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[ CAS No. 172172-24-6 ] {[proInfo.proName]}

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Chemical Structure| 172172-24-6
Chemical Structure| 172172-24-6
Structure of 172172-24-6 * Storage: {[proInfo.prStorage]}
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Product Details of [ 172172-24-6 ]

CAS No. :172172-24-6 MDL No. :N/A
Formula : C32H46ClMnN2O2 Boiling Point : -
Linear Structure Formula :- InChI Key :-
M.W : 581.11 Pubchem ID :-
Synonyms :

Safety of [ 172172-24-6 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P264-P280-P302+P352-P337+P313-P305+P351+P338-P362+P364-P332+P313 UN#:N/A
Hazard Statements:H315-H319 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 172172-24-6 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 172172-24-6 ]

[ 172172-24-6 ] Synthesis Path-Downstream   1~3

  • 1
  • [ 37942-07-7 ]
  • [ 6156-78-1 ]
  • [ 107-15-3 ]
  • lithium chloride [ No CAS ]
  • [ 172172-24-6 ]
YieldReaction ConditionsOperation in experiment
In ethanol ligand reacted with ethylenediamine, refluxed with manganese acetate, pptd. with LiCl; IR;
  • 2
  • [ 6156-78-1 ]
  • lithium chloride [ No CAS ]
  • N,N'-bis(3,5-di-tert-butylsalicylidene)-1,2-ethylenediamine [ No CAS ]
  • [ 172172-24-6 ]
YieldReaction ConditionsOperation in experiment
75% In ethanol Mn- and org.-compds. reaction in solvent, pptn. by solid LiCl addn.; dissolving in CH2Cl2, recrystallization after hexane addn.; elem anal.;
In ethanol at 79.84℃; Reflux; Synthesis of Schiff bases and Mn(III)-complexes General procedure: Schiff base ligands and their corresponding complexes [NN-bis-(3,5-di-tert-butylsalicylidene)-ethylendiamine]manganese(III)chloride [Mn(3,5-dtSALEN)Cl)] (I) and [NN-bis-(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine]manganese(III)chloride [Mn(3,5-dtSALHD)Cl] (II) were prepared adopting amethodology widely reported in the literature [13,19,38-40].The ligands were prepared by condensation of 3,5-di-tert-butylsalicylaldehyde with the corresponding diamine (either,ethylenediamine or 1,2-cyclohexanediamine) in a molar ratio 1:2in ethanol. Complexes (I) and (II) were obtained then by addinga saturated solution prepared with 3.66 mmol of manganeseacetate in absolute ethanol to 1.83 mmol of the correspondingligand dissolved in 25 cm3of the same solvent pre-heated at353 K under reflux; air was slowly and shortly (10-20 s) bubbledthrough the reacting mixture since long oxidation might leadto form oxo-Mn(V) species easily detected by darkening of thebrownish solution [41], which inactivate the catalytic responseof the complexes in the targeted reaction. Then, the air streamwas stopped and the heating was kept along one extra hour withdarkening of the yellow-orange solution to brown. Afterwards,5.29 mmol of lithium chloride in ethanol were added to achieve theaccess of Cl into the coordination sphere of the transition metal,and the mixture was heated further 30 min. The resulting solidwas then dissolved in dichloromethane and refined employingthe method from Cubillos et al. [40] by means of liquid extractionwith n-heptane. The final solid was recovered by vacuum filtering and then dried at room temperature in a desiccator. The sameprocedure was used to prepare both complexes.
  • 3
  • C40H37O4P [ No CAS ]
  • [ 172172-24-6 ]
  • C72H85MnN2O6P(2+) [ No CAS ]
YieldReaction ConditionsOperation in experiment
With sodium hydroxide In water; acetone at 20℃; for 5h; Inert atmosphere;
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