to room temperature. Varying siloxane chain lengths, substituents or Si-H bond positions affected the method in whichcompounds were isolated and characterized. THF and unreacted TCCA had to be removed soon after the reactions were completed, otherwise product degeneration was observed after a few days.

Reference： [1]Hafner, Thomas; Torvisco, Ana; Uhlig, Frank [Journal of Organometallic Chemistry, 2018, vol. 875, p. 1 - 4]

7
[ 3582-71-6 ]
[ 2050-14-8 ]
C₁₈H₂₆N₂O₄Si₃ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
83%	With triethylamine; In benzene; at 20 - 50℃; for 19h;Inert atmosphere;	General procedure: A corresponding 1,3-dichlorodisiloxane (1) or 1,5-dichlorotrisiloxane(5) (4 mmol) in benzene (10 mL) was addeddropwise to a mixture of 2,2-dihydroxyazobenzene (2) (4 mmol)and triethylmine (8 mmol) in benzene (25 mL) with vigorousstirring. The reaction mixture was stirred at room temperaturefor 1 h, then at 45-50 C for 18 h. Benzene was removed fromthe reaction mixture under reduced pressure, the residue wasdissolved in diethyl ether (25 mL), and triethylamine hydrochloridewas fi ltered off . The resulting fi ltrate was diluted with pentane(5 mL) and passed through a column with silica gel. After removalof solvents and vacuum drying, compounds 3a-d and 6were isolated as red viscous oils.

Reference： [1]Russian Chemical Bulletin,2021,vol. 70,p. 158 - 163
Izv. Akad. Nauk, Ser. Khim.,2021,p. 158 - 163,6

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[ CAS No. 3582-71-6 ] {[proInfo.proName]}

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Product Details of [ 3582-71-6 ]

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Application In Synthesis of [ 3582-71-6 ]

[ 3582-71-6 ] Synthesis Path-Upstream 1~5

[ 3582-71-6 ] Synthesis Path-Downstream 1~7

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