Alternatived Products of [ 931-42-0 ]
Product Details of [ 931-42-0 ]
CAS No. : | 931-42-0 |
MDL No. : | MFCD20621529 |
Formula : |
C7H11Br
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Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
175.07
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Pubchem ID : | - |
Synonyms : |
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Safety of [ 931-42-0 ]
Signal Word: | |
Class: | |
Precautionary Statements: | |
UN#: | |
Hazard Statements: | |
Packing Group: | |
Application In Synthesis of [ 931-42-0 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 931-42-0 ]
- 1
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[ 931-42-0 ]
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[ 13379-98-1 ]
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[ 686273-51-8 ]
Yield | Reaction Conditions | Operation in experiment |
65% |
With caesium carbonate In N,N-dimethyl-formamide for 1.5h; |
|
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With caesium carbonate In N,N-dimethyl-formamide at 25℃; |
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Reference:
[1]Williams, Jodi T.; Bahia, Perdip S.; Kariuki, Benson M.; Spencer, Neil; Philp, Douglas; Snaith, John S.
[Journal of Organic Chemistry, 2006, vol. 71, # 6, p. 2460 - 2471]
[2]Williams, Jodi T.; Bahia, Perdip Singh; Snaith, John S.
[Organic Letters, 2002, vol. 4, # 21, p. 3727 - 3730]
- 2
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[ 6153-05-5 ]
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[ 931-42-0 ]
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[ 1001653-25-3 ]
Yield | Reaction Conditions | Operation in experiment |
70% |
With tetra-(n-butyl)ammonium iodide; sodium hydride In tetrahydrofuran at 20℃; |
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70% |
Stage #1: (Z)-3-methylpent-2-en-4-ynol With sodium hydride In tetrahydrofuran; mineral oil at 20℃;
Stage #2: (2-bromoethylidene)cyclopentane With tetra-(n-butyl)ammonium iodide In tetrahydrofuran; mineral oil at 20℃; |
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Reference:
[1]Istrate, Florin M.; Gagosz, Fabien L.
[Journal of Organic Chemistry, 2008, vol. 73, # 2, p. 730 - 733]
[2]Istrate, Florin M.; Gagosz, Fabien
[Beilstein Journal of Organic Chemistry, 2011, vol. 7, p. 878 - 885]
- 3
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[ 1903-22-6 ]
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[ 931-42-0 ]
Yield | Reaction Conditions | Operation in experiment |
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Multi-step reaction with 2 steps
1.1: diisobutylaluminium hydride / chloroform / 3 h / -78 - 20 °C
1.2: 20 °C
2.1: phosphorus tribromide; pyridine / hexane / 3 h / 20 °C / Cooling with ice |
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Multi-step reaction with 2 steps
1: diisobutylaluminium hydride / tetrahydrofuran / 4 h / -78 °C
2: phosphorus tribromide / diethyl ether / 0 °C / Darkness; Inert atmosphere |
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Reference:
[1]Comito, Robert J.; Finelli, Fernanda G.; Macmillan, David W. C.
[Journal of the American Chemical Society, 2013, vol. 135, # 25, p. 9358 - 9361]
[2]Liu, Feng; Liu, Jia-Li; tu, Jia-Lin
[Organic Letters, 2020, vol. 22, # 18, p. 7369 - 7372]
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