Alternatived Products of [ 1812-51-7 ]
Product Details of [ 1812-51-7 ]
CAS No. : | 1812-51-7 |
MDL No. : | MFCD30296301 |
Formula : |
C14H14
|
Boiling Point : |
- |
Linear Structure Formula : | - |
InChI Key : | N/A |
M.W : | 182.26 g/mol |
Pubchem ID : | - |
Synonyms : |
|
Safety of [ 1812-51-7 ]
Signal Word: | Warning |
Class: | |
Precautionary Statements: | P280-P305+P351+P338 |
UN#: | |
Hazard Statements: | H302 |
Packing Group: | |
GHS Pictogram: |
|
Application In Synthesis of [ 1812-51-7 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Downstream synthetic route of [ 1812-51-7 ]
- 1
-
[ 64-67-5 ]

-
[ 23533-35-9 ]

-
[ 1812-51-7 ]
Yield | Reaction Conditions | Operation in experiment |
|
With diethyl ether |
|
- 2
-
[ 1812-51-7 ]

-
[ 86-73-7 ]
Yield | Reaction Conditions | Operation in experiment |
|
With palladium on activated charcoal at 475 - 490℃; |
|
|
Multi-step reaction with 2 steps
1: palladium coal / 475 - 480 °C
2: palladium coal / 475 - 490 °C |
|
- 3
-
[ 1812-51-7 ]

-
[ 2523-37-7 ]
Yield | Reaction Conditions | Operation in experiment |
|
With palladium on activated charcoal at 475 - 480℃; |
|
- 4
-
[ 1812-51-7 ]

-
(+/-)-<i>trans</i>-2-ethyl-bicyclohexyl
[ No CAS ]

-
(+/-)-<i>cis</i>-2-ethyl-bicyclohexyl
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
|
With nickel; methyl cyclohexane at 200℃; Hydrogenation; |
|
- 5
-
[ 16927-84-7 ]

-
[ 1812-51-7 ]
Yield | Reaction Conditions | Operation in experiment |
|
With copper chromite at 200℃; Hydrogenolyse; |
|
- 6
-
[ 100-41-4 ]

-
[ 94-36-0 ]

-
[ 1812-51-7 ]

-
2,3-diphenylbutane
[ No CAS ]

-
[ 65-85-0 ]

-
[ 71-43-2 ]
Yield | Reaction Conditions | Operation in experiment |
|
at 75℃; |
|
- 7
-
[ 17333-73-2 ]

-
[ 100-41-4 ]

-
[ 5668-93-9 ]

-
[ 1812-51-7 ]

-
[ 5707-44-8 ]
- 8
-
[ 1812-51-7 ]

-
[ 5707-44-8 ]
- 9
-
[ 2180-20-3 ]

-
[ 1165952-91-9 ]

-
[ 108-88-3 ]

-
[ 6294-31-1 ]

-
[ 10496-15-8 ]

-
[ 16823-61-3 ]

-
[ 1812-51-7 ]

-
[ 34005-03-3 ]

-
1-hexenyl hexyl sulfide
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
1: 34 % Chromat.
2: 34 % Chromat.
3: 5 % Chromat.
4: 17 % Chromat.
5: 4 % Chromat.
6: 6 % Chromat. |
With aluminum oxide; Ni(acac) at 200℃; for 12h; other dialkyl sulfoxides and 1,3-dienes; var. metal complexes and ligands; var. stoichiometry; |
|
Reference:
[1]Dzhemilev, U. M.; Kunakova, R. V.; Baibulatova, N. Z.; Tarasenko, A. E.; Mustafina, E. M.
[Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.), 1992, vol. 41, # 1, p. 128 - 134][Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1992, # 1, p. 160 - 166]
- 10
-
[ 2180-20-3 ]

-
[ 108-88-3 ]

-
[ 6294-31-1 ]

-
[ 1812-51-7 ]

-
[ 34005-03-3 ]

-
1-hexenyl hexyl sulfide
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
1: 34 % Chromat.
2: 17 % Chromat.
3: 5 % Chromat.
4: 34 % Chromat. |
With aluminum oxide; bis(acetylacetonate)nickel(II) In toluene at 150℃; for 12h; Further byproducts given; |
|
Reference:
[1]Dzhemilev, U. M.; Kunakova, R. V.; Baibulatova, N. Z.; Tarasenko, A. E.; Mustafina, E. M.
[Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.), 1992, vol. 41, # 1, p. 128 - 134][Izvestiya Akademi Nauk, Seriya Khimicheskaya, 1992, # 1, p. 160 - 166]
- 11
-
[ 100-41-4 ]

-
[ 71-43-2 ]

-
[ 92-52-4 ]

-
[ 5668-93-9 ]

-
[ 1812-51-7 ]

-
[ 5707-44-8 ]

-
[ 13049-40-6 ]

