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[ CAS No. 64479-78-3 ] {[proInfo.proName]}

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Product Details of [ 64479-78-3 ]

CAS No. :64479-78-3 MDL No. :MFCD00454168
Formula : C11H9N3O Boiling Point : -
Linear Structure Formula :- InChI Key :VEZNVMFOOMYSBF-UHFFFAOYSA-N
M.W : 199.21 Pubchem ID :3758644
Synonyms :

Safety of [ 64479-78-3 ]

Signal Word:Warning Class:
Precautionary Statements:P261-P264-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P313-P337+P313-P362-P403+P233-P405-P501 UN#:
Hazard Statements:H315-H319-H335 Packing Group:
GHS Pictogram:

Application In Synthesis of [ 64479-78-3 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

  • Downstream synthetic route of [ 64479-78-3 ]

[ 64479-78-3 ] Synthesis Path-Downstream   1~50

  • 1
  • [ 504-24-5 ]
  • [ 39178-35-3 ]
  • [ 64479-78-3 ]
YieldReaction ConditionsOperation in experiment
With pyridine
  • 2
  • [ 64479-78-3 ]
  • [ 138736-35-3 ]
  • [ 7732-18-5 ]
  • [ 2923-28-6 ]
  • [(4,4'-di-tert-butyl-2,2'-bipyridine)Pt(μ-N-(pyridin-4-yl)isonicotinamide))3](CF3SO3)6*3H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
68% In tetrahydrofuran; dichloromethane (t-Bu2bipy)Pt(O3SCF3)2 generated in situ from (t-Bu2bipy)PtCl2 and AgO3SCF3 in CH2Cl2-THF; filtered; added to N-(2-pyridin-4-yl)isonicotinamide in THF; filtered; washed (Et2O); dried (vac.); elem. anal.;
68% In tetrahydrofuran to soln. of Pd complex in CH2Cl2/THF (10:10, v/v) added Ag salt, filtered, added to soln. of ligand in THF; filtered, washed (ether), dried in vac.; elem. anal.;
  • 3
  • [ 64479-78-3 ]
  • [(4,4'-di-tert-butyl-2,2'-bipyridine)Pd(tetrahydrofuran)2](BF4)2 [ No CAS ]
  • [(4,4'-di-tert-butyl-2,2'-bipyridine)Pd(μ-N-(pyridin-4-yl)isonicotinamide)]3(BF4)6 [ No CAS ]
  • 4
  • copper(II) perchlorate hexahydrate [ No CAS ]
  • [ 64479-78-3 ]
  • disodium pyrazine 2,3-dicarboxylate [ No CAS ]
  • [Cu2(pyrazine-2,3-dicarboxylate)2(N-(4-pyridyl)isonicotinamide)*5water]n [ No CAS ]
YieldReaction ConditionsOperation in experiment
In ethanol; water addn. of soln. of sodium salt to soln. of Cu salt and bipyridine; filtration, drying (reduced pressure); elem. anal.;
  • 5
  • [ 14104-20-2 ]
  • [ 64479-78-3 ]
  • [ 162379-72-8 ]
  • [ 7732-18-5 ]
  • [(4,4'-di-tert-butyl-2,2'-bipyridine)Pd(μ-N-(pyridin-4-yl)isonicotinamide))3](BF4)6*H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
82% In tetrahydrofuran to soln. of Pd complex in THF/CH2Cl2 (10:10, v/v) added AgBF4, filtered,added to soln. of ligand in THF; filtered, washed (ether), dried in vac.; elem. anal.;
  • 6
  • [ 64479-78-3 ]
  • [ 137846-38-9 ]
  • [ 7732-18-5 ]
  • [(dppp)Pt(μ-N-(pyridin-4-yl)isonicotinamide)]x(CF3SO3)2x*xH2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
98% In tetrahydrofuran to mixt. of Pd complex and ligand added THF; filtered, washed (ether), dried in vac.; elem. anal.;
  • 7
  • cobalt(II) nitrate hexahydrate [ No CAS ]
  • [ 64479-78-3 ]
  • sodium 1,2-benzenedicarboxylate [ No CAS ]
  • [[Co(H2O)2(phthalate)(μ-N-(4-pyridyl)isonicotinamide)]*2.36H2O]n [ No CAS ]
YieldReaction ConditionsOperation in experiment
