[ CAS No. 106-90-1 ] {[proInfo.proName]}

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Structure of 106-90-1 * Storage: {[proInfo.prStorage]}

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Quality Control of [ 106-90-1 ]

COA NMR CNMR HPLC LC-MS

Related Doc. of [ 106-90-1 ]

SDS Specification

Alternatived Products of [ 106-90-1 ]

Product Details of [ 106-90-1 ]

CAS No. :	106-90-1	MDL No. :	MFCD00005138
Formula :	C₆H₈O₃	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	RPQRDASANLAFCM-UHFFFAOYSA-N
M.W :	128.13	Pubchem ID :	7836
Synonyms :

Safety of [ 106-90-1 ]

Signal Word:	Danger	Class:	6.1,3
Precautionary Statements:	P501-P261-P270-P262-P240-P210-P233-P243-P241-P242-P271-P264-P280-P272-P370+P378-P303+P361+P353-P333+P313-P301+P330+P331-P362-P301+P310+P330-P302+P350+P310-P304+P340+P310-P305+P351+P338+P310-P403+P233-P403+P235-P405	UN#:	2929
Hazard Statements:	H310-H301+H331-H314-H317-H225	Packing Group:	Ⅱ
GHS Pictogram:

Application In Synthesis of [ 106-90-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 106-90-1 ]

[ 106-90-1 ] Synthesis Path-Downstream 1~4

1
[ CAS Unavailable ]
[ 9067-32-7 ]
[ CAS Unavailable ]

Yield	Reaction Conditions	Operation in experiment
	With tetrabutylammomium bromide; triethylamine In water at 20 - 60℃; for 25h;	1.III 1% Hy was reacted with a 20-fold molar excess of glycidyl acrylate and equal amounts of triethylamine and tetrabutylammonium bromide in water for 24 hours at room temperature. The reaction was continued at 60° C. for 1 hour. After the reaction, the solution was precipitated in acetone, dissolved in DI water precipitated a second time in acetone, and dissolved again in DI water to remove excess reactants. The GAHy solution was lyophilized and stored.

Reference： [1]Current Patent Assignee: DENTSPLY SIRONA INC - US2007/269518, 2007, A1 Location in patent: Page/Page column 5

2
[ 106-90-1 ]
6-chlorotoluene-2-diazonium chloride [ No CAS ]
[ 87-63-8 ]
α-chloro-β-(3-chloro-o-tolyl)2,3-epoxypropyl propionate [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
70%	With acetic acid; sodium nitrite;copper(l) chloride; In hydrogenchloride; water; acetone;	EXAMPLE 16 Preparation of alpha-chloro-beta-(3-chloro-o-tolyl)2,3-epoxypropyl propionate. 141.5 g of 6-chloro-o-toluidine are slowly added with agitation to a mixture of 200 ml of concentrated HCl and 2.0 ml of acetic acid in a 3-liter reactor. The hydrochloride solution thus formed is cooled to 0 C., and 150 ml of an aqueous solution containing 74 g of NaNO2 are added drop by drop over a period of 15 minutes. After filtering the 6-chlorotoluene-2-diazonium chloride solution is added to a mixture of 170 ml of glycidyl acrylate and 240 ml of acetone; whereafter a solution of 6 g of CuCl in 60 ml of HCl is added at a temperature of 25 C. over a period of 2 hours. The evolution of nitrogen ceases completely after 2 hours reaction time at 25 C. The alpha-chloro-beta-(3-chloro-o-tolyl)propionate of 2,3-epoxypropyl is extracted in ether and the ethereal extract is washed in water. After drying on CaCl2 and removal of the solvent the residue is distilled at low pressure. 200 g, corresponding to a 70% yield, of an oil distilling between 195 and 200 C. at 0.1 mm Hg are obtained. Analysis: % Cl found: 28 % Cl calculated: 27

Reference： [1]Patent: US4145362,1979,A

3
[ 106-90-1 ]
[ 496-46-8 ]
C₂₈H₃₈N₄O₁₄ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
	at 50℃;	10 mol of <strong>[496-46-8]glycoluril</strong> (Sigma-Aldrich) was diluted in propylene glycol monomethyl ether acetate. While the solution was maintained at 50 C., a solution obtained by diluting 40 mol of glycidyl acrylate (Sigma-Aldrich) in the same solvent was slowly added thereto to allow the mixture to react. The obtained solution was separated through a column, and then the solvent was removed by using vacuum distillation, thereby obtaining a compound represented by [Formula 11]. The procedure was repeated to prepare a sufficient amount of the compound of [Formula 11]. (0093) (0094) The structure was confirmed through 1H-NMR. 5.80, 6.05, 6.43 (-CH=CH2), 3.43, 4.28, 4.43, 4.44 (aliphatic H), 2.0 (-OH)

Reference： [1]Patent: US8828644,2014,B2 .Location in patent: Page/Page column 11; 12

4
[ 106-90-1 ]
[ 21850-57-7 ]
[ 3524-68-3 ]
C₄₄H₆₂O₁₅ [ No CAS ]

