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[ CAS No. 1812-51-7 ] {[proInfo.proName]}

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Chemical Structure| 1812-51-7
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Product Details of [ 1812-51-7 ]

CAS No. :1812-51-7 MDL No. :MFCD30296301
Formula : C14H14 Boiling Point : -
Linear Structure Formula :- InChI Key :DLMYHUARHITGIJ-UHFFFAOYSA-N
M.W : 182.26 Pubchem ID :15742
Synonyms :

Safety of [ 1812-51-7 ]

Signal Word:Warning Class:
Precautionary Statements:P280-P305+P351+P338 UN#:
Hazard Statements:H302 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 1812-51-7 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 1812-51-7 ]

[ 1812-51-7 ] Synthesis Path-Downstream   1~42

  • 1
  • [ 64-67-5 ]
  • [ 23533-35-9 ]
  • [ 1812-51-7 ]
YieldReaction ConditionsOperation in experiment
With diethyl ether
  • 2
  • [ 1812-51-7 ]
  • [ 86-73-7 ]
YieldReaction ConditionsOperation in experiment
With palladium on activated charcoal at 475 - 490℃;
Multi-step reaction with 2 steps 1: palladium coal / 475 - 480 °C 2: palladium coal / 475 - 490 °C
  • 3
  • [ 1812-51-7 ]
  • [ 2523-37-7 ]
YieldReaction ConditionsOperation in experiment
With palladium on activated charcoal at 475 - 480℃;
  • 4
  • [ 1812-51-7 ]
  • (+/-)-<i>trans</i>-2-ethyl-bicyclohexyl [ No CAS ]
  • (+/-)-<i>cis</i>-2-ethyl-bicyclohexyl [ No CAS ]
YieldReaction ConditionsOperation in experiment
With nickel; methyl cyclohexane at 200℃; Hydrogenation;
  • 5
  • [ 16927-84-7 ]
  • [ 1812-51-7 ]
YieldReaction ConditionsOperation in experiment
With copper chromite at 200℃; Hydrogenolyse;
  • 6
  • [ 100-41-4 ]
  • [ 94-36-0 ]
  • [ 1812-51-7 ]
  • 2,3-diphenylbutane [ No CAS ]
  • [ 65-85-0 ]
  • [ 71-43-2 ]
YieldReaction ConditionsOperation in experiment
at 75℃;
  • 7
  • [ 17333-73-2 ]
  • [ 100-41-4 ]
  • [ 5668-93-9 ]
  • [ 1812-51-7 ]
  • [ 5707-44-8 ]
  • 8
  • [ 1812-51-7 ]
  • [ 5707-44-8 ]
  • 9
  • [ 2180-20-3 ]
  • [ 1165952-91-9 ]
  • [ 108-88-3 ]
  • [ 6294-31-1 ]
  • [ 10496-15-8 ]
  • [ 16823-61-3 ]
  • [ 1812-51-7 ]
  • [ 34005-03-3 ]
  • 1-hexenyl hexyl sulfide [ No CAS ]
YieldReaction ConditionsOperation in experiment
1: 34 % Chromat. 2: 34 % Chromat. 3: 5 % Chromat. 4: 17 % Chromat. 5: 4 % Chromat. 6: 6 % Chromat. With aluminum oxide; Ni(acac) at 200℃; for 12h; other dialkyl sulfoxides and 1,3-dienes; var. metal complexes and ligands; var. stoichiometry;
  • 10
  • [ 2180-20-3 ]
  • [ 108-88-3 ]
  • [ 6294-31-1 ]
  • [ 1812-51-7 ]
  • [ 34005-03-3 ]
  • 1-hexenyl hexyl sulfide [ No CAS ]
YieldReaction ConditionsOperation in experiment
1: 34 % Chromat. 2: 17 % Chromat. 3: 5 % Chromat. 4: 34 % Chromat. With aluminum oxide; bis(acetylacetonate)nickel(II) In toluene at 150℃; for 12h; Further byproducts given;
  • 11
  • [ 100-41-4 ]
  • [ 71-43-2 ]
  • [ 92-52-4 ]
  • [ 5668-93-9 ]
  • [ 1812-51-7 ]
  • [ 5707-44-8 ]
  • [ 13049-40-6 ]
  • [ 13049-39-3 ]
  • 12
  • [ 96-10-6 ]
  • [ 55365-18-9 ]
  • [ 1812-51-7 ]
YieldReaction ConditionsOperation in experiment
With oxovanadium(V) ethoxydichloride 1.) Et2O, RT, 1 h, 2.) Et2O, reflux, 2 h; Yield given. Multistep reaction;
YieldReaction ConditionsOperation in experiment
Katalyt. Dehydrierung;
Verhalten gegen Elektronenstrahlen;
YieldReaction ConditionsOperation in experiment
With phosphorus pentoxide
  • 16
  • [ 74-96-4 ]
  • [ 1812-51-7 ]
YieldReaction ConditionsOperation in experiment
With iodine 1.) THF, RT, 2.) a) -78 deg C, 3 h, b) RT, 3 h; Yield given. Multistep reaction;
YieldReaction ConditionsOperation in experiment
With sulfur at 210 - 240℃;
YieldReaction ConditionsOperation in experiment
With sulfur at 210 - 240℃;
  • 19
  • [ 1812-51-7 ]
  • [ 86-73-7 ]
  • [ 85-01-8 ]
  • [ 2523-37-7 ]
YieldReaction ConditionsOperation in experiment
at 475 - 480℃;
  • 20
  • [ 16927-84-7 ]
  • [ 1812-51-7 ]
YieldReaction ConditionsOperation in experiment
at 200℃;
  • 21
  • 1-ethyl-2-phenyl-cyclohexene [ No CAS ]
  • [ 1812-51-7 ]
YieldReaction ConditionsOperation in experiment
