Alternatived Products of [ 792934-46-4 ]
Product Details of [ 792934-46-4 ]
CAS No. : | 792934-46-4 |
MDL No. : | MFCD31563336 |
Formula : |
C24H20N2S2
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
400.56
|
Pubchem ID : | - |
Synonyms : |
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Safety of [ 792934-46-4 ]
Application In Synthesis of [ 792934-46-4 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 792934-46-4 ]
- 1
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[ 56290-06-3 ]
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[ 162607-23-0 ]
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[ 792934-46-4 ]
Yield | Reaction Conditions | Operation in experiment |
44% |
With tetrakis(triphenylphosphine) palladium(0); sodium carbonate In tetrahydrofuran Heating; |
|
44% |
With sodium carbonate In tetrahydrofuran Heating; |
|
|
With sodium carbonate In tetrahydrofuran; water |
1; 1 Example 1; FIG. 1
The ligand (LI) is synthesized by the Suzuki cross-coupling reactions of 2.5 equivalents of 2, 5-dimethyl-3-thienylboronic acid and 5, 6-dibromo-1, 10- phenanthroline in the presence of the palladium catalyst, Pd (PPH3) 4, and sodium carbonate in a heterogeneous mixture of water AND THE ACCORDING to the synthetic route depicted in Fig. 1. Excitation of (L1) with 313 nm light resulted in the formation of the close form, corresponding to the photocyclization product. The overlaid electronic absorption spectra of the open and close forms of (LI) in benzene solution are shown in Fig. 2. |
Reference:
[1]Yam, Vivian Wing-Wan; Ko, Chi-Chiu; Zhu, Nianyong
[Journal of the American Chemical Society, 2004, vol. 126, # 40, p. 12734 - 12735]
[2]Ko, Chi-Chiu; Kwok, Wai-Ming; Yam, Vivian Wing-Wan; Phillips, David Lee
[Chemistry - A European Journal, 2006, vol. 12, # 22, p. 5840 - 5848]
[3]Current Patent Assignee: THE UNIVERSITY OF HONG KONG - WO2005/3126, 2005, A1
Location in patent: Page 4; 1/4