Alternatived Products of [ 1256355-43-7 ]
Product Details of [ 1256355-43-7 ]
CAS No. : | 1256355-43-7 |
MDL No. : | MFCD08704671 |
Formula : |
C9H11BO4
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | VGWIKSSTFJNMNF-UHFFFAOYSA-N |
M.W : |
193.99
|
Pubchem ID : | 53216712 |
Synonyms : |
|
Safety of [ 1256355-43-7 ]
Application In Synthesis of [ 1256355-43-7 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 1256355-43-7 ]
- 1
-
[ 19190-91-1 ]
-
[ 1256355-43-7 ]
-
C21H17BrO2
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
82.5% |
With tetrakis(triphenylphosphine) palladium(0); potassium carbonate; In water; toluene; for 24h;Inert atmosphere; Reflux; |
<strong>[19190-91-1]5,6-Dibromoacenaphthene</strong> (112 g, 0.36 mol), 2-methoxycarbonyl-4-methyl-phenylboronic acid (58.2 g, 0.3 mol) was added to a 3 L three- 69 g, 0.5 mol), toluene (1200 g), deionized water (450 g) under nitrogen, Pd (PPh3)4(5.0 g), heated to reflux, incubated for 24 h, cooled to 30 C. The organic phase was rapidly passed through a 25 cm thick silica gel column, and the crude product was removed from the column. The resulting crude product was recrystallized from anhydrous ethanol Compound 3, 94.1 g as a white solid, 82.5% yield. |