at 210 - 240℃;
  • 22
  • [ 101433-57-2 ]
  • [ 1812-51-7 ]
  • [ 100-41-4 ]
  • [ 85-01-8 ]
  • [ 32658-82-5 ]
YieldReaction ConditionsOperation in experiment
at 320℃;
  • 23
  • [ 23533-35-9 ]
  • [ 1812-51-7 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: diethyl ether 2: copper chromite / 200 °C / 102971 Torr / Hydrogenolyse
  • 24
  • [ 92495-58-4 ]
  • [ 75-16-1 ]
  • [ 1812-51-7 ]
YieldReaction ConditionsOperation in experiment
86% In diethyl ether; toluene at 80℃; for 10h;
  • 25
  • [ 591-50-4 ]
  • [ 90002-36-1 ]
  • [ 1812-51-7 ]
  • 26
  • [ 100-41-4 ]
  • [ 66003-76-7 ]
  • [ 5668-93-9 ]
  • [ 1812-51-7 ]
  • [ 5707-44-8 ]
  • 27
  • [ 120-12-7 ]
  • [ 1812-51-7 ]
YieldReaction ConditionsOperation in experiment
31% With carbon dioxide; water; hydrogen; sulfur at 415℃; Molecular sieve; High pressure;
  • 28
  • [ 66950-63-8 ]
  • [ 1519010-69-5 ]
  • [ 1812-51-7 ]
YieldReaction ConditionsOperation in experiment
33% With NiCl2(Tris-(4-methoxy-phenyl)-phosphin)2; potassium phosphate tribasic trihydrate; P(p-CH3OC6H4)3 In toluene at 110℃; for 10h; Inert atmosphere;
  • 29
  • [ 7677-24-9 ]
  • [ 1812-51-7 ]
  • C15H13N [ No CAS ]
YieldReaction ConditionsOperation in experiment
39% With C23H26N2O2; copper (I) acetate; N-fluorobis(benzenesulfon)imide In benzene at 20℃; Inert atmosphere; enantioselective reaction;
  • 30
  • [ 18282-40-1 ]
  • [ 98-80-6 ]
  • [ 1812-51-7 ]
YieldReaction ConditionsOperation in experiment
87% With bis-triphenylphosphine-palladium(II) chloride; potassium carbonate In water; N,N-dimethyl-formamide at 60℃; for 18h;
65% With bis-triphenylphosphine-palladium(II) chloride; potassium carbonate In water; N,N-dimethyl-formamide at 60℃; for 24h;
  • 31
  • [ 507-20-0 ]
  • [ 1812-51-7 ]
  • 4,4′-di-tert-butyl-2-ethyl-1,1′-biphenyl [ No CAS ]
YieldReaction ConditionsOperation in experiment
2% With aluminum (III) chloride In nitromethane for 0.0833333h;
  • 32
  • [ 1973-22-4 ]
  • [ 98-80-6 ]
  • [ 1812-51-7 ]
YieldReaction ConditionsOperation in experiment
96% With bis-triphenylphosphine-palladium(II) chloride; potassium carbonate In 1,2-dimethoxyethane; water at 80℃; Inert atmosphere;
With C25H29FeI2N3OPd; sodium carbonate In N,N-dimethyl-formamide at 100℃; for 19h; Schlenk technique; Sealed tube; 4.13. General procedure for the Suzuki-Miyaura cross-couplingreactions General procedure: 1.0 mmol of halobenzene, 1.0 mmol of phenyl boronic acid, andthe prescribed amount of catalyst (0.5% mol) in 5 mL of DMF wereintroduced into a Schlenk tube in the open air. The tube wascharged with a magnetic stir bar and an equimolar amount of base(Na2CO3, 2 mmol), and sealed, then fully immersed in a 100 °Csilicon oil bath. After the prescribed reaction time, the mixture wascooled to room temperature. Water was added (20 mL). Whitesuspension was extracted with dichloromethane (3 x 50 mL). Theorganic phase was washed once again with water, separated and treated with anhydrous MgSO4, filtered and analyzed by gas chromatography(GC-MS). The results presented are the average of tworuns.
72 %Chromat. With potassium carbonate In ethanol; water at 70℃; for 0.75h;
57 %Chromat. With C36H36Cl2Fe2NPPd; sodium carbonate In N,N-dimethyl-formamide at 100℃; for 18h; Inert atmosphere; Schlenk technique; 5.General procedure for the Suzuki-Miyaura cross-coupling reactions General procedure: In a Schlenk tube under N 2 1.0 mmol of aryl bromide, 1.0 mmol of aryl boronic acid, and 0.5 or 0.25% mol of catalyst in 5 mL of DMF were introduced into a Schlenk tube. The tube was charged with a magnetic stir bar and base (Na 2 CO 3 , 2 mmol), and sealed, then fully immersed in a 100 °C oil bath. After 18 hrs, the mix- ture was cooled to room temperature. Water was added (20 mL). The white suspension was extracted with dichloromethane (3 ×50 mL). The organic phase was washed once again with water, sepa- rated and treated with anhydrous MgSO 4 , filtered, and analyzed by gas chromatography (GC-MS). The results presented are the aver- age of two runs.

