Home Cart 0 Sign in  

[ CAS No. 26158-00-9 ]

{[proInfo.proName]}
Cat. No.: {[proInfo.prAm]}
HazMat Fee +

There will be a HazMat fee per item when shipping a dangerous goods. The HazMat fee will be charged to your UPS/DHL/FedEx collect account or added to the invoice unless the package is shipped via Ground service. Ship by air in Excepted Quantity (each bottle), which is up to 1g/1mL for class 6.1 packing group I or II, and up to 25g/25ml for all other HazMat items.

type HazMat fee
Excepted Quantity Free
Ground (Domestic only) Free
Inaccessible (Haz class 6.1), Domestic USD 41.00
Inaccessible (Haz class 6.1), International USD 64.00
Accessible (Haz class 3, 4, 5 or 8), Domestic USD 83.00
Accessible (Haz class 3, 4, 5 or 8), International USD 133.00
2D
Chemical Structure| 26158-00-9
Chemical Structure| 26158-00-9
Structure of 26158-00-9 *Storage: {[proInfo.prStorage]}

Quality Control of [ 26158-00-9 ]

Purity: {[proInfo.showProBatch.pb_purity]}

Related Doc. of [ 26158-00-9 ]

SDS

Product Details of [ 26158-00-9 ]

CAS No. :26158-00-9MDL No. :MFCD00149976
Formula :C6H8O4SBoiling Point :-
Linear Structure Formula :-InChI Key :MVIOINXPSFUJEN-UHFFFAOYSA-N
M.W :176.19Pubchem ID :15619088
Synonyms :

Computed Properties of [ 26158-00-9 ]

TPSA : - H-Bond Acceptor Count : -
XLogP3 : - H-Bond Donor Count : -
SP3 : - Rotatable Bond Count : -

Safety of [ 26158-00-9 ]

Signal Word:DangerClass8
Precautionary Statements:P280-P305+P351+P338-P310UN#:2585
Hazard Statements:H302+H312+H332-H314Packing Group:
GHS Pictogram:

Application In Synthesis of [ 26158-00-9 ]

  • Downstream synthetic route of [ 26158-00-9 ]

