Home Cart 0 Sign in  

[ CAS No. 5467-99-2 ]

{[proInfo.proName]} ,{[proInfo.pro_purity]}
Cat. No.: {[proInfo.prAm]}
Chemical Structure| 5467-99-2
Chemical Structure| 5467-99-2
Structure of 5467-99-2 * Storage: {[proInfo.prStorage]}

Quality Control of [ 5467-99-2 ]

Related Doc. of [ 5467-99-2 ]

SDS
Alternatived Products of [ 5467-99-2 ]
Alternatived Products of [ 5467-99-2 ]

Product Details of [ 5467-99-2 ]

CAS No. :5467-99-2 MDL No. :MFCD04347391
Formula : C15H14O2 Boiling Point : 344.2°C at 760 mmHg
Linear Structure Formula :- InChI Key :-
M.W :226.27 g/mol Pubchem ID :230518
Synonyms :

Safety of [ 5467-99-2 ]

Signal Word:Warning Class:N/A
Precautionary Statements:P261-P305+P351+P338 UN#:N/A
Hazard Statements:H302-H315-H319-H335 Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 5467-99-2 ]

  • Downstream synthetic route of [ 5467-99-2 ]

[ 5467-99-2 ] Synthesis Path-Downstream   1~16

  • 1
  • [ 103-83-3 ]
  • [ 99-75-2 ]
  • [ 5467-99-2 ]
YieldReaction ConditionsOperation in experiment
at 210℃;
  • 2
  • [ 5815-08-7 ]
  • [ 5467-99-2 ]
  • [ 20973-74-4 ]
YieldReaction ConditionsOperation in experiment
at 160℃;
  • 3
  • [ 60410-77-7 ]
  • [ 20194-18-7 ]
  • [ 5467-99-2 ]
  • [ 83078-39-1 ]
  • [ 53724-36-0 ]
YieldReaction ConditionsOperation in experiment
1: 70% 2: 90% 3: 1% In diethyl ether; ethanol at 0℃; for 3h;
  • 4
  • [ 5467-99-2 ]
  • [ 120-12-7 ]
  • [ 620-47-3 ]
  • [ 613-12-7 ]
YieldReaction ConditionsOperation in experiment
1: 20% 2: 13% 3: 30% at 400℃;
  • 5
  • [ 874-60-2 ]
  • [ 100-51-6 ]
  • [ 5467-99-2 ]
YieldReaction ConditionsOperation in experiment
89% With triethylamine In acetone at 20℃; Cooling with ice;
88% With triethylamine In diethyl ether for 5h; Heating;
  • 6
  • [ 81386-30-3 ]
  • [ 100-51-6 ]
  • [ 140-11-4 ]
  • [ 30377-13-0 ]
  • [ 5467-99-2 ]
  • [ 7753-06-2 ]
YieldReaction ConditionsOperation in experiment
at 200℃; for 3h; Further byproducts given;
YieldReaction ConditionsOperation in experiment
Verseifungsgeschwindigkeit in W.-Dioxan 2:3 (v:v) bei 35grad;
  • 9
  • [ 201230-82-2 ]
  • [ 624-31-7 ]
  • [ 100-51-6 ]
  • [ 5467-99-2 ]
YieldReaction ConditionsOperation in experiment
83% With 1,8-diazabicyclo[5.4.0]undec-7-ene In benzene at 120℃; for 3h;
78% With Cs2CO3 at 80℃; for 20h; Microwave irradiation; Sealed tube;
73% With triethylamine In benzene at 140℃; for 6h;
70% With bis(1,5-cyclooctadiene)nickel (0); 1,10-Phenanthroline; potassium carbonate In N,N-dimethyl-formamide at 130℃; for 36h; Glovebox;
39 %Spectr. With 1,4-diaza-bicyclo[2.2.2]octane; ammonium carbamate In toluene at 95℃; for 24h;

