[ CAS No. 707-61-9 ]

Name: 707-61-9|4-Methyl-1-phenyl-2,3-dihydro-1H-phosphole 1-oxide|97%
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SKU: A100603
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Quality Control of [ 707-61-9 ]

COA NMR CNMR HPLC LC-MS

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SDS Specification

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Product Details of [ 707-61-9 ]

CAS No. :	707-61-9	MDL No. :	MFCD00014518
Formula :	C₁₁H₁₃OP	Boiling Point :	-
Linear Structure Formula :	-	InChI Key :	YMKWWHFRGALXLE-UHFFFAOYSA-N
M.W :	192.19	Pubchem ID :	69722
Synonyms :

Safety of [ 707-61-9 ]

Signal Word:	Danger	Class:	6.1
Precautionary Statements:	P273-P301+P312+P330	UN#:	2811
Hazard Statements:	H302-H350-H412	Packing Group:	Ⅲ
GHS Pictogram:

Application In Synthesis of [ 707-61-9 ]

* All experimental methods are cited from the reference, please refer to the original source for details. We do not guarantee the accuracy of the content in the reference.

Downstream synthetic route of [ 707-61-9 ]

[ 707-61-9 ] Synthesis Path-Downstream 1~69

1
[ 707-61-9 ]
[ 149443-46-9 ]

Reference： [1]Advanced Synthesis and Catalysis,2016,vol. 358,p. 26 - 29
[2]Chemistry - A European Journal,2016,vol. 22,p. 2458 - 2465
[3]Chemische Berichte,1964,vol. 97,p. 1988 - 1993
[4]Chemical Communications (London),1967,p. 914 - 915
[5]Organic and Biomolecular Chemistry,2017,vol. 15,p. 6426 - 6432
[6]Organometallics,2021,vol. 40,p. 693 - 701

2
[ 707-61-9 ]
[ 34868-22-9 ]

Yield	Reaction Conditions	Operation in experiment
100%	With hydrogen;palladium 10% on activated carbon; In methanol; at 20℃; under 15001.5 Torr;	Synthetic Procedures; Preparation of Compound (1): 3-methyl-l-phenylphospholane-l-oxide,; Rapidly, in air, commercially available 3-methyl-l -phenyl -2-phospholene-l -oxide (3.0 g, 16 mmol, CAS 707-61-9) was weighed into a tared 500 mL round-bottom flask. Methanol (300 mL) was added to prepare a 0.05 M solution. The phospholene oxide was hydrogenated via the H-Cube Midi with a catalyst cartridge containing 10% Pd/C. The reduction occurred at ambient temperature, under 20 bar H2, at 1 mL/min flow rate. Methanol was removed in vacuo to yield the product as a viscous 2: 1 mixture of diastereomers in 100% yield. 1H-NMR and 31P-NMR spectra match previously reported data.

Reference： [1]Angewandte Chemie - International Edition,2009,vol. 48,p. 6836 - 6839
Angewandte Chemie,2009,vol. 121,p. 6968 - 6971
[2]Patent: WO2010/118042,2010,A2 .Location in patent: Page/Page column 9
[3]Chemistry - A European Journal,2013,vol. 19,p. 15281 - 15289
[4]Chemistry - A European Journal,2013,vol. 19,p. 15281 - 15289
[5]Synthetic Communications,2000,vol. 30,p. 4221 - 4231
[6]Journal of the American Chemical Society,1971,vol. 93,p. 6205 - 6216
[7]Journal of the American Chemical Society,2017,vol. 139,p. 6839 - 6842
[8]Journal of the American Chemical Society,2018,vol. 140,p. 15200 - 15205
[9]Angewandte Chemie - International Edition,2020,vol. 59,p. 4505 - 4510
Angew. Chem.,2020,vol. 132,p. 4535 - 4540,6

3
[ 707-61-9 ]
[ 78088-63-8 ]

Reference： [1]Bulletin of the Academy of Sciences of the USSR Division of Chemical Science,1968,p. 1237 - 1242
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya,1968,p. 1313 - 1319

4
[ 707-61-9 ]
[ 42408-51-5 ]

Reference： [1]Phosphorus, Sulfur and Silicon and the Related Elements,2013,vol. 188,p. 213 - 223
[2]Synthesis,1989,p. 595 - 597
[3]Tetrahedron Letters,1973,p. 1249 - 1252

5
[ 707-61-9 ]
[ 34868-22-9 ]
3-Methyl-1-phenyl-4,5-dihydrophosphol [ No CAS ]
[ 149443-46-9 ]
1-phenyl-3-methylphospholan [ No CAS ]

