Chemistry Organic Building Blocks Iodides

Iodides

Organic compounds that possess at least one carbon-iodine bond are known as organoiodine compounds. While these compounds are prevalent in organic chemistry, they are comparatively uncommon in the natural world.

The carbon-halogen bonds exhibit varying strengths, with the C-I bond being the least strong. This trend in bond strength aligns with the halogens' electronegativity, with bond strength decreasing in the order F > Cl > Br > I.

Of the halides, iodide usually is the best leaving group. Because of the weakness of the C–I bond, samples of organoiodine compounds are often yellow due to an impurity of I-.

The preparation of organoiodine compounds can vary depending on the desired degree and regiochemistry of iodination, as well as the characteristics of the precursor materials. When working with unsaturated substrates, direct iodination with I2 is a commonly used method among numerous routes available.

The high atomic weight of iodine results in the notable characteristic of organoiodine compounds - their high density.

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By Key Group+−

1-lodobutane 1-lodobutane benziodoxol diiodo diiodobenzene diiodobenzoate diiodobenzoic diiodophenol diiodophenoxy diiodopyridine diphenyliodonium fluoro-iodo-nitro-benzene fluoroiodobenzene iodo-benzofuran iodo-fluorene iodo-indazol-amine iodo-indazole iodo-indazole-carboxylate iodo-indole iodo-isoquinoline iodo-methyl-pyrazole iodo-pyrazole-carboxylate iodo-pyrazolopyridine iodo-pyrrolopyridine iodo-pyrrolopyridine-carboxylate iodo-pyrrolopyrimidine iodo-trifluoromethyl-pyridine iodoacetate iodoaniline iodoanisole iodobenzaldehyde iodobenzamide iodobenzene iodobenzo iodobenzoate iodobenzoic iodobenzonitrile iodobenzotrifluoride iodobenzoyl iodobenzyl iodobiphenyl iodobutane iodobutanoate iododibenzo iodoethane iodoethoxy iodoethyl iodohexane iodoimidazo iodoisobenzofuran iodomethyl iodomethyl-imidazole iodomethyl-indazole iodonaphthalene iodonicotinaldehyde iodonicotinate iodonicotinic iodonicotinonitrile iodonitrobenzene iodophenol iodophenoxy iodopicolinic iodopropane iodopropanoate iodopropyl iodopyrazine iodopyrazolo iodopyridine iodopyrimidine iodoquinazoline iodoquinoline iodotetrahydrofuran iodothieno iodothiophene iodotoluene triiodobenzene triiodobenzoic

By Parent Nucleus+−

Aliphatic Heterocycles Aromatic Heterocycles Azetidines Benzimidazoles Benzofurans Benzothiazoles Carbazoles Dioxolanes Imidazoles Indazoles Indoles Indolines Isoquinolines Isoxazoles Morpholines Other Aliphatic Heterocycles Other Aromatic Heterocycles Oxazolidines Oxetanes Piperidines Pyrazines Pyrazoles Pyridazines Pyridines Pyrimidines Pyrroles Pyrrolidines Quinazolines Quinolines Quinoxalines Spiroes Tetrahydropyrans Thiadiazoles Thiazoles Triazoles

By Functional Group+−

Alcohols Aldehydes Aliphatic Chain Hydrocarbons Aliphatic Cyclic Hydrocarbons Alkenyls Alkyls Alkynyls Amides Amines Aryls Benzyl bromides Benzyl Chlorides Bromides Carboxylic Acid Salts Carboxylic Acids Chiral Building Blocks Chlorides Difluoromethyls Esters Ethers Fluorinated Building Blocks Hydrazines Ketones Nitriles Nitroes Organoboron Phenols Sulfamides Sulfides Sulfones Sulfonic Acids Thiophenes Trifluoromethyls

