Alternatived Products of [ 5650-10-2 ]
Product Details of [ 5650-10-2 ]
| CAS No. : | 5650-10-2 |
MDL No. : | MFCD20487183 |
| Formula : |
C15H17N
|
Boiling Point : |
- |
| Linear Structure Formula : | - |
InChI Key : | - |
| M.W : |
211.30
|
Pubchem ID : | - |
| Synonyms : |
|
Application In Synthesis of [ 5650-10-2 ]
* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.
- Upstream synthesis route of [ 5650-10-2 ]
- Downstream synthetic route of [ 5650-10-2 ]
- 1
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[ 142-04-1 ]
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[ 2479-47-2 ]
-
[ 62-53-3 ]
-
[ 1198-37-4 ]
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[ 5650-10-2 ]
-
[ 122-39-4 ]
- 2
-
[ 3225-26-1 ]
-
[ 5650-10-2 ]
-
[ 4972-13-8 ]
-
C15H16N
[ No CAS ]
Reference：
[1]Russian Journal of Physical Chemistry,1989,vol. 63,p. 1429 - 1432
Zhurnal Fizicheskoi Khimii,1989,vol. 63,p. 2601 - 2605
[2]Russian Journal of Physical Chemistry,1989,vol. 63,p. 1429 - 1432
Zhurnal Fizicheskoi Khimii,1989,vol. 63,p. 2601 - 2605
- 3
-
[ 2479-47-2 ]
-
[ 5650-10-2 ]
- 4
-
[ 5650-10-2 ]
-
[ 131222-99-6 ]
-
C48H42N2
[ No CAS ]
| Yield | Reaction Conditions | Operation in experiment |
| 98% |
With tri-tert-butyl phosphine; sodium t-butanolate;palladium diacetate; In toluene; at 100℃; |
Under argon flow, <strong>[131222-99-6]6,12-dibromochrysene</strong> (3.8 g, 10 mmol), 4-isopropyldiphenylamine (5.2 g, 25 mmol), palladium acetate (0.03 g, 1.5 mol %), tri-t-butylphosphine (0.06 g, 3 mol %), t-butoxysodium (2.4 g, 25 mmol), and anhydrous toluene (100 mL) were added to a 300-mL three-neck flask equipped with a condenser, and the mixture was heated overnight at 100 C. with stirring. After completion of reaction, precipitated crystals were collected through filtration, followed by washing with toluene (50 mL) and methanol (100 mL), to thereby yield 6.3 g of a pale yellow powder. The powder was identified as compound (9) through an NMR spectrum (see FIG. 6) and an FD-MS (yield: 98%). The NMR spectrum was obtained under the same conditions as employed in Synthesis Example 1. |
- 5
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[ 27973-29-1 ]
-
[ 5650-10-2 ]
-
N,N'-diphenyl-N,N'-bis(4-isopropylphenyl)pyrene-1,6-diamine
[ No CAS ]
| Yield | Reaction Conditions | Operation in experiment |
| 89% |
With tri-tert-butyl phosphine; sodium t-butanolate In toluene at 100℃; |
1
Under an argon gas flow, 3.6 g (10 mmol) of 1,6-dibromopyrene, 5.2 g (25 mmol) of 4-isopropyl diphenyl amine, 0.03 g (1.5 mol%) of palladium acetate, 0.06 g (3 mol%) of tri-t-butyl phosphine, 2.4 g (25 mmol) of t-butoxy sodium and 100 milliliter of dried toluene were charged into a three-necked flask having a capacity of 300 milliliter and equipped with a condenser, and then stirred under heating at a temperature of 100°C over night. After completion of the reaction, the precipitated crystals were separated from the reaction solution by filtration, and then washed with 50 milliliter of toluene and 100 milliliter of methanol, thereby obtaining 5.5 g of a light-yellow powder. The thus obtained powder was subjected to NMR spectrum analysis (Fig. 1) and FD-MS (field-desorption mass spectrum analysis). As a result, the reaction product was identified as Compound (8) (yield: 89%). Meanwhile, the NMR spectrum was measured by Fourier-transform Nuclear Magnetic Resonance analyzer "R-1900" (90 MHz) produced by Hitachi, Ltd., using CDCl3 as a solvent. |
- 6
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[ 27973-29-1 ]
-
[ 5650-10-2 ]
-
C46H40N2
[ No CAS ]
| Yield | Reaction Conditions | Operation in experiment |
| 89% |
With tri-tert-butyl phosphine; sodium t-butanolate In toluene at 100℃; |
1
Synthesis Example 1 Synthesis of Compound (1) Under the stream of argon, 3.6 g (10 mmole) of 1,6-dibromopyrene, 5.2 g (25 mmole) of 4-isopropyldiphenylamine, 0.03 g (1.5% by mole) of palladium acetate, 0.06 g (3% by mole) of tri-t-butylphosphine, 2.4 g (25 mmole) of t-butoxysodium and 100 ml of dry toluene were placed into a 300 ml three-necked flask equipped with a condenser, and the resultant mixture was heated at 100 C under stirring for one night. After the reaction was completed, the formed crystals were separated by filtration and washed with 50 ml of toluene and 100 ml of methanol, and 5.5 g of a light yellow powder substance was obtained. The obtained product was identified to be Compound (1) from the 1H-NMR spectrum (Figure 1) and by the measurement in accordance with the field desorption mass spectroscopy (FD-MS) (the yield: 89%). In the 1H-NMR spectroscopy, the measurement was conducted using CDCl3 as the solvent and a Fourier transform nuclear magnetic resonance apparatus R-1900 (90 MHz) manufactured by HITACHI SEISAKUSHO Co., Ltd. or DRX-500 (500 MHz) manufactured by BRUCKER Company. |
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