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[ CAS No. 808142-89-4 ] {[proInfo.proName]}

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Chemical Structure| 808142-89-4
Chemical Structure| 808142-89-4
Structure of 808142-89-4 * Storage: {[proInfo.prStorage]}
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Product Details of [ 808142-89-4 ]

CAS No. :808142-89-4 MDL No. :
Formula : C48H36Cl2F4Ir2N4 Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W : 1200.16 Pubchem ID :-
Synonyms :

Safety of [ 808142-89-4 ]

Signal Word:Warning Class:
Precautionary Statements:P264-P280-P337+P313-P305+P351+P338-P302+P352-P332+P313-P362 UN#:
Hazard Statements:H315-H319 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 808142-89-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 808142-89-4 ]

[ 808142-89-4 ] Synthesis Path-Downstream   1~7

  • 1
  • ammonium hexafluorophosphate [ No CAS ]
  • [ 808142-89-4 ]
  • [ 72914-19-3 ]
  • [ 808142-88-3 ]
  • 2
  • iridium(III) chloride trihydrate hydrochloride [ No CAS ]
  • [ 85237-65-6 ]
  • [ 808142-89-4 ]
YieldReaction ConditionsOperation in experiment
In 2-methoxy-ethanol; water ligand added to Ir salt in methoxyethanol/H2O, refluxed for 12 h; filtered, washed (H2O and Et2O), dried;
  • 3
  • iridium(III) chloride hydrate [ No CAS ]
  • [ 85237-65-6 ]
  • [ 808142-89-4 ]
YieldReaction ConditionsOperation in experiment
In 2-methoxy-ethanol; water mixt. of 2.1 equiv. of pyridine deriv. and iridium compd. (ratio = 3:1) in 2-methoxyethanol/water heated at 125°C for 18 h; cooling, addn. of water, solid vac.-filtered, washed with water and hexane, dried under vac.;
  • 4
  • iridium(III) trichloride hydrate [ No CAS ]
  • [ 85237-65-6 ]
  • [ 808142-89-4 ]
YieldReaction ConditionsOperation in experiment
according to Lowry, M. S. et al., J. Am. Chem. Soc. 126 (2004) 14129;
  • 5
  • iridium(III) chloride trihydrate [ No CAS ]
  • [ 85237-65-6 ]
  • [ 808142-89-4 ]
YieldReaction ConditionsOperation in experiment
70% In 2-methoxy-ethanol; water for 12h; Inert atmosphere; Reflux;
  • 6
  • iridium(III) chloride n-hydrate [ No CAS ]
  • [ 85237-65-6 ]
  • [ 808142-89-4 ]
YieldReaction ConditionsOperation in experiment
In 2-methoxy-ethanol at 125℃; for 16h;
  • 7
  • iridium(III) trichloride monohydrate [ No CAS ]
  • [ 85237-65-6 ]
  • [ 808142-89-4 ]
YieldReaction ConditionsOperation in experiment
90.7% In 1,2-dimethoxyethane at 80℃; for 20h; Inert atmosphere; 1.2 2) Preparation of Intermediate II Under nitrogen protection, 28 mmol of iridium trichloride hydrate and 62 mmol of intermediate I prepared in step 1) were added to the three-necked flask, and then a mixture of ethylene glycol methyl ether and water (300 mL) was added, wherein ethyl acetate was added. The volume ratio of glycol methyl ether and water was 3:1; the mixture was heated to 80° C., refluxed for 20 hours, and a solid was precipitated.After the reaction was completed, it was cooled to room temperature, filtered, washed with water and methanol, and dried to obtain a yellow solid intermediate II for use. The yield of intermediate II was 90.7%.
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