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[ CAS No. 16356-02-8 ]

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Cat. No.: {[proInfo.prAm]}
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Chemical Structure| 16356-02-8
Chemical Structure| 16356-02-8
Structure of 16356-02-8 * Storage: {[proInfo.prStorage]}

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Alternatived Products of [ 16356-02-8 ]

Product Details of [ 16356-02-8 ]

CAS No. :16356-02-8 MDL No. :MFCD00048069
Formula : C6H10O2 Boiling Point : -
Linear Structure Formula :- InChI Key :N/A
M.W :114.14 g/mol Pubchem ID :-
Synonyms :

Safety of [ 16356-02-8 ]

Signal Word:Danger Class:3
Precautionary Statements:P501-P240-P210-P233-P243-P241-P242-P280-P370+P378-P303+P361+P353-P403+P235 UN#:3271
Hazard Statements:H225 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 16356-02-8 ]

  • Downstream synthetic route of [ 16356-02-8 ]

[ 16356-02-8 ] Synthesis Path-Downstream   1~25

  • 1
  • [ 16356-02-8 ]
  • [ 13179-96-9 ]
YieldReaction ConditionsOperation in experiment
With hydrogen; nickel at 170℃;
With hydrogen; platinum
  • 2
  • [ 16356-02-8 ]
  • [ 40206-02-8 ]
YieldReaction ConditionsOperation in experiment
99% With dicobalt octacarbonyl In toluene at 230℃; for 0.0833333h; Flow reactor;
50% In tetrahydrofuran at 30℃; Heating;
With sodium tetrahydroborate In hexane at 82.5℃; for 66h; effect of use of var. catalysts, and var. times, and var. temp.;
With sodium tetrahydroborate In hexane at 82.5℃; for 66h; Yield given;
at 60℃; for 6h; Yield given;
40.5 g With sodium tetrahydroborate; tricyclohexylphosphine In hexane at 82.5℃; for 120h;

