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[ CAS No. 918870-83-4 ] {[proInfo.proName]}

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Chemical Structure| 918870-83-4
Chemical Structure| 918870-83-4
Structure of 918870-83-4 * Storage: {[proInfo.prStorage]}
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Product Details of [ 918870-83-4 ]

CAS No. :918870-83-4 MDL No. :MFCD30603197
Formula : C13H16O3 Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W : 220.26 Pubchem ID :-
Synonyms :

Safety of [ 918870-83-4 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P261-P305+P351+P338 UN#:N/A
Hazard Statements:H302-H315-H319-H335 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 918870-83-4 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 918870-83-4 ]

[ 918870-83-4 ] Synthesis Path-Downstream   1~7

YieldReaction ConditionsOperation in experiment
56% Example 9 Synthesis of Ru Complex with 4-Isopropoxy-3-vinyl-benzoic acid methyl ester (7g) The synthetic procedure is the same as in Example 3 in 0.5 mmol scale. 197 mg of green solid product was obtained (56% yield). 1H-NMR (300 MHz, CDCl3): delta=16.45 (s, 1H, Ru=CH), 8.20 (dd, J=2.2, 8.8 Hz, 1H), 7.63 (d, J=2.2 Hz, 1H), 7.09 (s, 4H), 6.84 (d, J=8.8 Hz, 1H), 4.97-4.93 (m, 1H, OCHMe2), 4.20 (s, 4H), 3.90 (s, 3H), 2.47 (s, 12H), 2.43 (s, 6H), 1.29 (d, J=6.2 Hz, 6H).
  • 2
  • [ 246047-72-3 ]
  • [ 918870-83-4 ]
  • C33H40Cl2N2O3Ru [ No CAS ]
YieldReaction ConditionsOperation in experiment
56% With copper(l) chloride; In dichloromethane; at 20℃; for 0.5h; Ru complex (H2IMES)(PCy3)Cl2Ru=CHPh (1b, 450mg, 0.5mmol) and CuCl (135 mg, 1.25mmol, 2.5 eq) were added into a round-bottom flask under an Ar and dissolved in DCM (5.0 ml), and complex ligand (6g, 0.5mmol, 1.0 eq) dissolved in DCM (1.0 ml) was added into the solution. The synthetic procedure is the same as in Example 4. 197mg of green solid product 7g was obtained after complexation and purification (yield: 56%, purity: 98%). 1HNMR (300 MHz, CDCl3): delta = 16.45 (s, 1H, Ru=CH), 8.20 (dd, J = 2.2, 8.8 Hz, 1H), 7.63 (d, J = 2.2 Hz, 1H), 7.09 (s, 4H), 6.84 (d, J = 8.8 Hz, 1H), 4.97-4.93 (m, 1H, OCHMe2), 4.20 (s, 4H), 3.90 (s, 3H), 2.47 (s,12H), 2.43 (s, 6H), 1.29 (d, J = 6.2 Hz, 6H).
  • 3
  • [ 190271-78-4 ]
  • [ 1779-49-3 ]
  • [ 918870-83-4 ]
  • 4
  • [ 918870-83-4 ]
  • [ 1312312-22-3 ]
  • 5
  • [ 918870-83-4 ]
  • [ 1312312-24-5 ]
  • 6
  • [ 918870-83-4 ]
  • (4-isopropoxy-3-vinylphenyl)methanol [ No CAS ]
  • 7
  • [ 24589-99-9 ]
  • [ 918870-83-4 ]
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