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Chemical Structure| 1160861-53-9 Chemical Structure| 1160861-53-9
Chemical Structure| 1160861-53-9

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Kayla R. Storme ; Benedikt S. Schreib ; Zachary P. Smith ; Timothy M. Swager ;

Abstract: We report a scalable synthesis of high-molecular-weight poly(arylene ether)s (PAEs) using decafluorobiphenyl under SNAr reaction conditions and the preparation of enantiopure (R,R)-6,11-di(tert-butyl)triptycene-1,4-hydroquinone. The nonfluorinated biphenyl-based PAE was also synthesized using Pd-catalyzed C–O coupling methods, and structure–property comparisons were made from the different biphenyl-based polymers. The integration of free-volume-promoting triptycene moieties on the main chain gives rise to intrinsic porosity, which can be further modulated by incorporating biphenyl or perfluorobiphenyl comonomers. The nonfluorinated PAE exhibited a BET surface area of 270 m2 g–1, whereas the racemic and enantiopure fluorinated PAEs showed higher BET surface areas of 454 and 368 m2 g–1, respectively. WAXS analysis revealed that all of the polymers tested have a greater disruption of chain packing compared to related polyimides, with the fluorinated PAEs having the highest average interchain spacing. The fluorinated PAEs also demonstrated high gas permeability as a result of their free volume. The triptycene-based PAEs also were resistant to plasticization even at CO2 pressures of ∼31 bar.

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Product Details of t-BuBrettPhos

CAS No. :1160861-53-9
Formula : C31H49O2P
M.W : 484.69
SMILES Code : COC1=C(C2=C(C(C)C)C=C(C(C)C)C=C2C(C)C)C(P(C(C)(C)C)C(C)(C)C)=C(OC)C=C1
MDL No. :MFCD13181930
InChI Key :REWLCYPYZCHYSS-UHFFFAOYSA-N
Pubchem ID :44233348

Safety of t-BuBrettPhos

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of t-BuBrettPhos

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1160861-53-9 ]

[ 1160861-53-9 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 225931-80-6 ]
  • [ 1160861-53-9 ]
  • [ 20651-67-6 ]
  • C41H62IO2PPd [ No CAS ]
 

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