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[ CAS No. 1437769-83-9 ]

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2D
Chemical Structure| 1437769-83-9
Chemical Structure| 1437769-83-9
Structure of 1437769-83-9 *Storage: {[proInfo.prStorage]}

Quality Control of [ 1437769-83-9 ]

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Alternatived Products of [ 1437769-83-9 ]
Alternatived Products of [ 1437769-83-9 ]

Product Details of [ 1437769-83-9 ]

CAS No. :1437769-83-9MDL No. :MFCD19237213
Formula : C16H19BO3 Boiling Point : -
Linear Structure Formula :-InChI Key :-
M.W :270.13Pubchem ID :-
Synonyms :

Computed Properties of [ 1437769-83-9 ]

TPSA : - H-Bond Acceptor Count : -
XLogP3 : - H-Bond Donor Count : -
SP3 : - Rotatable Bond Count : -

Safety of [ 1437769-83-9 ]

Signal Word:WarningClass:
Precautionary Statements:P261-P264-P270-P271-P280-P301+P312-P302+P352-P304+P340-P330-P363-P501UN#:
Hazard Statements:H302-H312-H332Packing Group:
GHS Pictogram:

Application In Synthesis of [ 1437769-83-9 ]

  • Downstream synthetic route of [ 1437769-83-9 ]

[ 1437769-83-9 ] Synthesis Path-Downstream   1~6

  • 1
  • [ 1437769-83-9 ]
  • [ 86557-98-4 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: N-ethyl-N,N-diisopropylamine / dichloromethane / 2 h / -78 °C / Inert atmosphere 2: sec.-butyllithium / hexane; diethyl ether; cyclohexane / 0.5 h / -78 - 25 °C / Inert atmosphere
  • 2
  • [ 358-23-6 ]
  • [ 1437769-83-9 ]
  • [ 1437769-76-0 ]
YieldReaction ConditionsOperation in experiment
79.6% With N-ethyl-N,N-diisopropylamine In dichloromethane at -78℃; for 2h; Inert atmosphere;
  • 3
  • [ 135-19-3 ]
  • [ 25015-63-8 ]
  • [ 1437769-83-9 ]
YieldReaction ConditionsOperation in experiment
74.8% Stage #1: β-naphthol With bis(1,5-cyclooctadiene)diiridium(I) dichloride; H2SiEt2 In benzene at 20℃; for 2h; Inert atmosphere; Stage #2: 4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane With bis(1,5-cyclooctadiene)diiridium(I) dichloride; bis(pinacol)diborane; 4,4'-di-tert-butyl-2,2'-bipyridine In tetrahydrofuran; benzene at 20 - 80℃; for 2h;
  • 4
  • [ 135-19-3 ]
  • [ 73183-34-3 ]
  • [ 1437769-83-9 ]
YieldReaction ConditionsOperation in experiment
67% Stage #1: β-naphthol; bis(pinacol)diborane With (1,5-cyclooctadiene)(methoxy)iridium(I) dimer; triethylamine; 4,4'-di-tert-butyl-2,2'-bipyridine In toluene at 80℃; for 3h; Glovebox; Sealed tube; Stage #2: With 2,3-dimethyl-2,3-butane diol In chloroform at 20℃; for 0.666667h;
  • 5
  • [ 30478-88-7 ]
  • [ 73183-34-3 ]
  • [ 1437769-83-9 ]
YieldReaction ConditionsOperation in experiment
78% With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; In N,N-dimethyl-formamide; at 90℃; The starting material, <strong>[30478-88-7]3-bromonaphthalen-2-ol</strong> (CAS Registry Number: 30478-88-7) (28.61 g, 128.26 mmol) was dissolved in DMF (640 ml) Pd (dppf) Cl2 (3.14 g, 3.85 mmol) and KOAc (37.76 g, 384.77 mmol) were added to a solution of bis (pinacolato) diboron (35.83 g, 141.08 mmol)90 CUnder stirringRespectively. When the reaction was complete, DMF was removed by distillation and extracted with CH2Cl2 and water. The organic layer was dried over MgSO4 and concentrated. The resulting compound was purified by silicagel column and recrystallized to obtain 27.02 g (yield: 78%) of the product.
  • 6
  • potassium hydrogen bifluoride [ No CAS ]
  • [ 1437769-83-9 ]
  • [ 1033783-07-1 ]
YieldReaction ConditionsOperation in experiment
65 mg In methanol at 20℃; for 24h; Inert atmosphere;
Historical Records

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[ 1437769-83-9 ]

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