Reference： [1]Journal of Chemical Research, Miniprint,1984,p. 315 - 345

6
[ 707-61-9 ]
[ 91207-34-0 ]

Reference： [1]Journal of Heterocyclic Chemistry,2002,vol. 39,p. 69 - 75
[2]Phosphorus, Sulfur and Silicon and the Related Elements,2002,vol. 177,p. 1801 - 1806
[3]Heterocyclic Communications,2010,vol. 16,p. 173 - 180
[4]Journal of general chemistry of the USSR,1984,vol. 54,p. 467 - 471
Zhurnal Obshchei Khimii,1984,vol. 54,p. 530 - 535

7
[ 824-72-6 ]
[ 78-79-5 ]
[ 707-61-9 ]

Reference： [1]Carbohydrate Research,2001,vol. 336,p. 257 - 270
[2]Synthesis,1989,p. 595 - 597

8
[ 707-61-9 ]
3-Methyl-1-oxo-1-phenyl-1λ⁵-phospholane-2,3-diol [ No CAS ]
3-deoxy-2-C-methyl-1,4-C-(phenylphosphinylidene)-α-L-glycero-tetrafuranose [ No CAS ]

Reference： [1]Journal of the Chemical Society. Chemical communications,1988,p. 569 - 570

9
[ 707-61-9 ]
(1S,2R,3S)-3-Methyl-1-oxo-1-phenyl-1λ⁵-phospholane-2,3-diol [ No CAS ]
cis-2,3-dihydroxy-3-methyl-1-phenylphospholane [ No CAS ]

Reference： [1]Journal of Carbohydrate Chemistry,1997,vol. 16,p. 499 - 519

10
[ 707-61-9 ]
(+/-)-threo 2-bromo-3-hydroxy-3-methyl-1-phenylphospholane 1-oxide [ No CAS ]
(+/-)-erythro 2-bromo-3-hydroxy-3-methyl-1-phenylphospholane 1-oxide [ No CAS ]

Reference： [1]Journal of Carbohydrate Chemistry,1999,vol. 18,p. 915 - 935
[2]Tetrahedron Letters,2004,vol. 45,p. 2851 - 2854

11
[ 107-19-7 ]
[ 707-61-9 ]
3-hydroxy-2-(4-hydroxymethyl-1H-1,2,3-triazol-1-yl)-3-methyl-1-phenylphospholane-1-oxide [ No CAS ]
3-hydroxy-2-(5-hydroxymethyl-1H-1,2,3-triazol-1-yl)-3-methyl-1-phenylphospholane-1-oxide [ No CAS ]

Reference： [1]Carbohydrate Research,2001,vol. 336,p. 257 - 270

12
[ 536-74-3 ]
[ 707-61-9 ]
3-hydroxy-2-(5-phenyl-1H-1,2,3-triazol-1-yl)-3-methyl-1-phenylphospholane-1-oxide [ No CAS ]
3-hydroxy-2-(4-phenyl-1H-1,2,3-triazol-1-yl)-3-methyl-1-phenylphospholane-1-oxide [ No CAS ]

Reference： [1]Carbohydrate Research,2001,vol. 336,p. 257 - 270

13
[ 922-67-8 ]
[ 707-61-9 ]
3-hydroxy-2-(4-methoxycarbonyl-1H-1,2,3-triazol-1-yl)-3-methyl-1-phenylphospholane-1-oxide [ No CAS ]
3-hydroxy-2-(5-methoxycarbonyl-1H-1,2,3-triazol-1-yl)-3-methyl-1-phenylphospholane-1-oxide [ No CAS ]

Reference： [1]Carbohydrate Research,2001,vol. 336,p. 257 - 270

14
[ 762-42-5 ]
[ 707-61-9 ]
3-hydroxy-2-(4,5-dimethoxycarbonyl-1H-1,2,3-triazol-1-yl)-3-methyl-1-phenylphospholane-1-oxide [ No CAS ]

Reference： [1]Carbohydrate Research,2001,vol. 336,p. 257 - 270

15
[ 110-65-6 ]
[ 707-61-9 ]
3-hydroxy-2-(4,5-dihydroxymethyl-1H-1,2,3-triazol-1-yl)-3-methyl-1-phenylphospholane-1-oxide [ No CAS ]