  • 33
  • [ 108-86-1 ]
  • [ 1812-51-7 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1.1: magnesium / tetrahydrofuran / 1.08 h / 20 °C / Inert atmosphere; Reflux 1.2: 16 h / 0 - 20 °C / Inert atmosphere 2.1: (triphenylphosphine)gold(I) chloride / acetonitrile / 16 h / 20 °C / Inert atmosphere
  • 34
  • [ 960-16-7 ]
  • o-ethylbenzenediazonium tetrafluoroborate [ No CAS ]
  • [ 1812-51-7 ]
YieldReaction ConditionsOperation in experiment
49 %Spectr. With (triphenylphosphine)gold(I) chloride In acetonitrile at 20℃; for 16h; Inert atmosphere;
  • 35
  • [ 18282-40-1 ]
  • potassium phenyltrifluoborate [ No CAS ]
  • [ 1812-51-7 ]
YieldReaction ConditionsOperation in experiment
61% With choline chloride; palladium diacetate; sodium carbonate; glycerol at 60℃; for 5h;
  • 36
  • [ 1973-22-4 ]
  • [ 591-51-5 ]
  • [ 1812-51-7 ]
YieldReaction ConditionsOperation in experiment
98% With bis(tri-t-butylphosphine)palladium(0); water; sodium chloride In dibutyl ether at 20℃; for 0.00555556h; Schlenk technique;
  • 37
  • [ 92-52-4 ]
  • [ 1812-51-7 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: ammonia; lithium / tetrahydrofuran / 1 h / -78 °C 2: trityl tetrakis(pentafluorophenyl)borate / dichloromethane / 72 h / 20 °C / Schlenk technique
  • 38
  • 1-ethyl-1,4-dihydro-1,1'-biphenyl [ No CAS ]
  • [ 1812-51-7 ]
YieldReaction ConditionsOperation in experiment
78% With trityl tetrakis(pentafluorophenyl)borate In dichloromethane at 20℃; for 72h; Schlenk technique;
  • 39
  • [ 1812-51-7 ]
  • [ 124-38-9 ]
  • [ 126489-67-6 ]
YieldReaction ConditionsOperation in experiment
64% With (4s,6s)-2,4,5,6-tetra(9H-carbazol-9-yl)isophthalonitrile; triisopropylsilanethiol In N,N-dimethyl-formamide at 0℃; for 24h; Irradiation; Sealed tube;
  • 40
  • [ 188290-36-0 ]
  • [ 622-76-4 ]
  • [ 1812-51-7 ]
YieldReaction ConditionsOperation in experiment
43% With 9-(2-mesityl)-10-methylacridinium perchlorate In acetonitrile at 20℃; for 12h; Irradiation; Inert atmosphere; Schlenk technique; regioselective reaction;
  • 41
  • [ 945-51-7 ]
  • [ 90002-36-1 ]
  • [ 1812-51-7 ]
YieldReaction ConditionsOperation in experiment
85% With SIPr-PdCl<SUB>2</SUB>-Py; sodium t-butanolate In tetrahydrofuran at 70℃; for 12h; Inert atmosphere;
  • 42
  • [ 1812-51-7 ]
  • [ 51-79-6 ]
  • ethyl (1-([1,1'-biphenyl]-2-yl)ethyl)carbamate [ No CAS ]
YieldReaction ConditionsOperation in experiment
52% With 2,2'-isopropylidenebis[(4S)-4-tert-butyl-2-oxazoline]; N-fluorobis(benzenesulfon)imide; copper(l) chloride In acetonitrile at 60℃; for 24h; Glovebox; Inert atmosphere; Sealed tube;
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