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[ CAS No. 13241-33-3 ]

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Cat. No.: {[proInfo.prAm]}
2D
Chemical Structure| 13241-33-3
Chemical Structure| 13241-33-3
Structure of 13241-33-3 *Storage: {[proInfo.prStorage]}

Quality Control of [ 13241-33-3 ]

Purity: {[proInfo.showProBatch.pb_purity]}

Related Doc. of [ 13241-33-3 ]

SDS

Product Details of [ 13241-33-3 ]

CAS No. :13241-33-3MDL No. :MFCD16661259
Formula :C28H34O15Boiling Point :933.7°C at 760 mmHg
Linear Structure Formula :-InChI Key :-
M.W :610.56Pubchem ID :442439
Synonyms :

Computed Properties of [ 13241-33-3 ]

TPSA : - H-Bond Acceptor Count : -
XLogP3 : - H-Bond Donor Count : -
SP3 : - Rotatable Bond Count : -

Safety of [ 13241-33-3 ]

Signal Word:WarningClassN/A
Precautionary Statements:P261-P305+P351+P338UN#:N/A
Hazard Statements:H302-H315-H319-H335Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 13241-33-3 ]

  • Downstream synthetic route of [ 13241-33-3 ]

[ 13241-33-3 ] Synthesis Path-Downstream   1~10

  • 2
  • [ 13241-33-3 ]
  • [ 693-38-9 ]
  • 6''-O-palmitoyl neohesperidin [ No CAS ]
YieldReaction ConditionsOperation in experiment
88% With lipozyme TL IM from Thermomyces lanuginosus; In tert-Amyl alcohol; dimethyl sulfoxide; at 52.0℃; for 0.583333h;Flow reactor; Enzymatic reaction; General procedure: Method C: 0.49 mmol of the [13241-33-3]neohesperidin was dissolved in10 mL 2-methyl -2-butanol/DMSO 4:1 (feed 1, ~0.049 M) and3.92 mmol vinyl laurate or vinyl palmitate were dissolved in 10 mL2-methyl-2-butanol (feed 2; ~0.39 M). Lipozyme TL IM (0.87 g)were filled in silica gel tubing (inner diameter ID 2.0 mm,length 1 m). The next reaction procedure is similar to Method B.
  • 3
  • [ 13241-33-3 ]
  • [ 2146-71-6 ]
  • [ 502764-74-1 ]
YieldReaction ConditionsOperation in experiment
92% With lipozyme TL IM from Thermomyces lanuginosus; In tert-Amyl alcohol; dimethyl sulfoxide; at 52.0℃; for 0.583333h;Flow reactor; Enzymatic reaction; General procedure: Method C: 0.49 mmol of the [13241-33-3]neohesperidin was dissolved in10 mL 2-methyl -2-butanol/DMSO 4:1 (feed 1, ~0.049 M) and3.92 mmol vinyl laurate or vinyl palmitate were dissolved in 10 mL2-methyl-2-butanol (feed 2; ~0.39 M). Lipozyme TL IM (0.87 g)were filled in silica gel tubing (inner diameter ID 2.0 mm,length 1 m). The next reaction procedure is similar to Method B.
  • 4
  • [ 108-05-4 ]
  • [ 13241-33-3 ]
  • 6''-O-ethanoyl neohesperidin [ No CAS ]
YieldReaction ConditionsOperation in experiment
60% With lipozyme TL IM from Thermomyces lanuginosus; In tert-Amyl alcohol; dimethyl sulfoxide; at 52.0℃; for 0.583333h;Flow reactor; Enzymatic reaction; General procedure: Method B: 0.49 mmol of the [13241-33-3]neohesperidin was dissolved in10 mL 2-methyl -2-butanol/DMSO 4:1 (feed 1, ~0.049 M) and10.29 mmol vinyl acetate were dissolved in 10 mL 2-methyl -2-butanol (feed 2; ~1.03 M). Lipozyme TL IM (0.87 g) were filled insilica gel tubing (inner diameter ID 2.0 mm, length 1m).Streams 1 and 2 were mixed together at a flow rate of.8.91 mL min1 in a Y-mixer at 52 C and the resulting stream(17.82 mL min1) was connected to a sample vial which was used tocollect the final mixture. The final mixture was then evaporated,and the oily residue was submitted to column chromatography onsilica gel (200e300 mesh). The products were eluted with agradient of ethyl acetate/methanol/H2O (25:2.5:0.6, by vol). Thepurification was monitored by TLC. The fractions containing themain products were pooled, the solvent evaporated, and the residueanalyzed by 1H NMR.
  • 5
  • [ 67-56-1 ]
  • [ 13241-33-3 ]
  • C30H40O16 [ No CAS ]
YieldReaction ConditionsOperation in experiment
103.1 g With nido-decaborane; trimethyl orthoformate; at 65.0℃; for 6.0h;Industrial scale; 100 g of [13241-33-3]neohesperidin was dissolved in 1100 g of methanol at a mass concentration of 99%45 g of trimethyl orthoformate and 7.5 g of ketal catalyst decane boron were added,At 65 & lt; 0 & gt; C,The ketal reaction was carried out for 6 h,Concentrated under reduced pressure,Cooling crystallization,filter,dry,To give 103.1 g of compound I;
  • 6
  • [ 13241-33-3 ]
  • [ 64-17-5 ]
  • C32H44O16 [ No CAS ]
YieldReaction ConditionsOperation in experiment
102.7 g With indium(III) chloride; orthoformic acid triethyl ester; at 70.0℃; for 3.0h;Industrial scale; 100 g of [13241-33-3]neohesperidin was dissolved in 1100 g of methanol at a mass concentration of 99%45 g of trimethyl orthoformate and 7.5 g of ketal catalyst decane boron were added,At 65 & lt; 0 & gt; C,The ketal reaction was carried out for 6 h,Concentrated under reduced pressure,Cooling crystallization,filter,dry,To give 103.1 g of compound I;
  • 7
  • [ 13241-33-3 ]
  • C30H40O16 [ No CAS ]
  • 8
  • [ 13241-33-3 ]
  • C32H46O15 [ No CAS ]
  • 9
  • [ 13241-33-3 ]
  • C32H44O15 [ No CAS ]
  • 10
  • [ 13241-33-3 ]
  • C30H42O16 [ No CAS ]
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