There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.
Type | HazMat fee for 500 gram (Estimated) |
Excepted Quantity | USD 0.00 |
Limited Quantity | USD 15-60 |
Inaccessible (Haz class 6.1), Domestic | USD 80+ |
Inaccessible (Haz class 6.1), International | USD 150+ |
Accessible (Haz class 3, 4, 5 or 8), Domestic | USD 100+ |
Accessible (Haz class 3, 4, 5 or 8), International | USD 200+ |
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CAS No. : | 455-10-7 | MDL No. : | N/A |
Formula : | C9H10ClF | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | - |
M.W : | 172.63 | Pubchem ID : | - |
Synonyms : |
|
Signal Word: | Danger | Class: | 8 |
Precautionary Statements: | P260-P264-P280-P301+P310+P330+P331-P303+P361+P353+P310-P304+P340+P310-P305+P351+P338+P310-P363-P405-P501 | UN#: | 1760 |
Hazard Statements: | H314 | Packing Group: | Ⅲ |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
89% | With thionyl chloride In dichloromethane at 20℃; | INTERMEDIATE D2 Synthesis of 1-(2-chloropropan-2-yl)-4-fluorobenzene (Intermediate D2) A solution of 2-(4-fluorophenyl)-2-propanol (500 mg, 3.24 mmol) and SOCh (579 mg, 4.86 mmol) in DCM (5 mL) was stirred at room temperature overnight. The mixture was concentrated to dryness to afford crude Intermediate D2 (500 mg, 89% yield) as a colorless oil. TLC: EtO Ac/pet. ether =l/5(v/v), Rf=0.57 1H NMR: (400 MHz, DMSO-d6) d 7.68 - 7.62 (m, 2H), 7.22-7.17 (m, 2H), 1.96 (s, 6H). |
With hydrogenchloride | ||
With thionyl chloride In dichloromethane for 0.5h; |
With thionyl chloride In dichloromethane for 1h; Heating; |