[ 26158-00-9 ] Synthesis Path-Downstream   1~10

  • 1
  • [ 26158-00-9 ]
  • [ 512-35-6 ]
  • 2
  • [ 26158-00-9 ]
  • [ 125602-71-3 ]
  • [ 125602-71-3 ]
YieldReaction ConditionsOperation in experiment
67.3% In ethyl acetate; (S) -4- [4-[(4-chlorophenyl) (2-pyridyl) methoxy] piperidino] butanoic acid 0.5 g (1.29mmol) Obtained according to Reference Example 5 was dissolved in ethyl acetate25 ml, and then benzene sulfonic acid monohydrate 0.20g (1.14mmol) was addedand concentrated under reduced pressure. ethyl acetate 25ml was again added tothe residue and allowed to stand for about 1 week, and the part of thecandy-like material is crystallized. Mixed with a spatula, further allowed tostand and the entire was crystallized. The crystals were recrystallized fromacetonitrile 5ml, and the desired product 0.42g (yield: 67.3%, optical purity:99.2% ee) was obtained as a pale gray prism crystal. [alpha] D20+ 6.0 (c = 5, MeOH). Melting point: 161 ~ 163 C
  • 3
  • 7-acetyl-N-(5-((3-methoxyazetidin-1-yl)carbonyl)quinolin-2-yl)-4-(methoxymethyl)-3-methylbenzo[b]thiophene-2-carboxamide [ No CAS ]
  • [ 26158-00-9 ]
  • 7-acetyl-N-(5-((3-methoxyazetidin-1-yl)carbonyl)quinolin-2-yl)-4-(methoxymethyl)-3-methylbenzo[b]thiophene-2-carboxamide benzenesulfonate [ No CAS ]
YieldReaction ConditionsOperation in experiment
In methanol; Example 104 7-Acetyl-N-(5-((3-methoxyazetidin-1-yl)carbonyl)quinolin-2-yl)-4-(methoxymethyl)-3-methylbenzo[b]thiophene-2-carboxamide benzenesulfonate To a suspension of the compound (1.10 g) obtained in Example 102 in methanol (5.5 mL), [26158-00-9]benzenesulfonic acid monohydrate (412 mg) was added at room temperature, and the mixture was heated to 70 C., then cooled to room temperature, and stirred overnight. The reaction mixture was cooled to 4 C., and the precipitated solid was collected by filtration to obtain the title compound (1.176 g). 1H NMR (CDCl3, 400 MHz): delta (ppm) 9.11-9.18 (m, 1H), 8.87 (d, J=9.8 Hz, 1H), 8.43-8.51 (m, 1H), 8.09 (d, J=7.5 Hz, 1H), 7.83-7.93 (m, 3H), 7.69-7.74 (m, 1H), 7.62 (d, J=7.8 Hz, 1H), 7.25-7.35 (m, 5H), 4.95 (s, 2H), 4.44-4.53 (m, 1H), 4.26-4.33 (m, 1H), 4.15-4.22 (m, 2H), 3.94-4.01 (m, 1H), 3.49 (s, 3H), 3.33 (s, 3H), 2.93 (s, 3H), 2.78 (s, 3H) MS (ESI+) m/z: 518 [M+H]+
  • 4
  • [ 153051-52-6 ]
  • [ 26158-00-9 ]
  • [MoO(O3SC6H5)(C56H52N4)] [ No CAS ]
  • 5
  • [ 73515-72-7 ]
  • [ 26158-00-9 ]
  • benzenesulfonato(5,10,15,20-meso-tetraphenylporphyrinato)oxomolybdenum(V) [ No CAS ]
  • 6
  • [ 288-13-1 ]
  • copper(II) perchlorate hexahydrate [ No CAS ]
  • [ 1934-75-4 ]
  • [ 26158-00-9 ]
  • catena-[Cu2(Cu(di(pyrazolecarbimido)aminate)2)(pyrazole)2(PhSO3)2](PhSO3)2*4H2O [ No CAS ]
  • 7
  • [ 26158-00-9 ]
  • [ 882-33-7 ]
  • 8
  • [ 26158-00-9 ]
  • [ 108-98-5 ]
  • 9
  • [ 219536-98-8 ]
  • [ 26158-00-9 ]
  • 10-hydroxymethyl-1,2,3,4-tetrahydro-benzo[b][1,6]-naphthyridine dibenzenesulfonate [ No CAS ]
YieldReaction ConditionsOperation in experiment
In methanol; EXAMPLE 13 Synthesis of 10-hydroxymethyl-1,2,3,4-tetrahydro-benzo[b][1,6]-naphthyridine dibenzenesulfonate 2-t-Butoxycarbonyl-10-hydroxymethyl-1,2,3,4-tetrahydro-benzo[b][1,6]-naphthyridine (202 mg, 0.643 mmol) was dissolved in methanol (1.3 ml), followed by adding thereto [26158-00-9]benzenesulfonic acid monohydrate (226.3 mg, 1.285 mmol), and the resulting mixture was heated under reflux at 70 C. for 3 hours. The reaction mixture was cooled to room temperature and then concentrated under reduced pressure to obtain the desired compound (361.2 mg, quant.) as a brown substance. 1H-NMR (200 MHzFT, TMS, CD3OD); 3.58-3.85 (4H, complex), 4.97 (2H, s), 5.22 (2H, s), 7.24-7.45 (6H, m), 7.64-7.80 (4H, m), 7.90-8.01 (1H, m), 8.09-8.16 (2H, complex), 8.59 (1H, d, J=8.6 Hz). MS (FAB, m-NBA) m/z 215?[M+H]+.
  • 10
  • [ 26158-00-9 ]
  • [ 84855-57-2 ]
  • [ 84855-88-9 ]
YieldReaction ConditionsOperation in experiment
74.8% EXAMPLE 1 Two grams of 1-diazo-3-methyl-4-cyclohexyl-2-butanone is dissolved in 50 ml of ether, 2.1 g of [26158-00-9]benzene-sulfonic acid monohydrate is slowly added to the solution at room temperature, and the mixture is stirred until evolution of nitrogen ceases. After the reaction, the ethereal layer is washed with water, dired over anhydrous sodium sulfate and distilled in a vacuum to remove the solvent. The resulting oily product is separated and purified by column chromatography (silica gel, developer solvent: chloroform), giving 2.5 g of 1-benzenesulfonyloxy-4-cyclohexyl-3-methyl-2-butanone (Compound 1) melting at 51 to 52 C. (yield: 74.8%).
Historical Records

Related Functional Groups of
[ 26158-00-9 ]

Sulfonic Acids

Chemical Structure| 98-11-3

[ 98-11-3 ]

Benzenesulfonic acid

Similarity: 1.00

Chemical Structure| 7134-41-0

[ 7134-41-0 ]

4-Mercaptobenzenesulfonic acid

Similarity: 1.00

Chemical Structure| 581-75-9

[ 581-75-9 ]

Naphthalene-2,6-disulfonic acid

Similarity: 0.94

Chemical Structure| 6036-00-6

[ 6036-00-6 ]

2-Naphthalenesulfonicacidhydrate

Similarity: 0.94

Chemical Structure| 6036-48-2

[ 6036-48-2 ]

Naphthalene-1-sulfonic acid hydrate

Similarity: 0.91

Aryls

Chemical Structure| 98-11-3

[ 98-11-3 ]

Benzenesulfonic acid

Similarity: 1.00

Chemical Structure| 7134-41-0

[ 7134-41-0 ]

4-Mercaptobenzenesulfonic acid

Similarity: 1.00

Chemical Structure| 831-59-4

[ 831-59-4 ]

Sodium benzene-1,3-disulfonate

Similarity: 0.94

Chemical Structure| 581-75-9

[ 581-75-9 ]

Naphthalene-2,6-disulfonic acid

Similarity: 0.94

Chemical Structure| 6036-00-6

[ 6036-00-6 ]

2-Naphthalenesulfonicacidhydrate

Similarity: 0.94