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Chemical Structure| 14804-39-8 Chemical Structure| 14804-39-8

Structure of 14804-39-8

Chemical Structure| 14804-39-8

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Product Details of [ 14804-39-8 ]

CAS No. :14804-39-8
Formula : C9H11NO3
M.W : 181.19
SMILES Code : O=[N+](C1=CC(C)=C(OC)C(C)=C1)[O-]
MDL No. :MFCD00024537
InChI Key :HSDNHFOJTRMGER-UHFFFAOYSA-N
Pubchem ID :139835

Safety of [ 14804-39-8 ]

GHS Pictogram:
Signal Word:Warning
Hazard Statements:H302-H315-H319-H335
Precautionary Statements:P261-P305+P351+P338

Application In Synthesis of [ 14804-39-8 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 14804-39-8 ]

[ 14804-39-8 ] Synthesis Path-Downstream   1~1

  • 1
  • [ 16947-63-0 ]
  • [ 77-78-1 ]
  • [ 14804-39-8 ]
YieldReaction ConditionsOperation in experiment
With potassium carbonate; In acetone; for 3.0h;Heating / reflux; Step 2: 2-Methoxy-1,3-dimethyl-5-nitrobenzene <strong>[16947-63-0]2,6-Dimethyl-4-nitroanilin</strong>e (15 g) Me2SO4 (22 g) and K2CO3 (23 g) were dissolved in 150 mL acetone and refluxed for 3 hours. The reaction mixture was filtered and concentrated. The organic residue was dissolved in warm hexane and let to crystallize out in the fridge. After filtration, 2-methoxy-1,3-dimethyl-5-nitrobenzene was collected as white solid (12 g). 1H-NMR (300 MHz, CDCl3): delta=7.95 (s, 2H), 3.80 (s, 3H), 2.38 (s, 6H) ppm. MS: m/z 182 (100, M+H)+
 

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