There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.
Type | HazMat fee for 500 gram (Estimated) |
Excepted Quantity | USD 0.00 |
Limited Quantity | USD 15-60 |
Inaccessible (Haz class 6.1), Domestic | USD 80+ |
Inaccessible (Haz class 6.1), International | USD 150+ |
Accessible (Haz class 3, 4, 5 or 8), Domestic | USD 100+ |
Accessible (Haz class 3, 4, 5 or 8), International | USD 200+ |
Purity | Size | Price | VIP Price | USA Stock *0-1 Day | Global Stock *5-7 Days | Quantity | |||||
{[ item.p_purity ]} | {[ item.pr_size ]} |
{[ getRatePrice(item.pr_usd, 1,1) ]} {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate) ]} |
{[ getRatePrice(item.pr_usd, 1,1) ]} | Inquiry {[ getRatePrice(item.pr_usd,item.pr_rate,item.mem_rate) ]} {[ getRatePrice(item.pr_usd,1,item.mem_rate) ]} | {[ item.pr_usastock ]} | Inquiry - | {[ item.pr_chinastock ]} | Inquiry - |
* Storage: {[proInfo.prStorage]}
CAS No. : | 952727-77-4 | MDL No. : | MFCD04114807 |
Formula : | C15H11Cl2NO2S | Boiling Point : | - |
Linear Structure Formula : | - | InChI Key : | - |
M.W : | 340.22 | Pubchem ID : | - |
Synonyms : |
|
Signal Word: | Danger | Class: | 6.1 |
Precautionary Statements: | P261-P264-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P310-P330-P332+P313-P337+P313-P361-P403+P233-P405-P501 | UN#: | 2811 |
Hazard Statements: | H301-H311-H315-H319-H331-H335 | Packing Group: | Ⅲ |
GHS Pictogram: |
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
Yield | Reaction Conditions | Operation in experiment |
---|---|---|
2% | To a solution of 1 //-pyrrolol 2,3-61 pyridi ne-4-carbaldehyde (42 mg; 0.289 mmol) in tetrahydrofuran (2 mL) was added cyclohexanamine (0.067 mL; 0.600 mmol) and the resulting solution was stirred at 25 Cfor 210 minutes. Then,2,4-dichloro-l-(isocyano(tosyl)methyl)benzene (81 mg; 0.240 mmol), CS2CO3 (117 mg; 0,360 mmol) and boron trifluoride diethyl etherate (0.088 mL; 0.720 mmol) were added. The resulting mixture was stirred at 60 C for 16 hours and then at 70 Cfor additional 7 hours. The solvent was evaporated in vacuo and The residue obtained after the workup was purified by column chromatography (hexane/acetone, 1 : 1) and then by preparative TLC (dichlorome thane/ethyl acetate, 1 :4). The product was obtained as a colorless wax (2 mg, 2 %). (0130) NMR (500 MHz, CDC13) d (ppm) 9.96 (s, 1H), 8.30 (d, / = 5.04 Hz, 1H), 8.27 (s, 1H), 7.34 (d, / = 3.55 Hz, 1H), 7.29 (d, / = 2.11 Hz, 1H), 7.23 (d, / = 8.31 Hz, 1H), 7.10 (dd, / = 8.33, 2.13 Hz, 1H), 6.95 (d, / = 4.99 Hz, 1H), 6.18 (d, / = 3.58 Hz, 1H), 3.94 (tt, / = 11.92, 3.68 Hz, 1H), 2.11 - 2.00 (m, 2H), 1.86 - 1.65 (m, 5H), 1.24 - 1.09 (m, 3H). (0131) 13C NMR (126 MHz, CDC13) d (ppm) 147.5, 141.5, 135.2, 134.9, 134.6, 133.0, 130.9, 130.2, 129.9, 127.2, 127.0, 120.8, 117.4, 100.4, 56.6, 35.3, 34.3, 25.7, 25.7, 25.1. |