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[ CAS No. 19654-14-9 ]

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2D
Chemical Structure| 19654-14-9
Chemical Structure| 19654-14-9
Structure of 19654-14-9 *Storage: {[proInfo.prStorage]}

Quality Control of [ 19654-14-9 ]

Purity: {[proInfo.showProBatch.pb_purity]}

Related Doc. of [ 19654-14-9 ]

SDS

Product Details of [ 19654-14-9 ]

CAS No. :19654-14-9MDL No. :MFCD00579076
Formula :C13H8BrNSBoiling Point :-
Linear Structure Formula :-InChI Key :N/A
M.W :290.18Pubchem ID :6382460
Synonyms :

Computed Properties of [ 19654-14-9 ]

TPSA : 41.1 H-Bond Acceptor Count : 2
XLogP3 : - H-Bond Donor Count : 0
SP3 : 0.00 Rotatable Bond Count : 1

Safety of [ 19654-14-9 ]

Signal Word:WarningClassN/A
Precautionary Statements:P261-P280-P305 P351 P338UN#:N/A
Hazard Statements:H302-H315-H319-H332-H335Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 19654-14-9 ]

  • Downstream synthetic route of [ 19654-14-9 ]

[ 19654-14-9 ] Synthesis Path-Downstream   1~10

YieldReaction ConditionsOperation in experiment
90% With water; caesium carbonate; for 0.166667h;Microwave irradiation; General procedure: Add 2 ml of water to the microwave reactor,1 mmol of benzothioamide and 0.2 mmol of cesium carbonate,Reacted at a fixed power of 120 W for 10 min,Extracted with ethyl acetate and concentrated under reduced pressure.To give a pale yellow solid, yield 99%.
87% With potassium thioacyanate; sodium hydroxide; In water; at 100.0℃; for 0.5h;Microwave irradiation; General procedure: In the reaction vessel, 2-iodoaniline (1 mmol), 4-methylbenzaldehyde (1 mmol), potassium thiocyanate (2.4 mmol), nickel/proline lithium complex (0.05 mmol), sodium hydroxide (1 mmol), and water (3 mL) were added.After being placed under the microwave reactor,Set in a microwave reactor to 100 C was heated for 30 minutes at 150 W power, cooled to room temperature.The product was extracted with ethyl acetate and concentrated under reduced pressure. The product was purified by column chromatography to give a white solid in 93% yield.
78% With acetic acid; at 20.0℃; for 0.333333h; General procedure: Add 1 ml of catalytic amount of glacial acetic acid to the mortar.1 mmol of o-aminophenol,1.2 mmol of benzaldehyde was rapidly ground at room temperature for 20 minutes.The product was extracted with ethyl acetate and water.Reduced pressure,The product was purified by column chromatography to give a pale yellow solid.The yield was 88%.
  • 2
  • 10-propyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-10H-phenothiazine [ No CAS ]
  • [ 19654-14-9 ]
  • C28H22N2S2 [ No CAS ]
  • 3
  • [ 2401-24-3 ]
  • [ 19654-14-9 ]
  • N-(3-(benzo[d]thiazol-2-yl)phenyl)-2-chloro-5-methoxyaniline [ No CAS ]
  • 4
  • [ 504-29-0 ]
  • [ 19654-14-9 ]
  • N-(3-(benzo[d]thiazol-2-yl)phenyl)pyridin-2-amine [ No CAS ]
  • 5
  • [ 934603-99-3 ]
  • [ 19654-14-9 ]
  • C69H51IrN2O2S2 [ No CAS ]
  • 6
  • [ 6952-59-6 ]
  • [ 137-07-5 ]
  • [ 19654-14-9 ]
YieldReaction ConditionsOperation in experiment
85% With trifluorormethanesulfonic acid; In neat (no solvent); at 100.0℃; for 12.0h; General procedure: A reaction flask was charged with a mixture of 1a (3.0 mmol), 2a (3.0 mmol), TfOH (0.06 mmol). The reaction mixture was stirred at 100 oC for 12 h, and then was cooled to room temperature. Water (10 mL) was added to the resultant mixture. The product was extracted with CH2Cl2 (10 mL × 2). The solvent was removed under reduced pressure, and the residue obtained was purified via silica gel chromatography (eluent: petroleum ether/ethyl acetate = 50:1) to afford the product 3a (595.8mg, 94% yield) as a white solid.
  • 7
  • [ 1711-09-7 ]
  • [ 19654-14-9 ]
  • 8
  • [ 62-53-3 ]
  • [ 19654-14-9 ]
  • 9
  • [ 19654-14-9 ]
  • [ 73183-34-3 ]
  • [ 1316275-52-1 ]
  • 10
  • [ 19654-14-9 ]
  • C45H29N3S2 [ No CAS ]
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