Framework+−

(2-iodophenyl)(phenyl)methanone (2-iodophenyl)methanol (3-iodophenyl)boronic acid (3-iodophenyl)methanol 1,2-benziodoxol-3-(1H)-one 1,2-difluoro-3-iodobenzene 1,2-diiodobenzene 1,3-dibromo-2-iodobenzene 1,3-dichloro-2-iodobenzene 1,3-difluoro-2-iodobenzene 1,3-diiodo-2-phenoxybenzene 1,3-diiodobenzene 1,4-dibromo-2-iodobenzene 1,4-difluoro-2-iodobenzene 1-(2-iodophenyl)ethan-1-one 1-(3-iodophenyl)ethan-1-one 1-(benzyloxy)-4-iodobenzene 1-(bromomethyl)-2-iodobenzene 1-benzyl-4-iodo-1H-pyrazole 1-bromo-2-iodobenzene 1-bromo-3-fluoro-2-iodobenzene 1-bromo-3-iodobenzene 1-bromo-4-iodobenzene 1-chloro-2-fluoro-3-iodobenzene 1-chloro-2-iodobenzene 1-chloro-3-iodo-2-methylbenzene 1-chloro-3-iodobenzene 1-chloro-4-iodobenzene 1-ethyl-2-iodobenzene 1-fluoro-2-iodo-4-methylbenzene 1-fluoro-2-iodobenzene 1-fluoro-3-iodo-2-methylbenzene 1-fluoro-3-iodobenzene 1-fluoro-4-iodobenzene 1-iodo-2,3-dimethylbenzene 1-iodo-2,4-dimethylbenzene 1-iodo-2-(trifluoromethoxy)benzene 1-iodo-2-(trifluoromethyl)benzene 1-iodo-2-isopropylbenzene 1-iodo-2-methoxybenzene 1-iodo-2-methylbenzene 1-iodo-2-nitrobenzene 1-iodo-3-(trifluoromethoxy)benzene 1-iodo-3-(trifluoromethyl)benzene 1-iodo-3-methoxybenzene 1-iodo-3-methylbenzene 1-iodo-3-nitrobenzene 1-iodo-4-methoxybenzene 1-iodo-4-phenoxybenzene 2,4-difluoro-1-iodobenzene 2,6-dichloro-4-iodopyridine 2,6-diiodoaniline 2,6-diiodophenol 2-bromo-3-iodopyridine 2-bromo-4-chloro-1-iodobenzene 2-bromo-6-iodoaniline 2-bromo-6-iodopyridine 2-chloro-3-iodopyridin-4-amine 2-chloro-3-iodopyridine 2-chloro-4-iodopyridine 2-chloro-5-iodopyridine 2-chloro-6-iodophenol 2-chloro-6-iodopyridine 2-fluoro-1-iodo-4-methylbenzene 2-fluoro-3-iodopyridine 2-fluoro-6-iodoaniline 2-hydroxy-3-iodobenzaldehyde 2-iodo-1,3-dimethylbenzene 2-iodo-1,4-dimethylbenzene 2-iodo-1-methyl-4-nitrobenzene 2-iodo-4-methylaniline 2-iodo-6-methylpyridine 2-iodo-6-nitroaniline 2-iodo-9H-fluorene 2-iodo-N,N-dimethylaniline 2-iodoaniline 2-iodobenzaldehyde 2-iodobenzamide 2-iodobenzene-1,3-diol 2-iodobenzoic acid 2-iodobenzonitrile 2-iodonaphthalene 2-iodophenol 2-iodopyrazine 2-iodopyridine 2-iodopyrimidine 2-iodothiophene 3-chloro-2-iodoaniline 3-chloro-4-iodoaniline 3-fluoro-2-iodoaniline 3-iodo-1-methyl-1H-pyrazole 3-iodo-1H-pyrrolo[2,3-b]pyridine 3-iodo-1H-pyrrolo[3,2-b]pyridine 3-iodo-2-methylaniline 3-iodoaniline 3-iodobenzaldehyde 3-iodobenzoic acid 3-iodobenzonitrile 3-iodoimidazo[1,2-a]pyridine 3-iodophenol 3-iodopyridazine 3-iodopyridin-2-amine 3-iodopyridin-2-ol 3-iodopyridin-4-amine 3-iodopyridin-4-ol 3-iodopyridine 3-iodotetrahydrofuran 4-bromo-2-chloro-1-iodobenzene 4-bromo-2-fluoro-1-iodobenzene 4-bromo-2-iodoaniline 4-chloro-2-iodoaniline 4-chloro-3-iodoaniline 4-chloro-5-iodopyrimidine 4-fluoro-2-iodoaniline 4-fluoro-3-iodobenzoic acid 4-iodo-1,1'-biphenyl 4-iodo-1H-pyrazole 4-iodo-N,N-diphenylaniline 4-iodopyridine 4-iodopyrimidine 5-bromo-2-iodopyridine 5-iodo-1H-imidazole 5-iodo-1H-pyrazole 5-iodo-7H-pyrrolo[2,3-d]pyrimidine 5-iodopyridin-2-amine 5-iodopyridin-2-ol 5-iodopyrimidine 6-chloro-5-iodopyridin-2-amine ethyl 2-iodobenzoate ethyl 3-iodobenzoate methyl 2-iodobenzoate methyl 3-iodo-4-methylbenzoate methyl 3-iodobenzoate methyl 4-amino-3-iodobenzoate N-(2-iodophenyl)acetamide phenyl(o-tolyl)iodonium tert-butyl 3-iodo-1H-indole-1-carboxylate

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