60% In ethanol; water EtOH soln. of ligand added to aq. soln. of Co(NO3)2*6H2O, stirred at 60°C for 30 min, soln. of disodium phthalate in H2O/EtOH added, stirred at 70°C for 4 h, cooled to room temp.; filtered, filtrate evapd., soln. slow evapd. at room temp.; elem. anal.;
  • 8
  • [ 64479-78-3 ]
  • [ 313674-46-3 ]
  • [[1,8-bis[trans-Pt(PEt3)2)]anthracene]2(C5H4NCONHC5H4N)2](NO3)4 [ No CAS ]
YieldReaction ConditionsOperation in experiment
82.7% In methanol; acetone to acetone soln. of Pt complex was added methanol soln. of ligand dropwise with continuous stirring, soln. was stirred for another 30 min; elem. anal.;
  • 9
  • [ 14074-80-7 ]
  • [ 64479-78-3 ]
  • [ 108-88-3 ]
  • (Zn(tetraphenylporphyrinato))2(N-(4-pyridyl)isonicotinamide)*2(toluene) [ No CAS ]
YieldReaction ConditionsOperation in experiment
In methanol; chloroform; toluene Zn complex reacted with ligand in CHCl3/toluene/MeOH; slow evapn.;
  • 10
  • [ 14074-80-7 ]
  • [ 64479-78-3 ]
  • [ 106-42-3 ]
  • [ 951224-76-3 ]
YieldReaction ConditionsOperation in experiment
In methanol; chloroform Zn complex reacted with ligand in CHCl3/p-xylene/MeOH; slow evapn.;
  • 11
  • [ 64479-78-3 ]
  • [ 1097005-15-6 ]
  • [((C14H8(CC)2)(Pt(PEt3)2)2)2(μ-N-(4-pyridyl)isonicotinamide)2](NO3)4 [ No CAS ]
YieldReaction ConditionsOperation in experiment
95% In acetone soln. of ligand (1 equiv.) in acetone was added to stirred suspn. of Pt complex in acetone at 60°C; stirred overnight; filtered; washed (Et2O); dried (vac.); elem. anal.;
  • 12
  • [ 64479-78-3 ]
  • [ 1097005-15-6 ]
  • (C14H8C4)2(Pt(P(C2H5)3)2)4(C5H4NCONHC5H4N)2 [ No CAS ]
  • (C14H8C4)2(Pt(P(C2H5)3)2)4(C5H4NCONHC5H4N)2 [ No CAS ]
YieldReaction ConditionsOperation in experiment
0% In not given
  • 13
  • [ 67-56-1 ]
  • [ 64479-78-3 ]
  • dichlorobis(N,N'-ethylenebis(acetylacetone)-2,2'-imine(-2H))diiron(III) [ No CAS ]
  • [ 143-66-8 ]
  • (N,N'-ethylenebis(acetylacetone)-2,2'-imine(-2H))(N-(4-pyridyl)-isonicotinamide)iron(III) tetraphenylborate*3(methanol) [ No CAS ]
YieldReaction ConditionsOperation in experiment
65% In methanol ligand added to soln. of Fe complex in MeOH; heated; filtered into freshly prepared soln. of NaBPh4 in MeOH; stirred overnight; filtered; elem. anal.;
  • 14
  • [ 67-56-1 ]
  • [ 64479-78-3 ]
  • dichlorobis(N,N'-ethylenebis(salicylaldimine)(-2H))diiron(III) [ No CAS ]
  • [ 143-66-8 ]
  • (N,N'-ethylenebis(salicylaldimine)(-2H))(N-(4-pyridyl)-isonicotinamide)iron(III) tetraphenylborate bis(methanol) [ No CAS ]
YieldReaction ConditionsOperation in experiment
43% In methanol ligand added to soln. of Fe complex in MeOH; heated and stirred for 10 min; filtered into freshly prepared soln. of NaBPh4 in MeOH; crystd. within hours; elem. anal.;
  • 15
  • [ 64479-78-3 ]
  • [Ru2(μ-η4-C2O4)(MeOH)26-p-iPrC6H4Me)2][O3SCF3]2 [ No CAS ]
  • [Ru4(μ-η4-C2O4)2(N-(4-pyridyl)isonicotinamide)(η6-p-cymene)4](O3SCF3)4 [ No CAS ]
YieldReaction ConditionsOperation in experiment
92% In methanol soln. of Ru complex (1 equiv.) in MeOH was added to ligand (1 equiv.); stirred at room temp. for 24 h; evapd. (vac.); dissolved in CH2Cl2; concd.; Et2O added; elem. anal.;
  • 16
  • [ 64479-78-3 ]
  • [Ru2(μ-η4-C6H2O4)(CH3OH)26-p-cymene)2](CF3SO3)2 [ No CAS ]
  • [Ru4(μ-η4-C6H2O4)2(N-(4-pyridyl)isonicotinamide)(η6-p-cymene)4](O3SCF3)4 [ No CAS ]
YieldReaction ConditionsOperation in experiment
