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[ CAS No. 44565-27-7 ]

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type HazMat fee
Excepted Quantity Free
Ground (Domestic only) Free
Inaccessible (Haz class 6.1), Domestic USD 41.00
Inaccessible (Haz class 6.1), International USD 64.00
Accessible (Haz class 3, 4, 5 or 8), Domestic USD 83.00
Accessible (Haz class 3, 4, 5 or 8), International USD 133.00
2D
Chemical Structure| 44565-27-7
Chemical Structure| 44565-27-7
Structure of 44565-27-7 *Storage: {[proInfo.prStorage]}

Quality Control of [ 44565-27-7 ]

Purity: {[proInfo.showProBatch.pb_purity]}

Related Doc. of [ 44565-27-7 ]

SDS

Product Details of [ 44565-27-7 ]

CAS No. :44565-27-7MDL No. :MFCD03093615
Formula :C5H13NOBoiling Point :174.682°C at 760 mmHg
Linear Structure Formula :-InChI Key :N/A
M.W :103.16Pubchem ID :10129911
Synonyms :

Computed Properties of [ 44565-27-7 ]

TPSA : - H-Bond Acceptor Count : -
XLogP3 : - H-Bond Donor Count : -
SP3 : - Rotatable Bond Count : -

Safety of [ 44565-27-7 ]

Signal Word:DangerClass3
Precautionary Statements:P501-P240-P210-P233-P243-P241-P242-P264-P280-P370 P378-P337 P313-P305 P351 P338-P303 P361 P353-P332 P313-P362-P403 P235UN#:1993
Hazard Statements:H315-H319-H226Packing Group:
GHS Pictogram:

Application In Synthesis of [ 44565-27-7 ]

  • Downstream synthetic route of [ 44565-27-7 ]

[ 44565-27-7 ] Synthesis Path-Downstream   1~10

  • 1
  • [ 13931-35-6 ]
  • [ 44565-27-7 ]
YieldReaction ConditionsOperation in experiment
74% EXAMPLE 6 3-Hydroxymethylbutylamine (VII) To a solution of 5 g of trans-3-formyl-2-enenitrile in 100 ml of methanol cooled in an ice bath and stirred with a magnetic stirrer, was added 2 g of NaBH4 over 5 minutes. After stirring for an additional 10 minutes in the ice bath, 12.6 g of CoCl2 *6H2 O was added and left to stir for 5 minutes. To the above mixture was added slowly 8.1 g of NaBH4 over a period of 15 minutes. When the addition was complete, the reaction mixture was left to stir for 2 hours before decomposing with 60 ml of 6 N hydrochloric acid. The resultant mixture was then basified with sodium hydroxide pellets to pH 12 and extracted four times with 150 ml portions of methylene chloride. The combined extracts were dried over K2 CO3 and evaporated to remove the solvent, giving 4.0 g of crude 3-hydroxymethylbutylamine (74% yield). The crude amino alcohol had an 60 Hz NMR spectrum in CDCl3 of delta0.9 (doublet, J=6 Hz, 3H), delta1.5 (multiplet, 3H), delta2.7 (multiplet, 2H), delta3.4 (doublet, J=5.5 Hz, 2H) and a D2 O exchangeable singlet at around delta3.5 (3H). The product was sufficiently pure for the synthesis of racemic dihydrozeatin by the method of Fujii et al. An additional amount (430 mg) of the crude amino alcohol product, which was less pure than that isolated above, was obtained by continuous extraction of the aqueous solution with ether or methylene chloride.
  • 4
  • [ 44565-27-7 ]
  • (R)-ethyl 6,6,6-trifluoro-5-hydroxy-3-oxo-5-phenylhexanoate [ No CAS ]
  • C19H26F3NO4 [ No CAS ]
  • C19H26F3NO4 [ No CAS ]
YieldReaction ConditionsOperation in experiment
In [D3]acetonitrile; at 25℃; for 12h; (R)-2d (premade 0.194 mmol/mL solution in CD3CN, 136.2 muL) was mixed with (±)-2d (premade 0.194 mmol/mL solution in CD3CN, 34.0 muL) at rt (25 C). To this mixture, a solution of (R)-1 (> 99% ee, 5 mg, 0.016 mmol) in 330 muL CD3CN was added and the mixture was mixed sufficiently (0 min). The mixture was transferred to a 5 mm diameter NMR tube and was analyzed by 1H NMR at the time indicated. The peaks at 0.65 ppm (d) of (R,R)-3b and 0.70 ppm (d) of (R,S)-3b were used to determine the dr.
  • 5
  • [ 44565-27-7 ]
  • [ 1415219-11-2 ]
  • 6
  • [ 44565-27-7 ]
  • 1,3-dimethyl-1-propylpyrrolidinium bromide [ No CAS ]
  • 7
  • [ 44565-27-7 ]
  • [ 45470-22-2 ]
  • 8
  • [ 44565-27-7 ]
  • 1-ethyl-1,3-dimethylpyrrolidinium bromide [ No CAS ]
  • 9
  • [ 44565-27-7 ]
  • [ 1415219-14-5 ]
  • 10
  • [ 44565-27-7 ]
  • [ 1415219-12-3 ]
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