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Quality Control of [ 41855-35-0 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 41855-35-0 ]

SDS Specification

Alternatived Products of [ 41855-35-0 ]

Product Details of [ 41855-35-0 ]

CAS No. :	41855-35-0	MDL No. :	MFCD00188456
Formula :	C₁₈H₂₆O₇	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	-
M.W :	354.39	Pubchem ID :	-
Synonyms :

Safety of [ 41855-35-0 ]

Signal Word:	Warning	Class:
Precautionary Statements:	P261-P305+P351+P338	UN#:
Hazard Statements:	H302-H315-H319-H335	Packing Group:
GHS Pictogram:

Application In Synthesis of [ 41855-35-0 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 41855-35-0 ]

[ 41855-35-0 ] Synthesis Path-Downstream 1~27

1
[ 60835-74-7 ]
[ 41855-35-0 ]
[ 135442-24-9 ]

Yield	Reaction Conditions	Operation in experiment
15%	With potassium hydroxide In methanol at 50 - 60℃; for 240h;

Reference： [1]Luboch; Cygan; Biernat [Tetrahedron, 1991, vol. 47, # 24, p. 4101 - 4112]

2
[ 41855-35-0 ]
[ 41757-97-5 ]

Yield	Reaction Conditions	Operation in experiment
92%	With sodium tetrahydroborate In ethanol for 18h; Ambient temperature;

Reference： [1]Talma, Auke G.; Vossen, Huib van; Sudhoelter, Ernst J. R.; Eerden, Johan van; Reinhoudt, David N. [Synthesis, 1986, # 8, p. 680 - 683]

3
[ 41855-35-0 ]
[ 76427-68-4 ]

Yield	Reaction Conditions	Operation in experiment
	With peracetic acid; sodium hydroxide Multistep reaction;
	Multi-step reaction with 2 steps 1.1: toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid / dichloromethane / 20 °C / Inert atmosphere 2.1: sodium hydroxide / water / 3 h / 50 °C 2.2: pH 2

Reference： [1]Kikukawa, Kiyoshi; He, Gong-Xin; Abe, Akito; Goto, Tokio; Arata, Ryozo; et al. [Journal of the Chemical Society. Perkin transactions II, 1987, p. 135 - 142]
[2]Paramonov, Sergey V.; Lokshin, Vladimir; Smolentsev, Artem B.; Glebov, Evgeni M.; Korolev, Valeri V.; Basok, Stepan S.; Lysenko, Konstantin A.; Delbaere, Stéphanie; Fedorova, Olga A. [Tetrahedron, 2012, vol. 68, # 38, p. 7873 - 7883]

4
[ 41855-35-0 ]
[ 81117-71-7 ]

Yield	Reaction Conditions	Operation in experiment
43%	With hydrogenchloride; amalgamated zinc In 1,4-dioxane; water; toluene for 40h; Heating;

Reference： [1]Shkinev, A. V.; Asrarov, M. I.; Gagel'gans, A. I.; Saifullina, N. Zh.; Mukhamedzhanova, E. A.; Tashmukhamedova, A. K. [Chemistry of Natural Compounds, 1983, vol. 19, # 5, p. 597 - 600][Khimiya Prirodnykh Soedinenii, 1983, # 5, p. 634 - 637]

5
[ 41855-35-0 ]
[ 77586-36-8 ]

Yield	Reaction Conditions	Operation in experiment
74%	With bromine In chloroform for 2h;

Reference： [1]Fenton, David E.; Parkin, Donald; Newton, Roger F. [Journal of the Chemical Society. Perkin transactions I, 1981, p. 449 - 454]

6
[ 1197-09-7 ]
[ 76871-59-5 ]
[ 41855-35-0 ]

Yield	Reaction Conditions	Operation in experiment
	With sodium carbonate In acetone at 50 - 60℃; for 65h; Yield given;