  • 3
  • [ 998-30-1 ]
  • [ 16356-02-8 ]
  • (E)-1,4-dimethoxy-1-triethoxysilyl-2-buten [ No CAS ]
YieldReaction ConditionsOperation in experiment
97% In tetrahydrofuran for 2h; Ambient temperature;
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In toluene at 100℃; for 2h; Green chemistry; (a) Procedure for hydrosilylation of alkynes performed in toluene or THF General procedure: A silane and an appropriate alkyne were placed in a 25cm3 round bottom flask equipped with a stirrer and a glass stopper. The reagents were dissolved in toluene or THF and Karstedt’s catalyst was added. Subsequently, the reaction mixture was heated to 60°C or 100°C, depending on the reaction. Samples of the reaction mixture were collected in intervals, and the conversion of SiH was determined by 1H NMR and GC-MS. Then the reactions were repeated in determined reaction time, and the resulting mixtures were isolated by the evaporation of the solvent under vacuum. Products were characterized by 1H, 13C, 29Si NMR, GC-MS analysis. The platinum residue was removed by filtration of petroleum ether solution through silica gel. After evaporation of solvents, the products were dried for 6h under vacuum. Isolated products were characterized by 1H, 13C, 29Si NMR, GC-MS. For new compounds, elemental analysis was performed as well.
  • 4
  • [ 16356-02-8 ]
  • [ 789-25-3 ]
  • (E)-1,4-dimethoxy-1-triphenylsilyl-2-buten [ No CAS ]
YieldReaction ConditionsOperation in experiment
94% In tetrahydrofuran for 24h; Ambient temperature;
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In toluene at 100℃; for 6h; Green chemistry; (a) Procedure for hydrosilylation of alkynes performed in toluene or THF General procedure: A silane and an appropriate alkyne were placed in a 25cm3 round bottom flask equipped with a stirrer and a glass stopper. The reagents were dissolved in toluene or THF and Karstedt’s catalyst was added. Subsequently, the reaction mixture was heated to 60°C or 100°C, depending on the reaction. Samples of the reaction mixture were collected in intervals, and the conversion of SiH was determined by 1H NMR and GC-MS. Then the reactions were repeated in determined reaction time, and the resulting mixtures were isolated by the evaporation of the solvent under vacuum. Products were characterized by 1H, 13C, 29Si NMR, GC-MS analysis. The platinum residue was removed by filtration of petroleum ether solution through silica gel. After evaporation of solvents, the products were dried for 6h under vacuum. Isolated products were characterized by 1H, 13C, 29Si NMR, GC-MS. For new compounds, elemental analysis was performed as well.
  • 6
  • [ 2142-69-0 ]
  • [ 16356-02-8 ]
  • 2,3-bis(methoxymethyl)-1-methyl-1H-inden-1-ol [ No CAS ]
YieldReaction ConditionsOperation in experiment
53% With palladium diacetate; ethanol; potassium acetate In N,N-dimethyl-formamide at 100℃; for 20h;
  • 7
  • [ 13047-06-8 ]
  • [ 16356-02-8 ]
  • 2,3-bis-methoxymethyl-1-phenyl-1<i>H</i>-inden-1-ol [ No CAS ]
YieldReaction ConditionsOperation in experiment
64% With palladium diacetate; ethanol; potassium acetate In N,N-dimethyl-formamide at 100℃; for 28h;
  • 8
  • [ 88284-48-4 ]
  • [ 16356-02-8 ]
  • [ 101789-64-4 ]
YieldReaction ConditionsOperation in experiment
59% With cesium fluoride; tris-(o-tolyl)phosphine In acetonitrile at 60℃; for 4h;
59% With palladium diacetate; cesium fluoride; tris-(o-tolyl)phosphine In acetonitrile at 60℃; for 4h;
  • 9
  • [ 16356-02-8 ]
  • [ 13179-96-9 ]
YieldReaction ConditionsOperation in experiment
at 170℃;
  • 10
  • [ 16356-02-8 ]
  • [ 67-56-1 ]
  • [ 628-28-4 ]
  • [ 13179-96-9 ]
YieldReaction ConditionsOperation in experiment
Hydrogenation;
  • 11
  • [ 75-15-0 ]
  • [ 89424-83-9 ]
  • [ 16356-02-8 ]
  • 5-(4,5-bis-methoxymethyl-[1,3]dithiol-2-ylidenemethyl)-1,3-dihydro-isobenzofuran [ No CAS ]
  • 12
  • [ 4873-09-0 ]
  • [ 16356-02-8 ]
  • 1,2,3,4-tetrakis(methoxymethyl)-5-methylbenzene [ No CAS ]
  • 13
  • [ 88284-48-4 ]
  • [ 107-05-1 ]