98% In methanol soln. of Ru complex (1 equiv.) in MeOH was added to ligand (1 equiv.); stirred at room temp. for 24 h; evapd. (vac.); dissolved in CH2Cl2; concd.; Et2O added; elem. anal.;
  • 17
  • [ 64479-78-3 ]
  • [ 1233502-93-6 ]
  • (C12H7N(CCPt(P(CH2CH3)3)2)2(C5H4NNHCOC5H4N))2(4+)*4NO3(1-)=Pt4C102H152N8O2P8(NO3)4 [ No CAS ]
YieldReaction ConditionsOperation in experiment
80% In acetone addn. of a soln. of Pt complex in acetone to a soln. of ligand in acetone, stirring at 50°C for 5 h; washing ppt. with acetone and Et2O; elem. anal.;
  • 18
  • [ 504-24-5 ]
  • [ 55-22-1 ]
  • [ 64479-78-3 ]
YieldReaction ConditionsOperation in experiment
75% Stage #1: pyridine-4-carboxylic acid With triethylamine In tetrahydrofuran for 0.166667h; Stage #2: With chloroformic acid ethyl ester In tetrahydrofuran at 0℃; for 0.5h; Stage #3: 4-aminopyridine In tetrahydrofuran at 0℃; for 1h;
73% Stage #1: pyridine-4-carboxylic acid With chloroformic acid ethyl ester; triethylamine In tetrahydrofuran at 5 - 10℃; for 0.5h; Stage #2: 4-aminopyridine In tetrahydrofuran at 0 - 20℃;
23.3% With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride In dichloromethane at 20℃; for 12h;
Stage #1: pyridine-4-carboxylic acid With thionyl chloride; triethylamine Stage #2: 4-aminopyridine With triethylamine

  • 19
  • [ 64479-78-3 ]
  • cadmium(II) nitrate tetrhydrate [ No CAS ]
  • [ 7325-46-4 ]
  • [ 7732-18-5 ]
  • [Cd3(1,4-phenylenediacetate)2(isonicotinate)2(H2O)2] [ No CAS ]
YieldReaction ConditionsOperation in experiment
22% In water High Pressure; Cd compd., 4-pina, and 1,4-phdaH2 (2.7:2.9:4.5 molar ratio) in H2O, sealed, heated at 120°C for 48 h; cooled to room temp., septd., washed (H2O, acetone), dried in air, elem.anal.;
  • 20
  • copper(II) perchlorate hexahydrate [ No CAS ]
  • [ 89-01-0 ]
  • [ 64479-78-3 ]
  • Cu2(pyrazine-2,3-dicarboxylate)2(N-(4-pyridyl)isonicotinamide) [ No CAS ]
YieldReaction ConditionsOperation in experiment
With NaOH In ethanol 2,3-pyrazinedicarboxylic acid, ligand dissolved in NaOH, EtOH, slowly added to Cu(ClO4)2*6H2O, stirred for 24 h at room temp.; filtered, washed with H2O, MeOH, dried at 363 K overnight; monitored by XRD;
  • 21
  • [ 64479-78-3 ]
  • Ni[Ni(CN)4] [ No CAS ]
  • Ni(N-(4-pyridyl)isonicotinamide)[Ni(CN)4] [ No CAS ]
YieldReaction ConditionsOperation in experiment
In toluene Inert atmosphere; Schlenk technique; Reflux;
YieldReaction ConditionsOperation in experiment
99% With N-(3-dimethylaminopropyl)-N-ethylcarbodiimide In N,N-dimethyl-formamide at 20℃; General procedure: A mixture of 4-aminopyridine (47 mg, 0.5 mmol), picolinic acid (62 mg, 0.5 mmol) and N-ethyl-N'-(3-dimethylaminopropyl)carbodiimide (192 mg, 1 mmol) in DMF (2 mL) was stirred at room temperature overnight. After solvent was removed under reduced pressure, the residue was purified by flash column chromatography (hexane: ethyl acetate, 1 : 1). The product 1 (74 mg) was obtained in 74% yield. The same procedure was used to synthesize 2 (99 mg, 99%), 3 (95 mg, 95%), 4 (reaction on 1.0 mmol scale, 136 mg, 58%) and 5 (reaction on 2.0 mmol scale, 514 mg, 92%). N-(pyridin-4-yl)isonicotinamide (2). 1H NMR (400 MHz, d6-DMSO) δ 10.85 (s, 1H), 8.82 (dd, J= 4.4, 1.6 Hz, 2H), 8.52 (d, J= 6.3 Hz, 2H), 7.87 (dd, J= 4.4, 1.7 Hz, 2H), 7.78 (dd, J= 4.8, 1.6 Hz, 2H); MS (ESI) m/z = 200 [M+H]+; HPLC purity, 99.4%.