  • 10
  • [ 99-94-5 ]
  • [ 100-51-6 ]
  • [ 5467-99-2 ]
YieldReaction ConditionsOperation in experiment
90% With 1H-imidazole; iodine; chloro-diphenylphosphine In acetonitrile for 5h; Reflux;
90% Stage #1: p-Toluic acid With N-chlorobenzotriazole; triphenylphosphine In dichloromethane for 0.25h; Cooling; Stage #2: benzyl alcohol With triethylamine In dichloromethane at 20℃; for 0.916667h; Preparation of benzyl benzoate by using PPh3/NCBT General procedure: To a cold solution of PPh3 (0.327 g, 1.25 mmol) in CH2Cl2 (3 mL), freshly prepared NCBT (0.194 g,1.25 mmol) was added with continuous stirring. Benzoic acid (0.122 g, 1 mmol) was then added and stirring was continued for 15 min. Benzyl alcohol (0.270 g, 2.5 mmol) was added and the temperature was raised up to room temperature. The pale yellow solution was neutralized by triethylamine (0.175 mL). Stirring was continued for 40 min at room temperature. The progress of the reaction was followed by TLC. Upon completion of the reaction, the concentrated residue was passed through a short silica-gel column using n-hexane-ethyl acetate (8:1) as eluent. Benzyl benzoate was obtained with 95% yield after removing the solvent under reduced pressure.
89% With 2-butyl-1,3-diphenyl-1,3,2-diazaphospholidine; 1,1'-azodicarbonyl-dipiperidine In 1,2-dichloro-ethane at 40℃;
85% With dmap; triethylamine; trichlorophosphate In dichloromethane at 20℃; for 2h;
78% With silica gel; zinc trifluoromethanesulfonate for 0.05h; microwave irradiation;
69% With triphenylphosphine In acetonitrile for 6h; Heating;
26 % Chromat. With [Cl(C6F13C2H4)2SnOSn(C2H4C6F13)2Cl]2 In various solvent(s) at 150℃; for 16h;
With 5,5'-dimethyl-3,3′-azoisooxazole; triphenylphosphine In acetonitrile Reflux;
86 %Chromat. With tris(1-glycyl-3-methyl imidazolium chloride-iron(III)) In neat (no solvent) at 25℃; for 6.5h; Green chemistry;
With oxalyl dichloride; triethylamine; Triphenylphosphine oxide In acetonitrile at 20℃; for 2h; Inert atmosphere; 4 A 100 mL three-necked flask was charged with 2.80 g of triphenylphosphine oxide, evacuated to N2, 5 mL of acetonitrile was added,Under the magnetic stirring, 0.63 mL of oxalyl chloride was slowly added dropwise, and the reaction was violent and a large amount of gas was released for 10 minutes. Then 0.68 g of p-methylbenzoic acid, 0.67 mL of benzyl alcohol and a catalytic amount of triethylamine were added,The reaction was carried out at room temperature for 2 hours. The reaction was followed by TLC, quantified by column chromatography and qualitative by NMR.The ratio of developing agent (petroleum ether / ethyl acetate) was 4: 1,The yield of benzyl p-methylbenzoate obtained by column chromatography was 8.25%

  • 11
  • [ 53772-44-4 ]
  • [ 99-94-5 ]
  • [ 5467-99-2 ]
YieldReaction ConditionsOperation in experiment
98% With 2,6-dimethyl-1,4-benzoquinone In dichloromethane at 20℃; for 0.5h;
  • 12
  • [ 874-60-2 ]
  • [ 100-51-6 ]
  • [ 51490-06-3 ]
  • [ 5467-99-2 ]
YieldReaction ConditionsOperation in experiment
1: 86% 2: 6% With samarium In acetonitrile at 70℃; for 0.0333333h;
  • 13
  • [ 16518-25-5 ]
  • [ 100-44-7 ]
  • [ 5467-99-2 ]
YieldReaction ConditionsOperation in experiment
at 70℃;
  • 14
  • [ 99-75-2 ]
  • [ 5467-99-2 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: 98 percent / KSCOCH3; Triton X-405 / 150 °C 2: 70 °C
  • 15
  • [ 100-51-6 ]
  • [ 5467-99-2 ]
YieldReaction ConditionsOperation in experiment
Multi-step reaction with 2 steps 1: 55 percent / pyridine / diethyl ether / 1 h / 20 °C 2: 98 percent / 2,6-dimethyl-1,4-benzoquinone / CH2Cl2 / 0.5 h / 20 °C
Multi-step reaction with 2 steps 1: 55 percent / pyridine / diethyl ether / 20 °C 2: 98 percent / 2,6-dimethyl-1,4-benzoquinone / CH2Cl2 / 0.5 h / 20 °C
  • 16
  • [ 104-87-0 ]
  • [ 100-52-7 ]
  • [ 120-51-4 ]
  • [ 38418-10-9 ]
  • [ 5467-99-2 ]
  • [ 21086-87-3 ]
YieldReaction ConditionsOperation in experiment
1: 25 % Chromat. 2: 2 % Chromat. 3: 5 % Chromat. 4: 5 % Chromat. In benzene-d6 at 20℃;
1: 9 %Spectr. 2: 6 %Spectr. 3: 6 %Spectr. 4: 6 %Spectr. With dimethylbis(η5-pentamethylcyclopentadienyl)thorium In benzene-d6 at 25℃; for 24h;
Historical Records

Related Functional Groups of
[ 5467-99-2 ]

Aryls

Chemical Structure| 13222-85-0

[ 13222-85-0 ]

4-Methylbenzoic anhydride

Similarity: 0.98

Chemical Structure| 93-97-0

[ 93-97-0 ]

Benzoic anhydride

Similarity: 0.98

Chemical Structure| 18699-48-4

[ 18699-48-4 ]

Diisobutyl terephthalate

Similarity: 0.98

Chemical Structure| 94-50-8

[ 94-50-8 ]

Octyl Benzoate

Similarity: 0.95

Chemical Structure| 64904-47-8

[ 64904-47-8 ]

2-Oxoethyl benzoate

Similarity: 0.95

Esters

Chemical Structure| 72985-23-0

[ 72985-23-0 ]

6-Methylisobenzofuran-1(3H)-one

Similarity: 0.98

Chemical Structure| 13222-85-0

[ 13222-85-0 ]

4-Methylbenzoic anhydride

Similarity: 0.98

Chemical Structure| 23405-32-5

[ 23405-32-5 ]

Methyl 1-oxo-1,3-dihydroisobenzofuran-5-carboxylate

Similarity: 0.98

Chemical Structure| 93-97-0

[ 93-97-0 ]

Benzoic anhydride

Similarity: 0.98

Chemical Structure| 54120-64-8

[ 54120-64-8 ]

5-Methylisobenzofuran-1(3H)-one

Similarity: 0.98