  • [ 16356-02-8 ]
  • [ 883-20-5 ]
  • 1,2-bis-methoxymethyl-3-methyl-naphthalene [ No CAS ]
YieldReaction ConditionsOperation in experiment
1: 50% 2: 4% Stage #1: 3-chloroprop-1-ene; 1,4-dimethoxy-2-butyne With tris(dibenzylideneacetone)dipalladium(0) chloroform complex; 1,1'-bis-(diphenylphosphino)ferrocene; cesium fluoride In tetrahydrofuran; acetonitrile at 20℃; for 0.0833333h; Stage #2: 2-(trimethylsilyl)phenyl trifluoromethanesulfonate With cesium fluoride In tetrahydrofuran; acetonitrile at 60℃; for 24h;
  • 14
  • [ 107428-05-7 ]
  • [ 16356-02-8 ]
  • 5,6-bis-methoxymethyl-4,7-dimethyl-indan-2,2-dicarboxylic acid dimethyl ester [ No CAS ]
YieldReaction ConditionsOperation in experiment
94% With 1,2-bis-(diphenylphosphino)ethane In benzene at 20℃; for 0.5h;
94% With 1,2-bis-(diphenylphosphino)ethane In benzene at 20℃; for 0.5h;
  • 15
  • [ 75999-66-5 ]
  • [ 16356-02-8 ]
  • 3,4-dimethoxymethyl-6-methoxy-2-trifluoromethylquinoline [ No CAS ]
YieldReaction ConditionsOperation in experiment
65% With triethylamine; 1,2-bis-(diphenylphosphino)ethane In toluene at 110℃;
  • 16
  • [ 38053-91-7 ]
  • [ 16356-02-8 ]
  • [(4,5-bis(methoxymethyl)-1,4-cyclohexadien-1-yl)oxy]trimethylsilane [ No CAS ]
  • 17
  • [ 110-67-8 ]
  • [ 16356-02-8 ]
  • 2-(2-methoxyethyl)-3,4,5,6-tetra(methoxymethyl)pyridine [ No CAS ]
  • 18
  • [ 762-42-5 ]
  • [ 16356-02-8 ]
  • [ 109552-63-8 ]
YieldReaction ConditionsOperation in experiment
98% With 1,2-bis-(diphenylphosphino)ethane In tetrahydrofuran at 50℃; for 2h;
  • 19
  • [ 762-42-5 ]
  • [ 16356-02-8 ]
  • [ 109552-63-8 ]
  • dimethyl 3,4,5,6-tetrakis(methoxymethyl)-1,2-benzenedicarboxylate [ No CAS ]
YieldReaction ConditionsOperation in experiment
1: 96% 2: 1% With 1,2-bis(di(pentafluorophenyl)phosphino)ethane In tetrahydrofuran at 50℃; for 1h;
  • 20
  • [ 16356-02-8 ]
  • bis[3-(2-methylphenyl)prop-2-yl] ether [ No CAS ]
  • 1,3-dihydro-5,6-bis(methoxymethyl)-4,7-bis(2-methylphenyl)isobenzofuran [ No CAS ]
YieldReaction ConditionsOperation in experiment
85% With bis(1,5-cyclooctadiene)diiridium(I) dichloride; (S,S)-1,2-bis(2,5-dimethylphospholano)benzene In xylene at 100℃; for 1h;
  • 21
  • [ 16356-02-8 ]
  • bis[3-(2-chlorophenyl)prop-2-yl] ether [ No CAS ]
  • 1,3-dihydro-5,6-bis(methoxymethyl)-4,7-bis(2-chlorophenyl)isobenzofuran [ No CAS ]
YieldReaction ConditionsOperation in experiment
85% With bis(1,5-cyclooctadiene)diiridium(I) dichloride; (S,S)-1,2-bis(2,5-dimethylphospholano)benzene In xylene at 100℃; for 1h;
  • 22
  • [ 16356-02-8 ]
  • (Z)-1,8-di(naphthalen-1-yl)oct-4-en-1,7-diyne [ No CAS ]
  • 2',3'-dimethoxymethyl-1,1':4',1''-ter-5',8'-dihydronaphthalene [ No CAS ]
YieldReaction ConditionsOperation in experiment
76% With bis(1,5-cyclooctadiene)diiridium(I) dichloride; (S,S)-1,2-bis(2,5-dimethylphospholano)benzene In xylene at 100℃; for 1h;
  • 23
  • [ 16356-02-8 ]
  • 1,7-di(naphthalen-1-yl)hepta-1,6-diyne [ No CAS ]
  • 2,3-dihydro-4,7-di(naphthalen-1-yl)-5,6-bis(methoxymethyl)-1H-indene [ No CAS ]
YieldReaction ConditionsOperation in experiment
96% With bis(1,5-cyclooctadiene)diiridium(I) dichloride; (S,S)-1,2-bis(2,5-dimethylphospholano)benzene In xylene at 100℃; for 1h;
  • 24
  • [ 16356-02-8 ]
  • bis[3-(4-methoxynaphthalen-1-yl)prop-2-yl] ether [ No CAS ]
  • 1,3-dihydro-5,6-bis(methoxymethyl)-4,7-bis(4-methoxynaphthalen-1-yl)isobenzofuran [ No CAS ]
YieldReaction ConditionsOperation in experiment
72% With bis(1,5-cyclooctadiene)diiridium(I) dichloride; (S,S)-1,2-bis(2,5-dimethylphospholano)benzene In xylene at 100℃; for 1h;
  • 25
  • [ 16356-02-8 ]
  • 4-methyl-N,N-bis(3-(naphthalen-1-yl)prop-2-yn-1-yl)benzenesulfonamide [ No CAS ]
  • 1,3-dihydro-4,7-di(naphthalen-1-yl)-5,6-bis(methoxymethyl)-2-tosylisoindoline [ No CAS ]
YieldReaction ConditionsOperation in experiment
92% With bis(1,5-cyclooctadiene)diiridium(I) dichloride; (S,S)-1,2-bis(2,5-dimethylphospholano)benzene In xylene at 100℃; for 1h;
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