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[ CAS No. 4695-14-1 ] {[proInfo.proName]}

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Chemical Structure| 4695-14-1
Chemical Structure| 4695-14-1
Structure of 4695-14-1 * Storage: {[proInfo.prStorage]}
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Product Details of [ 4695-14-1 ]

CAS No. :4695-14-1 MDL No. :MFCD00086997
Formula : C20H17NO Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W : 287.36 Pubchem ID :-
Synonyms :

Safety of [ 4695-14-1 ]

Signal Word: Class:
Precautionary Statements: UN#:
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Application In Synthesis of [ 4695-14-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 4695-14-1 ]

[ 4695-14-1 ] Synthesis Path-Downstream   1~68

  • 2
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  • [ 78906-80-6 ]
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  • 8
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  • [ 108-24-7 ]
  • <i>N</i>-acetyl-<i>N</i>-diphenylacetyl-aniline [ No CAS ]
  • 9
  • [ 525-06-4 ]
  • [ 62-53-3 ]
  • [ 4695-14-1 ]
  • 12
  • [ 36147-00-9 ]
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  • 13
  • [ 35133-13-2 ]
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  • [ 108-23-6 ]
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  • 21
  • [ 14181-84-1 ]
  • [ 650-51-1 ]
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  • [ 115264-62-5 ]
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  • [ 108661-30-9 ]
  • 22
  • [ 14181-84-1 ]
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  • [ 130716-08-4 ]
  • [ 130716-04-0 ]
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  • 25
  • [ 81838-77-9 ]
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  • 26
  • 2-Diphenylacetyl-4-methyl-6,6-diphenyl-2-aza-tricyclo[5.2.2.01,5]undeca-4,8,10-trien-3-one [ No CAS ]
  • [ 4695-14-1 ]
  • 27
  • [ 24046-81-9 ]
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  • 29
  • [ 7732-18-5 ]
  • [ 73178-71-9 ]
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  • 30
  • [ 7647-01-0 ]
  • [ 14181-84-1 ]
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  • 34
  • [ 62-53-3 ]
  • benzilide [ No CAS ]
  • [ 4695-14-1 ]
  • 35
  • diphenylacetic acid-<<i>N</i>'-phenylhydrazide [ No CAS ]
  • [ 4695-14-1 ]
  • 36
  • [ 5554-37-0 ]
  • [ 7553-56-2 ]
  • [ 64-19-7 ]
  • red phosphorus [ No CAS ]
  • [ 117-34-0 ]
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  • 37
  • [ 62-53-3 ]
  • [ 182318-00-9 ]
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  • 38
  • [ 24765-98-8 ]
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  • 39
  • [ 3469-00-9 ]
  • [ 62-53-3 ]
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  • 40
  • [ 117-34-0 ]
  • [ 62-53-3 ]
  • [ 4695-14-1 ]
YieldReaction ConditionsOperation in experiment
82% With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 20℃; for 15h;Inert atmosphere; General procedure: A solution of diphenylacetic acid (212 mg, 1.0 mmol), N-methylaniline (128 mg, 1.2mmol), DCC (247 mg, 1.2 mmol), and DMAP (24 mg, 0.2 mmol) in CH2Cl2 (1.5 mL) was stirred at room temperature for 15 h. After aqueous extractive workup and column chromatographic purification process (hexanes/Et2O,5:1) 1a was obtained as a white solid, 226 mg (75%). Other 2,2,N-triarylacetamides were prepared similarly from corresponding N-arylaminesand 2,2-diarylacetic acids. Diphenylacetic acid, bis(4-chlorophenyl)acetic acid and 9-fluorenecarboxylic acid were purchased from commercial sources, and other diarylacetic acids were prepared by Friedel-Crafts reaction of arenes and corresponding mandelic acid derivatives according to the reported methods.3,4
  • 41
  • [ 4467-90-7 ]
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  • 42
  • [ 62-53-3 ]
  • ethane-α.β-bis-sulfonic acid chloride [ No CAS ]
  • [ 4695-14-1 ]
  • 43
  • [ 117-34-0 ]
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  • 44
  • [ 4214-38-4 ]
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  • 45
  • [ 103-71-9 ]
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  • 47
  • [ 76-93-7 ]
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  • 48
  • [ 2325-27-1 ]
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  • [ 102662-36-2 ]
  • 51