  • 23
  • [ 64479-78-3 ]
  • [ 142-71-2 ]
  • [Cu(OAc)2(4-pyridylisonicotinamide)]·0.5H2O}n [ No CAS ]
YieldReaction ConditionsOperation in experiment
50% In ethanol; water at 20℃; for 504h;
  • 24
  • [ 64479-78-3 ]
  • [ 761442-02-8 ]
  • [ 1220714-37-3 ]
  • [ 7732-18-5 ]
  • 6Pd(2+)*6C6H16N2*2C18H14N8*12NO3(1-)*30H2O*2C11H9N3O [ No CAS ]
YieldReaction ConditionsOperation in experiment
95% at 20℃; for 24h;
  • 25
  • zinc(II) nitrate hexahydrate [ No CAS ]
  • [ 64479-78-3 ]
  • [ 4371-27-1 ]
  • [ 7732-18-5 ]
  • [ 33513-42-7 ]
  • [Zn4(bpta)2(N-(4-pyridyl)isonicotinamide)2(H2O)2]·4DMF·3H2O}n [ No CAS ]
YieldReaction ConditionsOperation in experiment
60% In ethanol at 85℃; for 24h; Sealed tube; Sonication;
  • 26
  • [ 67-56-1 ]
  • [ 64479-78-3 ]
  • [[3,3']-[1,2-phenylenebis(iminomethylidyne)]bis(2,4-pentane-dionato)(2-)-N,N',O(2),O(2')]dimethanoliron(II) [ No CAS ]
  • [ 7732-18-5 ]
  • [FeL1(N-(pyrid-4-yl)isonicotinamide)]*xMeOH/H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
for 336h; Inert atmosphere; Schlenk technique;
  • 27
  • [ 67-56-1 ]
  • [ 64479-78-3 ]
  • [[3,3']-[1,2-phenylenebis(iminomethylidyne)]bis(2,4-pentane-dionato)(2-)-N,N',O(2),O(2')]dimethanoliron(II) [ No CAS ]
  • [ 7732-18-5 ]
  • [FeL1(N-(pyrid-4-yl)isonicotinamide)]*0.5H2O*0.5MeOH [ No CAS ]
YieldReaction ConditionsOperation in experiment
95% at 20℃; for 2h; Inert atmosphere; Schlenk technique;
  • 28
  • [ 67-56-1 ]
  • [ 64479-78-3 ]
  • [[3,3']-[1,2-phenylenebis(iminomethylidyne)]bis(2,4-pentane-dionato)(2-)-N,N',O(2),O(2')]dimethanoliron(II) [ No CAS ]
  • [FeL1(N-(pyrid-4-yl)isonicotinamide)]*2MeOH [ No CAS ]
YieldReaction ConditionsOperation in experiment
for 168h; Inert atmosphere; Schlenk technique;
  • 29
  • [ 67-56-1 ]
  • [ 64479-78-3 ]
  • [[3,3']-[1,2-phenylenebis(iminomethylidyne)]bis(2,4-pentane-dionato)(2-)-N,N',O(2),O(2')]dimethanoliron(II) [ No CAS ]
  • [FeL1(N-(pyrid-4-yl)isonicotinamide)]*0.5MeOH [ No CAS ]
YieldReaction ConditionsOperation in experiment
74% for 1h; Inert atmosphere; Schlenk technique; Reflux;
  • 30
  • [ 64479-78-3 ]
  • [[3,3']-[1,2-phenylenebis(iminomethylidyne)]bis(2,4-pentane-dionato)(2-)-N,N',O(2),O(2')]dimethanoliron(II) [ No CAS ]
  • [ 33513-42-7 ]
  • [FeL1(N-(pyrid-4-yl)isonicotinamide)]*DMF [ No CAS ]
YieldReaction ConditionsOperation in experiment
52% at 20℃; Inert atmosphere; Schlenk technique; Reflux;
  • 31
  • [ 64479-78-3 ]
