Alternatived Products of [ 17092-92-1 ]
Product Details of [ 17092-92-1 ]
CAS No. : | 17092-92-1 |
MDL No. : | MFCD20926295 |
Formula : |
C11H16O2
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | - |
M.W : |
180.24
|
Pubchem ID : | - |
Synonyms : |
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Application In Synthesis of [ 17092-92-1 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 17092-92-1 ]
- 1
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[ 53537-93-2 ]
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[ 17092-92-1 ]
Yield | Reaction Conditions | Operation in experiment |
95% |
With thionyl chloride In pyridine Ambient temperature; |
|
- 2
-
(-)-methyl azafrinate
[ No CAS ]
-
[ 17092-92-1 ]
Yield | Reaction Conditions | Operation in experiment |
|
With nickel(IV) oxide; titanium tetrachloride multistep reaction; 1.) ether/benzene, 5 min, 2.) ether/benzene, RT, 20 h; configuration of the parent compound; |
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- 3
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(3aS,7aR)-2-oxo-3-phenylselenyl-4,4,7a-trimethyloctahydrobenzofuran
[ No CAS ]
-
[ 17092-92-1 ]
Yield | Reaction Conditions | Operation in experiment |
|
With dihydrogen peroxide; sodium hydrogencarbonate; acetic acid; platinum 1.) THF, 5 deg C, 1 h; 2.) r.t., 30 min; Yield given. Multistep reaction; |
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- 4
-
[ 199727-72-5 ]
-
[ 17092-92-1 ]
Yield | Reaction Conditions | Operation in experiment |
82% |
With dmap; trifluoromethanesulfonic acid anhydride In dichloromethane 1.) 0 deg C, 1 h, 2.) room temperature, overnight; |
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- 6
-
[ 41169-33-9 ]
-
[ 17092-92-1 ]
Yield | Reaction Conditions | Operation in experiment |
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Multi-step reaction with 4 steps
1: 90 percent / 2,2'-isopropylidenebis<(4S)-4-tert-butyl-2-oxazoline>Cu(SbF6)2 / CH2Cl2 / 18 h / Ambient temperature
2: 1.) KOH, 2.) HCl / multistep reaction, 1.) water, ethanol, room temperature, 6 h, 2.) water, room temperature, 12 h
3: 95 percent / hydrogen / (Ph3P)3RhCl / benzene / 12 h / 760 Torr / Ambient temperature
4: 82 percent / trifluoromethanesulfonic anhydride, 4-(N,N-dimethylamino)pyridine / CH2Cl2 / 1.) 0 deg C, 1 h, 2.) room temperature, overnight |
|
- 7
-
[ 199727-74-7 ]
-
[ 17092-92-1 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 2 steps
1: 95 percent / hydrogen / (Ph3P)3RhCl / benzene / 12 h / 760 Torr / Ambient temperature
2: 82 percent / trifluoromethanesulfonic anhydride, 4-(N,N-dimethylamino)pyridine / CH2Cl2 / 1.) 0 deg C, 1 h, 2.) room temperature, overnight |
|
- 8
-
[ 199727-73-6 ]
-
[ 17092-92-1 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 3 steps
1: 1.) KOH, 2.) HCl / multistep reaction, 1.) water, ethanol, room temperature, 6 h, 2.) water, room temperature, 12 h
2: 95 percent / hydrogen / (Ph3P)3RhCl / benzene / 12 h / 760 Torr / Ambient temperature
3: 82 percent / trifluoromethanesulfonic anhydride, 4-(N,N-dimethylamino)pyridine / CH2Cl2 / 1.) 0 deg C, 1 h, 2.) room temperature, overnight |
|
- 9
-
[ 104266-24-2 ]
-
[ 17092-92-1 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 3 steps
1: 81 percent / N,N-dimethylaminopyridine / triethylamine
2: 70 percent / lithium diisopropylamide / -78 °C
3: 95 percent / thionyl chloride / pyridine / Ambient temperature |
|
- 10
-
[ 104266-25-3 ]
-
[ 17092-92-1 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 2 steps
1: 70 percent / lithium diisopropylamide / -78 °C
2: 95 percent / thionyl chloride / pyridine / Ambient temperature |
|
- 11
-
[ 104266-23-1 ]
-
[ 17092-92-1 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 4 steps
1: citric acid / methanol / Ambient temperature
2: 81 percent / N,N-dimethylaminopyridine / triethylamine
3: 70 percent / lithium diisopropylamide / -78 °C
4: 95 percent / thionyl chloride / pyridine / Ambient temperature |
|
- 12
-
(1'RS,3'S)-2',2'-dimethyl-6'-methylene-3'-tetrahydropyranyloxycyclohexylacetic acid
[ No CAS ]
-
[ 17092-92-1 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 7 steps
1: 1.) 0.5 M NaHCO3; 2.) KI, I2 / 1.) ether, r.t., 20 min; 2.) water, reflux, overnight
2: 3.23 g / 0.5percent p-TsOH / methanol / 8 h / Ambient temperature
3: 94 percent / 1.) TfCl, DMAP; 3.) water / CH2Cl2 / 1.) 5 deg C, 10 min; 2.) r.t., 1 h; 3.) 30 min
4: 87 percent / (n-Bu)3SnH / benzene / Ambient temperature
5: 0.960 g / H2 / PtO2 / acetic acid / 23 h / 22800 Torr
6: 1.) LDA; 2.) HMPA / 1.) THF, -70 deg C, 30 min; 2.) THF, allowed to warm to r.t.
