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Chemical Structure| 1569-01-3 Chemical Structure| 1569-01-3

Structure of 1569-01-3

Chemical Structure| 1569-01-3

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Product Details of [ 1569-01-3 ]

CAS No. :1569-01-3
Formula : C6H14O2
M.W : 118.17
SMILES Code : CC(O)COCCC
English Name :1-Propoxy-2-propanol
MDL No. :MFCD00192420
InChI Key :FENFUOGYJVOCRY-UHFFFAOYSA-N
Pubchem ID :15286

Safety of [ 1569-01-3 ]

Application In Synthesis of [ 1569-01-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1569-01-3 ]

[ 1569-01-3 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 57-55-6 ]
  • [ CAS Unavailable ]
  • [ 106-36-5 ]
  • [ CAS Unavailable ]
  • [ 10215-30-2 ]
  • [ 1569-01-3 ]
  • [ 79-09-4 ]
  • [ 108-67-8 ]
YieldReaction ConditionsOperation in experiment
With [C6H3-2,6-(OP(tBu)2)2]IrH2; trifluorormethanesulfonic acid; hydrogen In 1,4-dioxane at 125℃; Autoclave; 11 Hydrogenation of 1,2 Propanediol. Reactions containing no water and/or more than 0.25 equivalents of triflic acid gave poor selectivity toward the n-alcohol and yielded up to fifteen distinct products which were identified by 1H NMR spectroscopy and/or GC/MS. Several of these products along with pathways that have been proposed for their generation are shown in Scheme 1. In addition to compounds shown in Scheme 1, dipropylene glycol, dipropyl ether, and isopropyl ether were also identified and reasonably result from condensation of the respective alcohols. In addition, some decomposition of the dioxane solvent was observed leading to the generation of ethanol and ethylene glycol, which were not observed in the absence of dioxane. With the exception of propane, isomers of 2,5- and 2,6-dimethyldioxane, and dipropoxypropane, which were observed by NMR spectroscopy and/or GC-MS, all major byproducts were quantified using a GC assay method developed and verified with authentic samples. The product profiles obtained under each set of reaction conditions were characterized by NMR spectroscopy, and GC-MS and/or comparison to authentic compounds prepared by independent synthesis.
 

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