Home Cart 0 Sign in  

[ CAS No. 1004761-68-5 ]

{[proInfo.proName]} ,{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]}
Chemical Structure| 1004761-68-5
Chemical Structure| 1004761-68-5
Structure of 1004761-68-5 * Storage: {[proInfo.prStorage]}

Quality Control of [ 1004761-68-5 ]

Related Doc. of [ 1004761-68-5 ]

SDS
Alternatived Products of [ 1004761-68-5 ]
Alternatived Products of [ 1004761-68-5 ]

Product Details of [ 1004761-68-5 ]

CAS No. :1004761-68-5 MDL No. :MFCD18837628
Formula : C14H22BNO2 Boiling Point : -
Linear Structure Formula :- InChI Key :N/A
M.W :247.14 g/mol Pubchem ID :-
Synonyms :

Safety of [ 1004761-68-5 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P261-P305+P351+P338 UN#:N/A
Hazard Statements:H302-H315-H319-H335 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 1004761-68-5 ]

  • Upstream synthesis route of [ 1004761-68-5 ]
  • Downstream synthetic route of [ 1004761-68-5 ]

[ 1004761-68-5 ] Synthesis Path-Upstream   1~1

  • 1
  • [ 1004761-68-5 ]
  • [ 24596-19-8 ]
  • [ 54827-17-7 ]
YieldReaction ConditionsOperation in experiment
210 g With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; caesium carbonate In 1,4-dioxane at 75℃; for 16 h; Inert atmosphere 2) 250 g of 2,6-dimethylaniline (5) and3L N, N- dimethylformamide solution was added to 5L three reaction flask,1 L of 246 g N-bromosuccinimide was slowly added dropwise at about 0 ° CN, N-dimethylformamide, and the mixture was stirred at room temperature for 2 hours.The reaction mixture was introduced into 30 L of water, extracted with 3 L of ethyl acetate twice,The organic phase was washed with 2 L saturated brine, dried over anhydrous sodium sulfate, filtered,Dried to afford 350 g of 2,6-dimethyl-4-bromoaniline (6) as a yellow solid.Next, 350 g of the product (6), 268 g of potassium acetate,364 g of bis (pinacolato) diboron, 50 g[1,1'-bis (diphenylphosphino) ferrocene] palladium dichloride,4L1,4 - dioxane, 400mL water was added 5L three-necked flask, nitrogen protection,Heated to 80 stirring continued 15h. After falling to room temperature, filtration,Dried to give 414g brown solid boric acid ester (7);332 g of product (6),414 g product (7) 667 g cesium carbonate,50 g of [1,1'-bis (diphenylphosphino) ferrocene] palladium dichloride,4L 1,4-dioxane was added 5L three-necked flask, a nitrogen atmosphere,Heat to 75 ° C and continue stirring for 16h. After falling to room temperature, filtration,The filtrate was washed with 2 L of water, dried over anhydrous sodium sulfate, filtered and spun dry.Recrystallized from 2 L ethyl acetate: petroleum ether = 1: 4 (volume ratio) solution,The solid was filtered off to give 210 g of white crystals2,2 ', 6,6'-tetramethylbiphenylenediamine(8).
Reference: [1] Patent: CN106810506, 2017, A, . Location in patent: Paragraph 0039
Historical Records

Related Functional Groups of
[ 1004761-68-5 ]

Organoboron

Chemical Structure| 590418-05-6

[ 590418-05-6 ]

2-Methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Similarity: 1.00

Chemical Structure| 850689-28-0

[ 850689-28-0 ]

2-Methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Similarity: 0.96

Chemical Structure| 1339927-45-5

[ 1339927-45-5 ]

(2-Amino-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)methanol

Similarity: 0.95

Chemical Structure| 590418-05-6

[ 590418-05-6 ]

2-Methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Similarity: 1.00

Chemical Structure| 850689-28-0

[ 850689-28-0 ]

2-Methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Similarity: 0.96

Amines

Chemical Structure| 590418-05-6

[ 590418-05-6 ]

2-Methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Similarity: 1.00

Chemical Structure| 850689-28-0

[ 850689-28-0 ]

2-Methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Similarity: 0.96

Chemical Structure| 1339927-45-5

[ 1339927-45-5 ]

(2-Amino-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)methanol

Similarity: 0.95

Chemical Structure| 590418-05-6

[ 590418-05-6 ]

2-Methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Similarity: 1.00

Chemical Structure| 850689-28-0

[ 850689-28-0 ]

2-Methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Similarity: 0.96

Aryls

Chemical Structure| 590418-05-6

[ 590418-05-6 ]

2-Methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Similarity: 1.00

Chemical Structure| 850689-28-0

[ 850689-28-0 ]

2-Methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Similarity: 0.96

Chemical Structure| 1339927-45-5

[ 1339927-45-5 ]

(2-Amino-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)methanol

Similarity: 0.95

Chemical Structure| 590418-05-6

[ 590418-05-6 ]

2-Methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Similarity: 1.00

Chemical Structure| 850689-28-0

[ 850689-28-0 ]

2-Methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Similarity: 0.96

Organoboron

Chemical Structure| 590418-05-6

[ 590418-05-6 ]

2-Methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Similarity: 1.00

Chemical Structure| 850689-28-0

[ 850689-28-0 ]

2-Methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Similarity: 0.96

Chemical Structure| 1339927-45-5

[ 1339927-45-5 ]

(2-Amino-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)methanol

Similarity: 0.95

Chemical Structure| 590418-05-6

[ 590418-05-6 ]

2-Methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Similarity: 1.00

Chemical Structure| 850689-28-0

[ 850689-28-0 ]

2-Methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Similarity: 0.96

Esters

Chemical Structure| 590418-05-6

[ 590418-05-6 ]

2-Methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Similarity: 1.00

Chemical Structure| 850689-28-0

[ 850689-28-0 ]

2-Methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Similarity: 0.96

Chemical Structure| 1339927-45-5

[ 1339927-45-5 ]

(2-Amino-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl)methanol

Similarity: 0.95

Chemical Structure| 590418-05-6

[ 590418-05-6 ]

2-Methyl-4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Similarity: 1.00

Chemical Structure| 850689-28-0

[ 850689-28-0 ]

2-Methyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)aniline

Similarity: 0.96