-
[ 13049-39-3 ]
- 12
-
[ 96-10-6 ]

-
[ 55365-18-9 ]

-
[ 1812-51-7 ]
Yield | Reaction Conditions | Operation in experiment |
|
With oxovanadium(V) ethoxydichloride 1.) Et2O, RT, 1 h, 2.) Et2O, reflux, 2 h; Yield given. Multistep reaction; |
|
Yield | Reaction Conditions | Operation in experiment |
|
Katalyt. Dehydrierung; |
|
|
Verhalten gegen Elektronenstrahlen; |
|
Yield | Reaction Conditions | Operation in experiment |
|
With phosphorus pentoxide |
|
- 16
-
[ 74-96-4 ]

-
[ 1812-51-7 ]
Yield | Reaction Conditions | Operation in experiment |
|
With iodine 1.) THF, RT, 2.) a) -78 deg C, 3 h, b) RT, 3 h; Yield given. Multistep reaction; |
|
Yield | Reaction Conditions | Operation in experiment |
|
With sulfur at 210 - 240℃; |
|
Yield | Reaction Conditions | Operation in experiment |
|
With sulfur at 210 - 240℃; |
|
- 19
-
[ 1812-51-7 ]

-
[ 86-73-7 ]

-
[ 85-01-8 ]

-
[ 2523-37-7 ]
Yield | Reaction Conditions | Operation in experiment |
|
at 475 - 480℃; |
|
- 20
-
[ 16927-84-7 ]

-
[ 1812-51-7 ]
Yield | Reaction Conditions | Operation in experiment |
|
at 200℃; |
|
- 21
-
1-ethyl-2-phenyl-cyclohexene
[ No CAS ]

-
[ 1812-51-7 ]
Yield | Reaction Conditions | Operation in experiment |
|
at 210 - 240℃; |
|
- 22
-
[ 101433-57-2 ]

-
[ 1812-51-7 ]

-
[ 100-41-4 ]

-
[ 85-01-8 ]

-
[ 32658-82-5 ]
Yield | Reaction Conditions | Operation in experiment |
|
at 320℃; |
|
- 23
-
[ 23533-35-9 ]

-
[ 1812-51-7 ]
Yield | Reaction Conditions | Operation in experiment |
|
Multi-step reaction with 2 steps
1: diethyl ether
2: copper chromite / 200 °C / 102971 Torr / Hydrogenolyse |
|
- 24
-
[ 92495-58-4 ]

-
[ 75-16-1 ]

-
[ 1812-51-7 ]
Yield | Reaction Conditions | Operation in experiment |
86% |
In diethyl ether; toluene at 80℃; for 10h; |
|
Reference:
[1]Guan, Bing-Tao; Xiang, Shi-Kai; Wang, Bi-Qin; Sun, Zuo-Peng; Wang, Yang; Zhao, Ke-Qing; Shi, Zhang-Jie
[Journal of the American Chemical Society, 2008, vol. 130, # 11, p. 3268 - 3269]
- 25
-
[ 591-50-4 ]

-
[ 90002-36-1 ]

-
[ 1812-51-7 ]
- 26
-
[ 100-41-4 ]

-
[ 66003-76-7 ]

-
[ 5668-93-9 ]

-
[ 1812-51-7 ]

-
[ 5707-44-8 ]
- 27
-
[ 120-12-7 ]

-
[ 1812-51-7 ]
Yield | Reaction Conditions | Operation in experiment |
31% |
With carbon dioxide; water; hydrogen; sulfur at 415℃; Molecular sieve; High pressure; |
|
Reference:
[1]Fan, Honglei; Wu, Tianbin; Yang, Guanying; Zhang, Peng; Ding, Guodong; Wang, Weitao; Jiang, Tao; Han, Buxing
[Catalysis Communications, 2013, vol. 33, p. 42 - 46]
- 28
-
[ 66950-63-8 ]

-
[ 1519010-69-5 ]

-
[ 1812-51-7 ]
Yield | Reaction Conditions | Operation in experiment |
33% |
With NiCl2(Tris-(4-methoxy-phenyl)-phosphin)2; potassium phosphate tribasic trihydrate; P(p-CH3OC6H4)3 In toluene at 110℃; for 10h; Inert atmosphere; |
|
- 29
-
[ 7677-24-9 ]

-
[ 1812-51-7 ]

-
C15H13N
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
39% |
With C23H26N2O2; copper (I) acetate; N-fluorobis(benzenesulfon)imide In benzene at 20℃; Inert atmosphere; enantioselective reaction; |
|
Reference:
[1]Zhang, Wen; Wang, Fei; McCann, Scott D.; Wang, Dinghai; Chen, Pinhong; Stahl, Shannon S.; Liu, Guosheng
[Science, 2016, vol. 353, # 6303, p. 1014 - 1018]
- 30
-
[ 18282-40-1 ]