  • [[3,3']-[1,2-phenylenebis(iminomethylidyne)]bis(2,4-pentane-dionato)(2-)-N,N',O(2),O(2')]dimethanoliron(II) [ No CAS ]
  • [ 7732-18-5 ]
  • [FeL1(N-(pyrid-4-yl)isonicotinamide)]*2H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
100% In tetrahydrofuran at 20℃; Inert atmosphere; Schlenk technique;
  • 32
  • [ 64479-78-3 ]
  • [ 64-17-5 ]
  • [[3,3']-[1,2-phenylenebis(iminomethylidyne)]bis(2,4-pentane-dionato)(2-)-N,N',O(2),O(2')]dimethanoliron(II) [ No CAS ]
  • [FeL1(N-(pyrid-4-yl)isonicotinamide)]*0.5EtOH [ No CAS ]
YieldReaction ConditionsOperation in experiment
87% for 1h; Inert atmosphere; Schlenk technique; Reflux;
  • 33
  • zinc(II) nitrate hexahydrate [ No CAS ]
  • [ 64479-78-3 ]
  • [ 787-70-2 ]
  • 2Zn(2+)*2C14H8O4(2-)*C11H9N3O [ No CAS ]
YieldReaction ConditionsOperation in experiment
In N,N-dimethyl-formamide Heating;
  • 34
  • [ 64479-78-3 ]
  • 3Zn(2+)*C12H10N2*2C39H24NO6(3-)*19C3H7NO*6H2O [ No CAS ]
  • [ 33513-42-7 ]
  • 3Zn(2+)*2C39H24NO6(3-)*13C3H7NO*4H2O*C11H9N3O [ No CAS ]
YieldReaction ConditionsOperation in experiment
at 20℃;
  • 35
  • [ 64479-78-3 ]
  • 3Zn(2+)*2C39H24NO6(3-)*11C3H7NO*5H2O*C10H8N2 [ No CAS ]
  • [ 33513-42-7 ]
  • 3Zn(2+)*2C39H24NO6(3-)*13C3H7NO*4H2O*C11H9N3O [ No CAS ]
YieldReaction ConditionsOperation in experiment
at 20℃;
  • 36
  • [ 64479-78-3 ]
  • 3Zn(2+)*C10H8N4*2C39H24NO6(3-)*6H2O*13C3H7NO [ No CAS ]
  • [ 33513-42-7 ]
  • 3Zn(2+)*2C39H24NO6(3-)*13C3H7NO*4H2O*C11H9N3O [ No CAS ]
YieldReaction ConditionsOperation in experiment
at 20℃;
  • 37
  • [ 64479-78-3 ]
  • [ 7732-18-5 ]
  • [ 149996-75-8 ]
  • [Cu2(dimethylmalonate+H)2(dimethylmalonate)(4-pyridylisonicotinamide)2]*0.5H2O}n [ No CAS ]
YieldReaction ConditionsOperation in experiment
29% In ethanol at 25℃; for 336h; Preparation of [Cu2(Hdmmal)2(dmmal)(4-pina)2]·0.5H2O}n (5) The synthesis of 5 proceeded similarly to that of 3, with the use 4-pina (18 mg, 0.095 mmol) as the dipyridylamide component. Blue blocks of 5 (12 mg, 29% yield based on Cu) were isolated after washing with distilled water and acetone and drying in air. Anal. Calc. for C37H39Cu2N6O14.5 5: C, 47.53; H, 4.21; N, 8.99. Found: C, 47.55; H, 4.16; N, 9.14%. IR (cm-1): 3547 (w), 2963 (w), 1684 (m), 1550 (s), 1519 (s), 1445 (m), 1427 (m), 1385 (m), 1335 (m), 1306 (m), 1289 (s), 1213 (m), 1124 (m), 1069 (m), 1031 (m), 989 (w), 906 (w), 845 (s), 815 (s), 758 (s), 707 (m), 691 (m).