  • [ 861363-82-8 ]
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  • 52
  • [ 100-63-0 ]
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  • 53
  • [ 114-83-0 ]
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  • 54
  • [ 36146-93-7 ]
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  • 55
  • [ 3839-89-2 ]
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  • 56
  • [ 2592-73-6 ]
  • [ 62-53-3 ]
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  • 57
  • [ 201230-82-2 ]
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  • [ 62-53-3 ]
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  • 58
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  • [ 119-61-9 ]
  • [ 4695-13-0 ]
  • [ 86-29-3 ]
  • [ 5267-35-6 ]
  • [ 22800-71-1 ]
  • [ 1375263-32-3 ]
  • 59
  • [ 117-34-0 ]
  • [ 4695-14-1 ]
  • C27H23NO [ No CAS ]
  • 60
  • [ 117-34-0 ]
  • [ 4695-14-1 ]
  • C23H19NO [ No CAS ]
  • 61
  • [ 4695-14-1 ]
  • [ 1922-79-8 ]
YieldReaction ConditionsOperation in experiment
57% With oxygen; In 1,2-dichloro-benzene; for 140h;Reflux; General procedure: A mixture of 1a (151 mg, 0.5 mmol) and montmorillonite K-10 (755 mg, 500%,w/w) in ODCB (2.0 mL) was heated to reflux for 14 h. The reaction mixture was filtered through a padof Celite and washed thoroughly with CH2Cl2. After removal of the volatiles and column chromatographic purification process (hexanes/Et2O, 10:1) 2a was obtained as a white solid, 132 mg (88%). Other compounds were prepared similarly, and the selected spectroscopic data of 2a-2m, 3, and 4 are as follows.
  • 62
  • C27H23NO [ No CAS ]
  • [ 4695-14-1 ]
  • [ 1922-79-8 ]
  • C27H23NO [ No CAS ]
YieldReaction ConditionsOperation in experiment
47%; 4%; 37% With oxygen; In 1,2-dichloro-benzene; for 10h;Reflux; General procedure: A mixture of 1a (151 mg, 0.5 mmol) and montmorillonite K-10 (755 mg, 500%,w/w) in ODCB (2.0 mL) was heated to reflux for 14 h. The reaction mixture was filtered through a padof Celite and washed thoroughly with CH2Cl2. After removal of the volatiles and column chromatographic purification process (hexanes/Et2O, 10:1) 2a was obtained as a white solid, 132 mg (88%). Other compounds were prepared similarly, and the selected spectroscopic data of 2a-2m, 3, and 4 are as follows.
  • 63
  • [ 758640-21-0 ]
  • [ 4695-14-1 ]
  • C27H23NO [ No CAS ]
  • 64
  • C23H21NO [ No CAS ]
  • [ 4695-14-1 ]
  • C23H19NO [ No CAS ]
YieldReaction ConditionsOperation in experiment
17%; 21% With oxygen; In 1,2-dichloro-benzene; for 38h;Reflux; General procedure: A mixture of 1a (151 mg, 0.5 mmol) and montmorillonite K-10 (755 mg, 500%,w/w) in ODCB (2.0 mL) was heated to reflux for 14 h. The reaction mixture was filtered through a padof Celite and washed thoroughly with CH2Cl2. After removal of the volatiles and column chromatographic purification process (hexanes/Et2O, 10:1) 2a was obtained as a white solid, 132 mg (88%). Other compounds were prepared similarly, and the selected spectroscopic data of 2a-2m, 3, and 4 are as follows.
  • 65
  • [ 589-09-3 ]
  • [ 4695-14-1 ]
  • C23H19NO [ No CAS ]
  • 66
  • [ 4695-14-1 ]
  • [ 5554-37-0 ]
YieldReaction ConditionsOperation in experiment
93% With potassium hydroxide; In dimethyl sulfoxide; at 80℃; for 30h;Sealed tube; (1) In a 250 ml two-necked flask were added 1.5 g of 2,2-diphenyl--N- phenyl-acetamide, 0.9 g of potassium hydroxide, 120 ml of dimethyl sulfoxide, in the air atmosphere sealed tube, and magnetic stirring at 80 C for 30 hours;After (2) The reaction was cooled to room temperature, washed with saturated brine, and extracted three times with ethyl acetate, the organic layers combined, dried over anhydrous sodium sulfate, and concentrated under reduced pressure using a rotary evaporator to remove solvent from the solution to give crude product;(3) The crude product was purified by 300-400 mesh silica gel column chromatography (volume ratio of petroleum ether: ethyl acetate = 4: 1), yielding a white solid which is 2,2-diphenyl-2-hydroxy -N - phenylacetamide, yield 93%,
  • 67
  • [ 117-34-0 ]
  • N-tert-butyl-N'-phenyl-S-phenylisothiourea [ No CAS ]
  • [ 4695-14-1 ]
  • 68
  • [ 4695-14-1 ]
  • [ 429-41-4 ]
  • tetra-N-butylammonium fluoride bis(N,2,2-triphenylacetamide) [ No CAS ]
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