Yield	Reaction Conditions	Operation in experiment
		weight 30g of methyl eleostearate D-A reaction product in a three-necked flask, and added 0.275g hydroquinone, place in the oil bath and install the stirring device, set the speed to 200r/min. Warming up to 60 C, weigh 0.825 g of N, N-dimethylethanolamine, stir well and heat to 80 C, and then 23 g of <strong>[3524-68-3]pentaerythritol triacrylate</strong> was slowly dropped into the three-necked flask, drip within 5 minutes, continue to heat up to 120 C, after 4 hours of reaction the absorption peak of the anhydride at 1849 and 1778 cm-1 disappeared in the infrared spectrum. cool down to 60 C, added 0.320 g of hydroquinone and 0.320 g of N, N-dimethylethanolamine, 20 minutes of incubation and then the temperature rose to 80 C and added 11g of glycidyl acrylate, continue to heat up at 100 C and continue to react for 4h, until the acid value of the reaction system is lower than 3mgK0H/g, after the reaction is over, adjust the pH at 7.0 using a 10 wt. % sodium carbonate solution, and then transferred to a separatory funnel, washed with saturated brine and allowed to separate layers and separate the lower layer. And then dissolved the product in dichloromethane, and then wash with hot deionized water, at this point, the water is found in the upper layer and the product is in the lower layer, continue to wash 5 times with water. Finally, add an appropriate amount of anhydrous sodium sulfate to fully dry and remove water, use a rotary evaporator to remove methylene chloride, obtained Tung Oil-Based Multifunctional UV Curing Active Monomer.

Reference： [1]Patent: CN108689853,2018,A .Location in patent: Paragraph 0029-0031

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P101	If medical advice is needed,have product container or label at hand.
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P285	In case of inadequate ventilation wear respiratory protection.
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Code	Phrase
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P311	Call a POISON CENTER or doctor/physician.
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P320
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P321
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P337	If eye irritation persists:
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P342	If experiencing respiratory symptoms:
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P361	Remove/Take off immediately all contaminated clothing.
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P378
P380	Evacuate area.
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P390	Absorb spillage to prevent material damage.
P391	Collect spillage. Hazardous to the aquatic environment
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P301 + P312	IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
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P302 + P334	IF ON SKIN: Immerse in cool water/wrap in wet bandages.
P302 + P350	IF ON SKIN: Gently wash with plenty of soap and water.
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P304 + P312	IF INHALED: Call a POISON CENTER or doctor/physician if you feel unwell.
P304 + P340	IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P304 + P341	IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
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P308 + P313	IF exposed or concerned: Get medical advice/attention.
P309 + P311	IF exposed or if you feel unwell: call a POISON CENTER or doctor/physician.
P332 + P313	IF SKIN irritation occurs: Get medical advice/attention.
P333 + P313	IF SKIN irritation or rash occurs: Get medical advice/attention.
P335 + P334	Brush off loose particles from skin. Immerse in cool water/wrap in wet bandages.
P337 + P313	IF eye irritation persists: Get medical advice/attention.
P342 + P311	IF experiencing respiratory symptoms: call a POISON CENTER or doctor/physician.
P370 + P376	In case of fire: Stop leak if safe to Do so.
P370 + P378	In case of fire:
P370 + P380	In case of fire: Evacuate area.
P370 + P380 + P375	In case of fire: Evacuate area. Fight fire remotely due to the risk of explosion.
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P401
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P413
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P403 + P233	Store in a well-ventilated place. Keep container tightly closed.
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H201	Explosive; mass explosion hazard
H202	Explosive; severe projection hazard
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H221	Flammable gas
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H230	May react explosively even in the absence of air
H231	May react explosively even in the absence of air at elevated pressure and/or temperature
H240	Heating may cause an explosion
H241	Heating may cause a fire or explosion
H242	Heating may cause a fire
H250	Catches fire spontaneously if exposed to air
H251	Self-heating; may catch fire
H252	Self-heating in large quantities; may catch fire
H260	In contact with water releases flammable gases which may ignite spontaneously
H261	In contact with water releases flammable gas
H270	May cause or intensify fire; oxidizer
H271	May cause fire or explosion; strong oxidizer
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H301	Toxic if swallowed
H302	Harmful if swallowed
H303	May be harmful if swallowed
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H305	May be harmful if swallowed and enters airways
H310	Fatal in contact with skin
H311	Toxic in contact with skin
H312	Harmful in contact with skin
H313	May be harmful in contact with skin
H314	Causes severe skin burns and eye damage
H315	Causes skin irritation
H316	Causes mild skin irritation
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H320	Causes eye irritation
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H371	May cause damage to organs
H372	Causes damage to organs through prolonged or repeated exposure
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Code	Phrase
H400	Very toxic to aquatic life
H401	Toxic to aquatic life
H402	Harmful to aquatic life
H410	Very toxic to aquatic life with long-lasting effects
H411	Toxic to aquatic life with long-lasting effects
H412	Harmful to aquatic life with long-lasting effects
H413	May cause long-lasting harmful effects to aquatic life
H420	Harms public health and the environment by destroying ozone in the upper atmosphere

[ CAS No. 106-90-1 ] {[proInfo.proName]}

Quality Control of [ 106-90-1 ]

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Product Details of [ 106-90-1 ]

Safety of [ 106-90-1 ]

Application In Synthesis of [ 106-90-1 ]

[ 106-90-1 ] Synthesis Path-Downstream 1~4

Precautionary Statements-General

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