7: 1.) 35percent H2O2, AcOH; 2.) NaHCO3, Pt-black / 1.) THF, 5 deg C, 1 h; 2.) r.t., 30 min |
|
- 13
-
ethyl <(1RS,3S)-2,2-dimethyl-6-methylene-3-tetrahydropyranyloxycyclohexyl>acetate
[ No CAS ]
-
[ 17092-92-1 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 8 steps
1: 10.6 g / 2.5percent KOH / ethanol / 2 h / Heating
2: 1.) 0.5 M NaHCO3; 2.) KI, I2 / 1.) ether, r.t., 20 min; 2.) water, reflux, overnight
3: 3.23 g / 0.5percent p-TsOH / methanol / 8 h / Ambient temperature
4: 94 percent / 1.) TfCl, DMAP; 3.) water / CH2Cl2 / 1.) 5 deg C, 10 min; 2.) r.t., 1 h; 3.) 30 min
5: 87 percent / (n-Bu)3SnH / benzene / Ambient temperature
6: 0.960 g / H2 / PtO2 / acetic acid / 23 h / 22800 Torr
7: 1.) LDA; 2.) HMPA / 1.) THF, -70 deg C, 30 min; 2.) THF, allowed to warm to r.t.
8: 1.) 35percent H2O2, AcOH; 2.) NaHCO3, Pt-black / 1.) THF, 5 deg C, 1 h; 2.) r.t., 30 min |
|
- 14
-
(3aRS,5S,7aRS)-4,4-dimethyl-7a-iodomethyl-2-oxo-3-tetrahydropyranyloxyoctahydrobenzofuran
[ No CAS ]
-
[ 17092-92-1 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 6 steps
1: 3.23 g / 0.5percent p-TsOH / methanol / 8 h / Ambient temperature
2: 94 percent / 1.) TfCl, DMAP; 3.) water / CH2Cl2 / 1.) 5 deg C, 10 min; 2.) r.t., 1 h; 3.) 30 min
3: 87 percent / (n-Bu)3SnH / benzene / Ambient temperature
4: 0.960 g / H2 / PtO2 / acetic acid / 23 h / 22800 Torr
5: 1.) LDA; 2.) HMPA / 1.) THF, -70 deg C, 30 min; 2.) THF, allowed to warm to r.t.
6: 1.) 35percent H2O2, AcOH; 2.) NaHCO3, Pt-black / 1.) THF, 5 deg C, 1 h; 2.) r.t., 30 min |
|
- 15
-
[ 104527-56-2 ]
-
[ 17092-92-1 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 2 steps
1: 1.) LDA; 2.) HMPA / 1.) THF, -70 deg C, 30 min; 2.) THF, allowed to warm to r.t.
2: 1.) 35percent H2O2, AcOH; 2.) NaHCO3, Pt-black / 1.) THF, 5 deg C, 1 h; 2.) r.t., 30 min |
|
- 16
-
[ 104527-55-1 ]
-
[ 17092-92-1 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 3 steps
1: 0.960 g / H2 / PtO2 / acetic acid / 23 h / 22800 Torr
2: 1.) LDA; 2.) HMPA / 1.) THF, -70 deg C, 30 min; 2.) THF, allowed to warm to r.t.
3: 1.) 35percent H2O2, AcOH; 2.) NaHCO3, Pt-black / 1.) THF, 5 deg C, 1 h; 2.) r.t., 30 min |
|
- 17
-
[ 104467-80-3 ]
-
[ 17092-92-1 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 4 steps
1: 87 percent / (n-Bu)3SnH / benzene / Ambient temperature
2: 0.960 g / H2 / PtO2 / acetic acid / 23 h / 22800 Torr
3: 1.) LDA; 2.) HMPA / 1.) THF, -70 deg C, 30 min; 2.) THF, allowed to warm to r.t.