Reference： [1]Alonso, Maria Teresa; Brunet, Ernesto; Hernandez, Concepcion; Rodriguez-Ubis, Juan Carlos [Tetrahedron Letters, 1993, vol. 34, # 46, p. 7465 - 7468]

7
[ 1197-09-7 ]
[ 41024-91-3 ]
[ 41855-35-0 ]

Yield	Reaction Conditions	Operation in experiment
48%	With sodium hydroxide In water; butan-1-ol for 72h; Heating;

Reference： [1]Fenton, David E.; Parkin, Donald; Newton, Roger F. [Journal of the Chemical Society. Perkin transactions I, 1981, p. 449 - 454]

8
[ 14098-24-9 ]
[ 108-24-7 ]
[ 41855-35-0 ]

Reference： [1]Synthesis,1986,p. 680 - 683
[2]Organometallics,2011,vol. 30,p. 396 - 404

9
[ 41855-35-0 ]
[ 90-02-8 ]
[ 105-58-8 ]
[ 154615-37-9 ]

Yield	Reaction Conditions	Operation in experiment
	With piperidine; potassium <i>tert</i>-butylate In ethanol Heating;

Reference： [1]Alonso, Maria Teresa; Brunet, Ernesto; Hernandez, Concepcion; Rodriguez-Ubis, Juan Carlos [Tetrahedron Letters, 1993, vol. 34, # 46, p. 7465 - 7468]

10
[ 14098-24-9 ]
[ 64-19-7 ]
[ 41855-35-0 ]

Yield	Reaction Conditions	Operation in experiment
80%	With methanesulfonic acid; phosphorus pentoxide; at 20℃; for 6h;	General procedure: A modification of the previously reported procedure23 was used. Commercially available Eaton's reagent (ca. 8 ml that corresponds to 6.28 mmol of phosphorus(V) oxide) and acetic acid (0.20 ml, 3.45 mmol) were mixed at room temperature. Then naphtho-15-crown-5 ether (1 g, 3.14 mmol) was added. The reaction mixture was stirred at room temperature for ca. 6 h and then poured into water. The suspension was extracted with dichloromethane and the combined organic phases were washed with water. Removal of the dried (MgSO4) solvent gave a dark brown oil, which upon repeated extractions with hot heptane, afforded the product as an off-white solid (1.02 g, 90%), mp 126-129 C.

Reference： [1]Chemistry of Natural Compounds,1983,vol. 19,p. 597 - 600
Khimiya Prirodnykh Soedinenii,1983,p. 634 - 637
[2]Tetrahedron,2012,vol. 68,p. 7873 - 7883
[3]Bulletin of the Chemical Society of Japan,1980,vol. 53,p. 2304 - 2308

11
[ CAS Unavailable ]
[ 41855-35-0 ]

Yield	Reaction Conditions	Operation in experiment
87%	With water In chloroform for 1h;

Reference： [1]Fenton, David E.; Parkin, Donald; Newton, Roger F. [Journal of the Chemical Society. Perkin transactions I, 1981, p. 449 - 454]

12
[ 673-22-3 ]
[ 41855-35-0 ]
[ 105-58-8 ]
[ 154615-38-0 ]

Yield	Reaction Conditions	Operation in experiment
	With piperidine; potassium <i>tert</i>-butylate In ethanol Heating;

Reference： [1]Alonso, Maria Teresa; Brunet, Ernesto; Hernandez, Concepcion; Rodriguez-Ubis, Juan Carlos [Tetrahedron Letters, 1993, vol. 34, # 46, p. 7465 - 7468]

13
[ 708-76-9 ]
[ 41855-35-0 ]
[ 105-58-8 ]
[ 154615-39-1 ]

Yield	Reaction Conditions	Operation in experiment
	With piperidine; potassium <i>tert</i>-butylate In ethanol Heating;

Reference： [1]Alonso, Maria Teresa; Brunet, Ernesto; Hernandez, Concepcion; Rodriguez-Ubis, Juan Carlos [Tetrahedron Letters, 1993, vol. 34, # 46, p. 7465 - 7468]

