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Chemical Structure| 872575-06-9 Chemical Structure| 872575-06-9

Structure of 872575-06-9

Chemical Structure| 872575-06-9

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Product Details of [ 872575-06-9 ]

CAS No. :872575-06-9
Formula : C14H30O3Si
M.W : 274.47
SMILES Code : CO[Si](OC)(CCCCCCCCCC=C)OC
English Name :Trimethoxy(undec-10-en-1-yl)silane

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Application In Synthesis of [ 872575-06-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 872575-06-9 ]

[ 872575-06-9 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 681-84-5 ]
  • [ 872-17-3 ]
  • [ 872575-06-9 ]
YieldReaction ConditionsOperation in experiment
95 % Stage #1: 11-chloroundec-1-ene With magnesium In tetrahydrofuran Inert atmosphere; Reflux; Stage #2: Tetramethoxysilan In tetrahydrofuran at -78 - 20℃; 1.4-1.5 Take by weighing 5.76g (0.24mol) of magnesium powder and place it in a three-necked flask, under the protection of nitrogen, add dropwise a tetrahydrofuran solution of 37.6g (0.2mol) of 11-chloro-1-undecene (initial , heat slightly to complete the initiation), and finally heat to reflux for 3 hours to complete the preparation of the Grignard reagent. Take a 1000mL three-neck flask, add 74mL (0.5mol) of tetramethyl silicate and 200mL tetrahydrofuran, cool to -78°C; then add the prepared Grignard reagent dropwise, react for another 30 minutes, slowly warm up to room temperature, and stir overnight . Post-treatment: Rotary evaporation to remove most of the solvent, and then vacuum distillation to obtain 51.2 g of the target product A-1, with a yield of 95%.
 

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