4: 1.) 35percent H2O2, AcOH; 2.) NaHCO3, Pt-black / 1.) THF, 5 deg C, 1 h; 2.) r.t., 30 min |
|
- 18
-
[ 104435-28-1 ]
-
[ 17092-92-1 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 5 steps
1: 94 percent / 1.) TfCl, DMAP; 3.) water / CH2Cl2 / 1.) 5 deg C, 10 min; 2.) r.t., 1 h; 3.) 30 min
2: 87 percent / (n-Bu)3SnH / benzene / Ambient temperature
3: 0.960 g / H2 / PtO2 / acetic acid / 23 h / 22800 Torr
4: 1.) LDA; 2.) HMPA / 1.) THF, -70 deg C, 30 min; 2.) THF, allowed to warm to r.t.
5: 1.) 35percent H2O2, AcOH; 2.) NaHCO3, Pt-black / 1.) THF, 5 deg C, 1 h; 2.) r.t., 30 min |
|
- 19
-
[ 104435-19-0 ]
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[ 17092-92-1 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 9 steps
1: 96 percent / 6 h / 140 °C
2: 10.6 g / 2.5percent KOH / ethanol / 2 h / Heating
3: 1.) 0.5 M NaHCO3; 2.) KI, I2 / 1.) ether, r.t., 20 min; 2.) water, reflux, overnight
4: 3.23 g / 0.5percent p-TsOH / methanol / 8 h / Ambient temperature
5: 94 percent / 1.) TfCl, DMAP; 3.) water / CH2Cl2 / 1.) 5 deg C, 10 min; 2.) r.t., 1 h; 3.) 30 min
6: 87 percent / (n-Bu)3SnH / benzene / Ambient temperature
7: 0.960 g / H2 / PtO2 / acetic acid / 23 h / 22800 Torr
8: 1.) LDA; 2.) HMPA / 1.) THF, -70 deg C, 30 min; 2.) THF, allowed to warm to r.t.
9: 1.) 35percent H2O2, AcOH; 2.) NaHCO3, Pt-black / 1.) THF, 5 deg C, 1 h; 2.) r.t., 30 min |
|
- 20
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[ 1638-05-7 ]
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[ 17092-92-1 ]
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[ 79-77-6 ]
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[ 432-25-7 ]
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[ 36340-49-5 ]
Yield | Reaction Conditions | Operation in experiment |
|
With dihydrogen peroxide; sodium acetate In water at 27℃; for 1h; Enzymatic reaction; |
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- 21
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[ 7235-40-7 ]
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[ 17092-92-1 ]
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[ 7500-42-7 ]
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[ 79-77-6 ]
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[ 432-25-7 ]
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[ 36340-49-5 ]
Yield | Reaction Conditions | Operation in experiment |
|
With dihydrogen peroxide; sodium acetate In water at 27℃; for 1h; Enzymatic reaction; |
|
- 22
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[ 1107-26-2 ]
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[ 17092-92-1 ]
-
[ 7500-42-7 ]
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[ 79-77-6 ]
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[ 432-25-7 ]
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[ 36340-49-5 ]
Yield | Reaction Conditions | Operation in experiment |
|
With dihydrogen peroxide; sodium acetate In water at 27℃; for 1h; Enzymatic reaction; |
|
- 23
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[ 7235-40-7 ]
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[ 17092-92-1 ]
Yield | Reaction Conditions | Operation in experiment |
|
With 1H-imidazole; tert.-butylhydroperoxide; mu-carbido bis(2,3,7,8,12,13,17,18-octapropyl-5,10,15,20-tetraazaporphinato)iron(IV); In benzene; at 25℃;Kinetics; |
The degradation of beta carotene (CCar=(1.64-8.05)10-4 M) was conductedin the presence of 1 (C1=1.610-6 M) and tBuOOH (CtBuOOH =2.7310-2 M) in benzene solution at 25 C. The experiments were controlledspectrophotometrically by decrease in the intensity of absorptionband of carotene at 462 nm. It should be noted that UV-visspectrum of <strong>[7235-40-7]beta-carotene</strong> remains unchanged in pure benzene. In thepresence of tBuOOH for 5 h the intensity of absorption bands onlyslightly decreased and the conversion of beta carotene was limited to ?5%(Table 1). There were no changes observed when 1 was added tobeta carotene benzene solution. When beta carotene, tBuOOH and 1 were simultaneously placed in solution, the disappearance of the beta caroteneabsorption band occurred within 4 min designating that the 1-tBuOOHsystem mediates the process. |