Alternatived Products of [ 1308652-67-6 ]
Product Details of [ 1308652-67-6 ]
CAS No. : | 1308652-67-6 |
MDL No. : | MFCD23702163 |
Formula : |
C30H22NP
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | JPVSMRIBFLAYKE-UHFFFAOYSA-N |
M.W : |
427.48
|
Pubchem ID : | 118878614 |
Synonyms : |
|
Safety of [ 1308652-67-6 ]
Application In Synthesis of [ 1308652-67-6 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 1308652-67-6 ]
- 1
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[ 902518-11-0 ]
-
[ 1079-66-9 ]
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[ 1308652-67-6 ]
- 2
-
[ 86-74-8 ]
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[ 1308652-67-6 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 2 steps
1.1: copper oxide (I); tripotassium phosphate tribasic; N,N-dimethyl-1,2-diaminoethane / toluene / 120 °C
2.1: n-butyllithium / tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere
2.2: -78 - 20 °C / Inert atmosphere |
|
|
Multi-step reaction with 2 steps
1.1: potassium hydroxide / N,N-dimethyl-formamide / 6 h / 155 °C
2.1: n-butyllithium / tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere
2.2: 12 h / -78 - 20 °C / Inert atmosphere |
|
|
Multi-step reaction with 2 steps
1.1: copper (I) iodide; potassium carbonate / 5,5-dimethyl-1,3-cyclohexadiene / 168 h / Inert atmosphere; Reflux
2.1: n-butyllithium / tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere
2.2: 12 h / -78 - 20 °C / Inert atmosphere |
|
|
Multi-step reaction with 2 steps
1.1: N<SUP>1</SUP>,N<SUP>2</SUP>-dimethylethane-1,2-diamine; tripotassium phosphate tribasic; copper oxide (I) / toluene / 72 h / 120 °C / Inert atmosphere
2.1: n-butyllithium / tetrahydrofuran; isopropanol; propan-2-one / 0.5 h / -78 - 20 °C / Inert atmosphere
2.2: 20 °C / Inert atmosphere |
|
Reference:
[1]Chun To, Sheung; Yee Kwong, Fuk
[Chemical Communications, 2011, vol. 47, # 17, p. 5079 - 5081]
[2]Leung, Man Pan; Choy, Pui Ying; Lai, Wing In; Gan, Kin Boon; Kwong, Fuk Yee
[Organic Process Research and Development, 2019, vol. 23, # 8, p. 1602 - 1609]
[3]Leung, Man Pan; Choy, Pui Ying; Lai, Wing In; Gan, Kin Boon; Kwong, Fuk Yee
[Organic Process Research and Development, 2019, vol. 23, # 8, p. 1602 - 1609]
[4]Rzayev, Javid; Zhang, Zhuan; Durand, Natacha; Soulé, Jean-François
[Organic Letters, 2022, vol. 24, # 37, p. 6755 - 6760]
- 3
-
[ 583-53-9 ]
-
[ 1308652-67-6 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 2 steps
1.1: copper oxide (I); tripotassium phosphate tribasic; N,N-dimethyl-1,2-diaminoethane / toluene / 120 °C
2.1: n-butyllithium / tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere
2.2: -78 - 20 °C / Inert atmosphere |
|
|
Multi-step reaction with 2 steps
1.1: copper (I) iodide; potassium carbonate / 5,5-dimethyl-1,3-cyclohexadiene / 168 h / Inert atmosphere; Reflux
2.1: n-butyllithium / tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere
2.2: 12 h / -78 - 20 °C / Inert atmosphere |
|
|
Multi-step reaction with 2 steps
1.1: N<SUP>1</SUP>,N<SUP>2</SUP>-dimethylethane-1,2-diamine; tripotassium phosphate tribasic; copper oxide (I) / toluene / 72 h / 120 °C / Inert atmosphere
2.1: n-butyllithium / tetrahydrofuran; isopropanol; propan-2-one / 0.5 h / -78 - 20 °C / Inert atmosphere
