Alternatived Products of [ 51385-93-4 ]
Product Details of [ 51385-93-4 ]
CAS No. : | 51385-93-4 |
MDL No. : | MFCD00453091 |
Formula : |
C13H12O3
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Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
216.23
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Pubchem ID : | - |
Synonyms : |
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Safety of [ 51385-93-4 ]
Signal Word: | |
Class: | |
Precautionary Statements: | |
UN#: | |
Hazard Statements: | |
Packing Group: | |
Application In Synthesis of [ 51385-93-4 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 51385-93-4 ]
- 1
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[ 51385-93-4 ]
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[ 17953-58-1 ]
Yield | Reaction Conditions | Operation in experiment |
|
With water; silver(l) oxide |
|
- 2
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[ 1535-67-7 ]
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[ 3469-26-9 ]
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[ 51385-93-4 ]
Yield | Reaction Conditions | Operation in experiment |
97% |
|
General procedure: In a round-bottomed flask equipped with a stirring bar and rubber septum was placed a 1 M solution of SnCl4 in anhydrous CH2Cl2 (1 mL, 1 mmol). To this solution was added PhSCF2H (1; 240.2 mg, 1.5 mmol) in anhydrous CH2Cl2 (1.5 mL), followed by a solution of an aromatic compound (0.5 mmol) in anhydrous CH2Cl2 (1 mL). The reaction was allowed to proceed for 2 h before it was quenched with a solution of IBX (140 mg, 0.5 mmol) in DMSO/H2O (4 mL; 3:1 v:v). After 2 h of stirring at rt, the reaction mixture was quenched by addition of a saturated aqueous solution of sodium thiosulfate (10 mL), then basified with a saturated aqueous solution of sodium hydrogen carbonate (10 mL), followed by stirring and extraction with CH2Cl2 (3 × 10 mL). The combined organic layers were washed with water (3 × 10 mL) and brine (10 mL), dried (anhydrous MgSO4), filtered and concentrated (aspirator). The residue was purified by PTLC, radial chromatography or column chromatography to furnish analytically pure product. |