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[ CAS No. 35051-49-1 ] {[proInfo.proName]}

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Type HazMat fee for 500 gram (Estimated)
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3d Animation Molecule Structure of 35051-49-1
Chemical Structure| 35051-49-1
Chemical Structure| 35051-49-1
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Product Details of [ 35051-49-1 ]

CAS No. :35051-49-1 MDL No. :MFCD00015163
Formula : C11H23O5P Boiling Point : -
Linear Structure Formula :(CH3CH2O)2POCH(CH2)2CH3CO2CH2CH3 InChI Key :BUPVIVDUPRDDFI-UHFFFAOYSA-N
M.W : 266.27 Pubchem ID :98244
Synonyms :

Safety of [ 35051-49-1 ]

Signal Word:Danger Class:6.1
Precautionary Statements:P261-P280-P301+P310-P311 UN#:3278
Hazard Statements:H301+H311+H331 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 35051-49-1 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 35051-49-1 ]

[ 35051-49-1 ] Synthesis Path-Downstream   1~4

  • 1
  • [ 615-83-8 ]
  • [ 122-52-1 ]
  • [ 35051-49-1 ]
YieldReaction ConditionsOperation in experiment
68% at 165℃; for 4h; Inert atmosphere; General procedure for Arbuzov reaction General procedure: Ethyl 2-(diethoxyphosphoryl)-4-(1,3-dioxoisoindolin-2-yl)butanoate (19a): Compound 17 (0.97 g, 2.85 mmol) was mixed with triethyl phosphite (0.95 mL, 0.907 g, 5.46 mmol, 1.92 eq) and heated on oil bath (165 °C) for 4 h under argon. The reaction mixture was distilled bulb-to-bulb under vacuo, giving product as yellow dense oil.
65% at 180℃; for 2h;
at 160 - 190℃;
  • 2
  • [ 35051-49-1 ]
  • [ 5736-88-9 ]
  • CH3(CH2)3OC6H4C2H(CH2)2CH3CO2CH2CH3 [ No CAS ]
  • 3
  • [ 615-83-8 ]
  • [ 35051-49-1 ]
YieldReaction ConditionsOperation in experiment
With triethyl phosphite 4.A Triethyl 2-Phosphonovalerate STR11 EXAMPLE 4A Triethyl 2-Phosphonovalerate STR11 In analogy to the procedure given in Example 3: Ethyl 2-bromovalerate was treated with triethylphosphite to give triethyl 2-phosphonovalerate as a colorless clear liquid, b.p.=95°-110° C. (0.175 mm of Hg).
With triethyl phosphite 4.A Triethyl 2-Phosphonovalerate STR10 EXAMPLE 4A Triethyl 2-Phosphonovalerate STR10 In analogy to the procedure given in Example 3: Ethyl 2-bromovalerate was treated with triethylphosphite to give triethyl 2-phosphonovalerate as a colorless clear liquid, b.p.=95°-110° C. (0.175 mm of Hg).
  • 4
  • [ 35051-49-1 ]
  • [ 6959-48-4 ]
  • ethyl 2-(diethoxyphosphoryl)-2-(pyridin-3-ylmethyl)pentanoate [ No CAS ]
YieldReaction ConditionsOperation in experiment
40% Ethyl 2-(diethoxyphosphoryl)-2-(pyridin-3-ylmethyl)pentanoate (31e). Triethyl 2-phosphonoalkanoate 30e (0.8 g, 3 mmol) in 2 ml of THF was added dropwisely to a cooled suspension of sodium hydride (60% in oil, 0.2 g, 4.5 mmol) in THF (2 ml). It was stirred on ice bath for 15 min and then for 45 min at room temperature. In another flask was placed 3-picolyl chloride hydrochloride (0.5 g, 3 mmol) in DMF (4 ml) and was added sodium hydride (60% in oil, 0.18 g, 5.1 mmol). The mixture was stirred for 0.5 h at room temperature. Then 3-picolyl chloride in DMF was added via a Pasteur pipette (with cooling in ice bath) and reaction mixture was stirred at 50 C. After 3 h reaction was cooled down and quenched with saturated solution of NH4Cl (0.5 ml). Then THF was evaporated, residue was dissolved in water (pH 9, Na2CO3(aq)), and extracted with CH2Cl2 (4 x 15 ml). After drying over Na2SO4, the organic phase was evaporated and the residue subjected to column chromatography
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