2.2: 20 °C / Inert atmosphere |
|
Reference:
[1]Chun To, Sheung; Yee Kwong, Fuk
[Chemical Communications, 2011, vol. 47, # 17, p. 5079 - 5081]
[2]Leung, Man Pan; Choy, Pui Ying; Lai, Wing In; Gan, Kin Boon; Kwong, Fuk Yee
[Organic Process Research and Development, 2019, vol. 23, # 8, p. 1602 - 1609]
[3]Rzayev, Javid; Zhang, Zhuan; Durand, Natacha; Soulé, Jean-François
[Organic Letters, 2022, vol. 24, # 37, p. 6755 - 6760]
- 4
-
[ 1072-85-1 ]
-
[ 1308652-67-6 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 2 steps
1.1: potassium hydroxide / N,N-dimethyl-formamide / 6 h / 155 °C
2.1: n-butyllithium / tetrahydrofuran / 0.5 h / -78 °C / Inert atmosphere
2.2: 12 h / -78 - 20 °C / Inert atmosphere |
|
- 5
-
[ 1308652-67-6 ]
-
[ 160979-17-9 ]
-
[ 2838447-68-8 ]
Yield | Reaction Conditions | Operation in experiment |
70% |
With bis[chlorido(η2,η2-cycloocta-1,5-diene)rhodium(I)]; Sodium hydrogenocarbonate In toluene at 140℃; for 16h; Schlenk technique; Inert atmosphere; |
|
- 6
-
[ 141-32-2 ]
-
[ 1308652-67-6 ]
-
[ 2838447-62-2 ]
Yield | Reaction Conditions | Operation in experiment |
87% |
With bis[chlorido(η2,η2-cycloocta-1,5-diene)rhodium(I)]; Sodium hydrogenocarbonate In toluene at 140℃; for 16h; Schlenk technique; Inert atmosphere; |
|
- 7
-
[ 1308652-67-6 ]
-
[ 140-88-5 ]
-
[ 2838447-63-3 ]
Yield | Reaction Conditions | Operation in experiment |
86% |
With silver hexafluoroantimonate; di-μ-chlorobis-[(η6-p-cymene)chlororuthenium(II)]; anhydrous potassium acetate In toluene at 140℃; for 24h; Schlenk technique; Inert atmosphere; |
|
- 8
-
[ 2495-35-4 ]
-
[ 1308652-67-6 ]
-
[ 2838447-64-4 ]
Yield | Reaction Conditions | Operation in experiment |
85% |
With bis[chlorido(η2,η2-cycloocta-1,5-diene)rhodium(I)]; Sodium hydrogenocarbonate In toluene at 140℃; for 16h; Schlenk technique; Inert atmosphere; |
|
- 9
-
[ 2680-03-7 ]
-
[ 1308652-67-6 ]
-
[ 2838447-67-7 ]
Yield | Reaction Conditions | Operation in experiment |
56% |
With bis[chlorido(η2,η2-cycloocta-1,5-diene)rhodium(I)]; Sodium hydrogenocarbonate In toluene at 140℃; for 16h; Schlenk technique; Inert atmosphere; |
|
- 10
-
[ 48076-38-6 ]
-
[ 1308652-67-6 ]
-
[ 2838447-65-5 ]
Yield | Reaction Conditions | Operation in experiment |
94% |
With bis[chlorido(η2,η2-cycloocta-1,5-diene)rhodium(I)]; Sodium hydrogenocarbonate In toluene at 140℃; for 16h; Schlenk technique; Inert atmosphere; |
|
- 11
-
[ 1308652-67-6 ]
-
[ 4835-96-5 ]
-
[ 2838447-66-6 ]
Yield | Reaction Conditions | Operation in experiment |
89% |
With bis[chlorido(η2,η2-cycloocta-1,5-diene)rhodium(I)]; Sodium hydrogenocarbonate In toluene at 140℃; for 16h; Schlenk technique; Inert atmosphere; |
|
- 12
-
[ 1072-85-1 ]
-
[ 86-74-8 ]
-
[ 1308652-67-6 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 2 steps
1.1: potassium <i>tert</i>-butylate / N,N-dimethyl-formamide / 12 h / 90 °C / Inert atmosphere
2.1: n-butyllithium / tetrahydrofuran / 1 h / -78 °C / Inert atmosphere
2.2: 13 h / -78 - 20 °C / Inert atmosphere |
|
Reference:
[1]Song, Xiaoqing; Lu, Guang; Man, Yi; Zhang, Jing; Chen, Shuo; Han, Chunmiao; Xu, Hui
[Angewandte Chemie - International Edition, 2023, vol. 62, # 21][Angew. Chem., 2023, vol. 135, # 21]