14
[ 41855-35-0 ]
[ 17754-90-4 ]
[ 105-58-8 ]
[ 154615-40-4 ]

Yield	Reaction Conditions	Operation in experiment
	With piperidine; potassium <i>tert</i>-butylate In ethanol Heating;

Reference： [1]Alonso, Maria Teresa; Brunet, Ernesto; Hernandez, Concepcion; Rodriguez-Ubis, Juan Carlos [Tetrahedron Letters, 1993, vol. 34, # 46, p. 7465 - 7468]

15
[ 41855-35-0 ]
[ 76427-66-2 ]

Yield	Reaction Conditions	Operation in experiment
70%	With toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid In dichloromethane at 20℃; Inert atmosphere;	4.3. Typical procedure for Bayer-Villiger oxidation General procedure: An adaptation of the previously reported procedures [9] and [10a] was used. m-Chloroperbenzoic acid (70%, 3 mmol) was added to a stirred solution of ketone 10 (1.5 mmol), TsOH (1 mmol) in dichloromethane (10 ml) in a single portion. The mixture was stirred at room temperature overnight under argon atmosphere, then filtered and the precipitate formed was washed with dichloromethane. The organic phase was washed with 10% aqueous sodium bisulfite solution (2×20 ml), a saturated aqueous NaHCO3 solution (3×20 ml), brine (2×20 ml) then dried (MgSO4) and evaporated.
65%	With peracetic acid In acetic acid at 30 - 32℃; for 5h;

Reference： [1]Location in patent: experimental part Paramonov, Sergey V.; Lokshin, Vladimir; Smolentsev, Artem B.; Glebov, Evgeni M.; Korolev, Valeri V.; Basok, Stepan S.; Lysenko, Konstantin A.; Delbaere, Stéphanie; Fedorova, Olga A. [Tetrahedron, 2012, vol. 68, # 38, p. 7873 - 7883]
[2]Wada, Fumio; Arata, Ryozo; Goto, Tokio; Kikukawa, Kiyoshi; Matsuda, Tsutomu [Bulletin of the Chemical Society of Japan, 1980, vol. 53, # 7, p. 2061 - 2063]

16
[ 41757-97-5 ]
[ 41855-35-0 ]

Yield	Reaction Conditions	Operation in experiment
	With chromium(VI) oxide; sulfuric acid In acetone Yield given;

Reference： [1]Arias; Echegoyen; Wilson; Lu; Lu [Journal of the American Chemical Society, 1995, vol. 117, # 4, p. 1422 - 1427]

17
[ 41855-35-0 ]
[ 160951-74-6 ]

Yield	Reaction Conditions	Operation in experiment
	With hydrazine hydrate In ethanol for 24h; Heating;

Reference： [1]Arias; Echegoyen; Wilson; Lu; Lu [Journal of the American Chemical Society, 1995, vol. 117, # 4, p. 1422 - 1427]

Yield	Reaction Conditions	Operation in experiment
	aus 3,4-Dihydroxy-acetophenon, CsF, entspr. Polyethylenglykolditosylat;

19
[ 41855-35-0 ]
[ 4637-24-5 ]
[ 330445-31-3 ]

Yield	Reaction Conditions	Operation in experiment
	4'-acetylbenzo-18-crown-6; <i>N</i>,<i>N</i>-dimethyl-formamide dimethyl acetal Stage #2: With hydrazine In ethanol

Reference： [1]Goodman; Bateman, Margaret A. [Tetrahedron Letters, 2001, vol. 42, # 1, p. 5 - 7]

20
[ 41855-35-0 ]
[ 75382-99-9 ]

Yield	Reaction Conditions	Operation in experiment
	Multi-step reaction with 2 steps 1: 1.) CH₃COOOH; 2.) aq. NaOH 2: NaOH