  • 38
  • [ 64479-78-3 ]
  • [ 54010-75-2 ]
  • [ 33513-42-7 ]
  • [Zn(N-(4-pyridyl)isonicotinamide)(DMF)4](OTf)2}n [ No CAS ]
YieldReaction ConditionsOperation in experiment
for 2h; 2.3.4 [Zn(4-pina)(DMF)4](OTf)2}n (4) A solution of Zn(OTf )2 (0.090 g, 0.25 mmol) in 1 mL of DMF was added to a stirred solution of 4-pina (0.050 g, 0.25 mmol) in 1 mL of DMF. The colorless solution was stirred for 2.0 h and 20 mL of Et2O was added to the mixture. The resulting white oil-like solid was washed with Et2O (5 mL × 3). Dissolving the white powder in DMF and vapor diffusion of Et2O into the colorless solution at room temperature led to colorless needles suitable for X-ray crystallographic characterization (0.128 g, 59.9% yield). Anal. Calcd for C25H37N7O11F6S2Zn: C, 35.12; H, 4.36; N, 11.47. Found: C, 35.38; H, 4.19; N, 11.09. FT-IR (cm -1): 1695, 1643, 1593, 1504, 1419, 1378, 1333, 1245, 1222, 1157, 1113, 1066, 1027, 850, 760, 677, 635, 594, 572, 551, 516, 435.
  • 39
  • [ 64479-78-3 ]
  • [ 197524-22-4 ]
  • [ 33513-42-7 ]
  • [Fe(N-(4-pyridyl)isonicotinamide)(DMF)4](OTf)2}n [ No CAS ]
YieldReaction ConditionsOperation in experiment
71.9% for 1h; 2.3.5 [Fe(4-pina)(DMF)4](OTf)2}n (5) A solution of [Fe(NCCH3)2(OTf )2] (0.109 g, 0.25 mmol) in 1 mL of DMF was added to a stirred solution of 4-pina (0.050 g, 0.25 mmol) in 1 mL of DMF. The orange solution was stirred for 1.0 h and 20 mL of Et2O was added to the mixture. The resulting yellow powder was washed with Et2O (5 mL × 3). Dissolving the product in DMF and vapor diffusion of Et2O into the orange solution at room temperature led to deep yellow crystals suitable for X-ray crystallographic characterization (0.152 g, 71.9% yield). Anal. Calcd for C25H37N7O11F6S2Fe: C, 35.51; H, 4.41; N, 11.60. Found: C, 35.84; H, 4.61; N, 11.43. FT-IR (cm-1): 1642, 1591, 1558, 1501, 1437, 1416, 1377, 1331, 1245, 1221, 1151, 1111, 1027, 842, 760, 678, 634, 589, 549, 572, 549, 516.
  • 40
  • zinc(II) nitrate hexahydrate [ No CAS ]
  • [ 64479-78-3 ]
  • [ 1141-38-4 ]
  • C12H6O4(2-)*Zn(2+)*C11H9N3O [ No CAS ]
YieldReaction ConditionsOperation in experiment
85% In N,N-dimethyl-formamide at 119.84℃; for 24h; Inert atmosphere; 1 Under nitrogen atmosphere, 2.19 g (7.4 mmol) of zinc nitrate hexahydrate, 1.59 g (7.4 mmol) of 2,6-naphthalenedicarboxylic acid, and 0.732 g (3.7 mmol) of N-(4-pyridyl)isonicotinamide was dissolved in 300 mL of N,N-dimethylformamide, and the mixture was stirred at 393 K for 24 hours. As a result of the single crystal X-ray structure analysis of the precipitated metal complex, the resulting metal complex was a three-dimensional structure in which the juncture and the skeleton were mutually penetrated. The precipitated metal complex was recovered by suction filtration, washed three times with methanol, and dried at 373 K and 50 Pa for 8 hours to obtain 2.37 g (yield: 85%) of the objective metal complex.
