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CAS No. : | 918870-83-4 | MDL No. : | MFCD30603197 |
Formula : | C13H16O3 | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | - |
M.W : | 220.26 | Pubchem ID : | - |
Synonyms : |
|
Signal Word: | Warning | Class: | N/A |
Precautionary Statements: | P261-P305+P351+P338 | UN#: | N/A |
Hazard Statements: | H302-H315-H319-H335 | Packing Group: | N/A |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
56% | Example 9 Synthesis of Ru Complex with 4-Isopropoxy-3-vinyl-benzoic acid methyl ester (7g) The synthetic procedure is the same as in Example 3 in 0.5 mmol scale. 197 mg of green solid product was obtained (56% yield). 1H-NMR (300 MHz, CDCl3): delta=16.45 (s, 1H, Ru=CH), 8.20 (dd, J=2.2, 8.8 Hz, 1H), 7.63 (d, J=2.2 Hz, 1H), 7.09 (s, 4H), 6.84 (d, J=8.8 Hz, 1H), 4.97-4.93 (m, 1H, OCHMe2), 4.20 (s, 4H), 3.90 (s, 3H), 2.47 (s, 12H), 2.43 (s, 6H), 1.29 (d, J=6.2 Hz, 6H). |
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
56% | With copper(l) chloride; In dichloromethane; at 20℃; for 0.5h; | Ru complex (H2IMES)(PCy3)Cl2Ru=CHPh (1b, 450mg, 0.5mmol) and CuCl (135 mg, 1.25mmol, 2.5 eq) were added into a round-bottom flask under an Ar and dissolved in DCM (5.0 ml), and complex ligand (6g, 0.5mmol, 1.0 eq) dissolved in DCM (1.0 ml) was added into the solution. The synthetic procedure is the same as in Example 4. 197mg of green solid product 7g was obtained after complexation and purification (yield: 56%, purity: 98%). 1HNMR (300 MHz, CDCl3): delta = 16.45 (s, 1H, Ru=CH), 8.20 (dd, J = 2.2, 8.8 Hz, 1H), 7.63 (d, J = 2.2 Hz, 1H), 7.09 (s, 4H), 6.84 (d, J = 8.8 Hz, 1H), 4.97-4.93 (m, 1H, OCHMe2), 4.20 (s, 4H), 3.90 (s, 3H), 2.47 (s,12H), 2.43 (s, 6H), 1.29 (d, J = 6.2 Hz, 6H). |
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