-
[ 98-80-6 ]

-
[ 1812-51-7 ]
Yield | Reaction Conditions | Operation in experiment |
87% |
With bis-triphenylphosphine-palladium(II) chloride; potassium carbonate In water; N,N-dimethyl-formamide at 60℃; for 18h; |
|
65% |
With bis-triphenylphosphine-palladium(II) chloride; potassium carbonate In water; N,N-dimethyl-formamide at 60℃; for 24h; |
|
Reference:
[1]Hill, Richard R.; Rychnovsky, Scott D.
[Journal of Organic Chemistry, 2016, vol. 81, # 22, p. 10707 - 10714]
[2]Meng, Qing-Yuan; Schirmer, Tobias E.; Berger, Anna Lucia; Donabauer, Karsten; König, Burkhard
[Journal of the American Chemical Society, 2019, vol. 141, # 29, p. 11393 - 11397]
- 31
-
[ 507-20-0 ]

-
[ 1812-51-7 ]

-
4,4′-di-tert-butyl-2-ethyl-1,1′-biphenyl
[ No CAS ]
Yield | Reaction Conditions | Operation in experiment |
2% |
With aluminum (III) chloride In nitromethane for 0.0833333h; |
|
- 32
-
[ 1973-22-4 ]

-
[ 98-80-6 ]

-
[ 1812-51-7 ]
Yield | Reaction Conditions | Operation in experiment |
96% |
With bis-triphenylphosphine-palladium(II) chloride; potassium carbonate In 1,2-dimethoxyethane; water at 80℃; Inert atmosphere; |
|
|
With C25H29FeI2N3OPd; sodium carbonate In N,N-dimethyl-formamide at 100℃; for 19h; Schlenk technique; Sealed tube; |
4.13. General procedure for the Suzuki-Miyaura cross-couplingreactions
General procedure: 1.0 mmol of halobenzene, 1.0 mmol of phenyl boronic acid, andthe prescribed amount of catalyst (0.5% mol) in 5 mL of DMF wereintroduced into a Schlenk tube in the open air. The tube wascharged with a magnetic stir bar and an equimolar amount of base(Na2CO3, 2 mmol), and sealed, then fully immersed in a 100 °Csilicon oil bath. After the prescribed reaction time, the mixture wascooled to room temperature. Water was added (20 mL). Whitesuspension was extracted with dichloromethane (3 x 50 mL). Theorganic phase was washed once again with water, separated and treated with anhydrous MgSO4, filtered and analyzed by gas chromatography(GC-MS). The results presented are the average of tworuns. |
72 %Chromat. |
With potassium carbonate In ethanol; water at 70℃; for 0.75h; |
|
57 %Chromat. |
With C36H36Cl2Fe2NPPd; sodium carbonate In N,N-dimethyl-formamide at 100℃; for 18h; Inert atmosphere; Schlenk technique; |
5.General procedure for the Suzuki-Miyaura cross-coupling reactions
General procedure: In a Schlenk tube under N 2 1.0 mmol of aryl bromide, 1.0 mmol of aryl boronic acid, and 0.5 or 0.25% mol of catalyst in 5 mL of DMF were introduced into a Schlenk tube. The tube was charged with a magnetic stir bar and base (Na 2 CO 3 , 2 mmol), and sealed, then fully immersed in a 100 °C oil bath. After 18 hrs, the mix- ture was cooled to room temperature. Water was added (20 mL). The white suspension was extracted with dichloromethane (3 ×50 mL). The organic phase was washed once again with water, sepa- rated and treated with anhydrous MgSO 4 , filtered, and analyzed by gas chromatography (GC-MS). The results presented are the aver- age of two runs. |

Reference:
[1]Liu, Shuai; Achou, Raphaël; Boulanger, Coline; Pawar, Govind; Kumar, Nivesh; Lusseau, Jonathan; Robert, Frédéric; Landais, Yannick
[Chemical Communications, 2020, vol. 56, # 85, p. 13013 - 13016]
[2]Azpiroz, Ramón; Sharma, Pankaj; Javier Pérez-Flores; Gutierrez, René; Espinosa-Pérez, Georgina; Lara-Ochoa, Francisco
[Journal of Organometallic Chemistry, 2017, vol. 848, p. 196 - 206]
[3]Jamwal, Babita; Kaur, Manpreet; Sharma, Harsha; Khajuria, Chhavi; Paul, Satya; Clark
[New Journal of Chemistry, 2019, vol. 43, # 12, p. 4919 - 4928]
[4]Anzaldo, Bertin; Gaviño, Ruben; Gutiérrez, René; Sharma, Pankaj; Toscano, Alfredo R.; Villamizar C, Claudia P.
[Journal of Organometallic Chemistry, 2020, vol. 929]