  • 41
  • zinc(II) nitrate hexahydrate [ No CAS ]
  • [ 64479-78-3 ]
  • [ 610-29-7 ]
  • C8H3NO6(2-)*Zn(2+)*C11H9N3O [ No CAS ]
YieldReaction ConditionsOperation in experiment
72% In N,N-dimethyl-formamide; at 119.84℃; for 24h;Inert atmosphere; Under nitrogen atmosphere, 4.40 g (15 mmol) of zinc nitrate hexahydrate, (15 mmol) of <strong>[610-29-7]2-nitroterephthalic acid</strong>, and (7.4 mmol) of N-(4-pyridyl) isonicotinamide were dissolved in 600 mL of N, N-dimethylformamide, and the mixture was stirred at 393 K for 24 hours. As a result of the single crystal X-ray structure analysis, the precipitated metal complex has three- dimensional structure in which the juncture and the skeleton were mutually penetrated. The precipitated metal complex was recovered by suction filtration, and washed three times with methanol. Subsequently, it was dried at 373 K and 50 Pa for 8 hours, to obtain 4.00 g (yield: 72%) of the objective metal complex.
  • 42
  • [ 64479-78-3 ]
  • [ 610-29-7 ]
  • [ 5893-61-8 ]
  • C8H3NO6(2-)*C11H9N3O*Cu(2+) [ No CAS ]
YieldReaction ConditionsOperation in experiment
98% Under nitrogen atmosphere, 1.13 g (5.0 mmol) of copper formate tetrahydrate and 1.06 g (5.0 mmol) of <strong>[610-29-7]2-nitroterephthalic acid</strong> were dissolved in 800 mL of methanol, and the mixture was stirred at 313 K for 24 hours. Thereafter, a solution obtained by dissolving 0.500 g (2.5 mmol) of N-(4-pyridyl)isonicotinamide in 40 mL of methanol was added, and further stirred at 313 K for 24 hours. As a result of the single crystal X-ray structure analysis of the precipitated metal complex, the resulting metal complex was a three-dimensional structure in which the juncture and the skeleton were mutually penetrated. The precipitated metal complex was recovered by suction filtration, and washed three times with methanol. Subsequently, it was dried at 373 K and 50 Pa for 8 hours and 1.83 g (yield 98%) of the objective metal complex was obtained.
  • 43
  • [ 64479-78-3 ]
  • iron(II) perchlorate monohydrate [ No CAS ]
  • [ 1147550-11-5 ]
  • [ 75-05-8 ]
  • [Fe(NCS)2(n-(4-pyridyl)-isonicotinamide)2]*2(CH3CN) [ No CAS ]
YieldReaction ConditionsOperation in experiment
75% for 336h; Synthesis of [Fe(NCS)2(pin)2]*2(CH3CN) (pin-S) A 2-mL solution of pin (34.0 mg, 0.157 mmol) in acetonitrile was placed at the base of one arm of an H-shaped tube. A 2-mL solution of Fe(ClO4)2*H2O (20 mg, 0.078 mmol) and NH4NCS (11.9 mg, 0.156 mmol) in acetonitrile was placed in the other arm of the H-shaped tube. Acetonitrile solvent was carefully layered to fill the rest of the tube, which was then stoppered. After 2 weeks, red plate-shaped crystals formed. Yield 75 %.
  • 44
  • [ 64479-78-3 ]
  • [ 137436-76-1 ]
  • [ 75-05-8 ]
  • [Cu(N-(4-pyridyl)isonicotinamide)(CH3CN)2]SbF6}n [ No CAS ]
YieldReaction ConditionsOperation in experiment
82.4% for 2h; [Cu(4-pina)(CH3CN)2]SbF6}n (3) A solution of [Cu(NCCH3)4]SbF6 (0.116 g, 0.25 mmol) in 1 mL CH3CN was added to a solutionof 4-pina (0.025 g, 0.25 mmol) in 1 mL CH3CN. The yellow solutionwas stirred for 2 h and 20 mL of Et2O was added to the mixture.The resulting yellow powder was washed with Et2O (5mL 3).The raw product was dissolved in CH3CN and the resulting solutionwas filtered through a celite plug. Vapor diffusion of Et2O into the clear yellow filtrate at room temperature led to the formation ofyellow crystals suitable for X-ray crystallographic characterization(0.128 g, 82.4% yield). Anal. Calc. for C15H15CuF6N5OSb: C, 31.03; H,2.60; N, 12.06. Found: C, 30.85; H, 2.50; N, 12.33. FT-IR (cm1):1701, 1618, 1593, 1553, 1514, 1434, 1340, 1296, 1271, 1216,1123, 1066, 904, 837, 761, 715, 662, 635, 537.
  • 45
  • [ 64479-78-3 ]
  • [ 137436-76-1 ]
  • [ 7732-18-5 ]
  • [Cu2(N-(4-pyridyl)isonicotinamide)4](SbF6)2(H2O)}n [ No CAS ]
YieldReaction ConditionsOperation in experiment
64.8% In N,N-dimethyl-formamide for 4h; [Cu(3-pna)2]SbF6}n (1) General procedure: A solution of [Cu(NCCH3)4] SbF6 (0.116g, 0.25 mmol) in 1 mL DMF was added to a solution of 3-pna(0.050 g, 0.50 mmol) in 1 mL DMF. The yellow solution was stirredfor 4.0 h and 20 mL of Et2O was added to the mixture. The resultingyellow powder was washed with Et2O (5mL 3). The product wasdissolved in DMF and the solution was filtered through a celiteplug. Vapor diffusion of Et2O into the clear yellow filtrate at roomtemperature led to the formation of yellow crystals suitable for Xraycrystallographic characterization (0.106 g, 60.8% yield).
  • 46
  • [ 67-56-1 ]
  • [ 64479-78-3 ]
  • potassium dicyanoargentate(I) [ No CAS ]
  • iron(II) tetrafluoroborate hexahydrate [ No CAS ]
  • {FeII(N-(pyridin-4-yl)-isonicotinamide)-[AgI(CN)2]2}*xMeOH [ No CAS ]
YieldReaction ConditionsOperation in experiment
for 336h;
  • 47
  • [ 67-56-1 ]
  • [ 64479-78-3 ]
  • iron(II) tetrafluoroborate hexahydrate [ No CAS ]
  • potassium dicyanoaurate [ No CAS ]
  • {FeII(N-(pyridin-4-yl)-isonicotinamide)-[AuI(CN)2]2}*xMeOH [ No CAS ]
YieldReaction ConditionsOperation in experiment
for 336h;
  • 48
  • [ 64479-78-3 ]
  • 4-((1-oxidopyridin-4-yl)carbamoyl)pyridine-1-oxide [ No CAS ]
YieldReaction ConditionsOperation in experiment
56% With 3-chloro-benzenecarboperoxoic acid In methanol at 70℃; 4-((1-oxidopyridin-4-yl)carbamoyl)pyridine-1-oxide (diNO) To a solution of N-(4-pyridyl)isonicotinamide(1.35 g, 6.8 mmol) in MeOH (25 mL), m-chloroperoxybenzoic acid (3.80 g, 17.0 mmol) was addedin portions for 15 min. The reaction mixture was refluxed overnight at 70.0 C and cooled to roomtemperature. The solid was collected by filtration, washed with hot methanol, and then dried.Yield 0.88 g, 56.0%. 1H NMR (400 MHz, DMSO-d6) : 10.81 (1H, s), 8.39 (2H d, J = 7.2), 8.18 (2H d,J = 7.2), 7.95 (2H d, J = 7.2), 7.79 (2H d, J = 7.2). MS (ESI) m/z for C11H9N3O3Na+: expected 254.05,found 254.05.
  • 49
  • [ 64479-78-3 ]
  • C22H24F6FeN2O8 [ No CAS ]
  • C20H16F6N2O6(2-)*Fe(2+)*C11H9N3O [ No CAS ]
YieldReaction ConditionsOperation in experiment
50% In ethanol for 2h; Reflux;
  • 50
  • zinc(II) nitrate hexahydrate [ No CAS ]
  • [ 64479-78-3 ]
  • [ 89-05-4 ]
  • C11H9N3O*C10H2O8(4-)*2Zn(2+)*4H2O [ No CAS ]
YieldReaction ConditionsOperation in experiment
60% In ethanol; water; N,N-dimethyl-formamide at 95℃; for 12h; Sealed tube;
Same Skeleton Products
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