Reference： [1]Carbohydrate Research,2001,vol. 336,p. 257 - 270

16
[ 917-92-0 ]
[ 707-61-9 ]
3-hydroxy-2-(4-t-butyl-1H-1,2,3-triazol-1-yl)-3-methyl-1-phenylphospholane-1-oxide [ No CAS ]
3-hydroxy-2-(5-t-butyl-1H-1,2,3-triazol-1-yl)-3-methyl-1-phenylphospholane-1-oxide [ No CAS ]

Reference： [1]Carbohydrate Research,2001,vol. 336,p. 257 - 270

17
[ 707-61-9 ]
[ 115-19-5 ]
3-hydroxy-2-[4-(1-hydroxy-1-methylethyl)-1H-1,2,3-triazol-1-yl]-3-methyl-1-phenylphospholane-1-oxide [ No CAS ]
3-hydroxy-2-[5-(1-hydroxy-1-methylethyl)-1H-1,2,3-triazol-1-yl]-3-methyl-1-phenylphospholane-1-oxide [ No CAS ]

Reference： [1]Carbohydrate Research,2001,vol. 336,p. 257 - 270

18
[ 707-61-9 ]
[ 762-21-0 ]
3-hydroxy-2-(4,5-diethoxycarbonyl-1H-1,2,3-triazol-1-yl)-3-methyl-1-phenylphospholane-1-oxide [ No CAS ]

Reference： [1]Carbohydrate Research,2001,vol. 336,p. 257 - 270

19
[ 707-61-9 ]
[ 142-45-0 ]
3-hydroxy-2-(4,5-dicarboxyl-1H-1,2,3-triazol-1-yl)-3-methyl-1-phenylphospholane-1-oxide [ No CAS ]

Reference： [1]Carbohydrate Research,2001,vol. 336,p. 257 - 270

20
[ 707-61-9 ]
[ 1066-54-2 ]
(1R,2S,3R)-3-hydroxy-3-methyl-1-phenyl-2-(4'-trimethylsilyl-1'H-1',2',3'-triazo-1'-yl)-phospholane 1-oxide [ No CAS ]

Reference： [1]Carbohydrate Research,2001,vol. 336,p. 257 - 270

21
[ 707-61-9 ]
threo-2-bromo-3-hydroxy-3-methyl-1-phenyl-2-phospholene 1-oxide [ No CAS ]

Reference： [1]Carbohydrate Research,2001,vol. 336,p. 257 - 270

22
phenylmagnesium bromide [ No CAS ]
[ 823-14-3 ]
[ 707-61-9 ]

Reference： [1]Journal of Heterocyclic Chemistry,2002,vol. 39,p. 69 - 75

23
[ 707-61-9 ]
[ 36044-21-0 ]

Reference： [1]Journal of Heterocyclic Chemistry,2002,vol. 39,p. 69 - 75

24
[ 67-56-1 ]
[ 707-61-9 ]
(+/-)-threo-1-phenyl-2-bromo-3-methoxy-3-methylphospholane 1-oxide [ No CAS ]

Reference： [1]Tetrahedron Letters,2004,vol. 45,p. 2851 - 2854

25
[ 67-56-1 ]
[ 707-61-9 ]
(+/-)-threo-1-phenyl-2-bromo-3-methoxy-3-methylphospholane 1-oxide [ No CAS ]
(+/-)-erythro-1-phenyl-2-bromo-3-methoxy-3-methylphospholane 1-oxide [ No CAS ]
(1S,2S,3S)-3-Bromo-2-methoxy-3-methyl-1-phenyl-phospholane 1-oxide [ No CAS ]
(1S,2R,3R)-3-Bromo-2-methoxy-3-methyl-1-phenyl-phospholane 1-oxide [ No CAS ]

Reference： [1]Tetrahedron Letters,2004,vol. 45,p. 1923 - 1927

26
[ 707-61-9 ]
[ 74-88-4 ]
[ 848484-65-1 ]
2,3-dimethyl-1-phenyl-3-phospholene 1-oxide [ No CAS ]

Reference： [1]Tetrahedron,2005,vol. 61,p. 1481 - 1492

27
[ 707-61-9 ]
erythro-1-phenyl-2,3-epoxy-3-methylphospholane 1-oxide [ No CAS ]

Reference： [1]Tetrahedron Letters,2004,vol. 45,p. 2851 - 2854
[2]Journal of Carbohydrate Chemistry,1999,vol. 18,p. 915 - 935

28
[ 707-61-9 ]
[ 660442-19-3 ]

Reference： [1]Tetrahedron Letters,2004,vol. 45,p. 2851 - 2854

29
[ 707-61-9 ]
(1S,2S,5R)-5-Methyl-2-phenyl-6-oxa-2-phospha-bicyclo[3.1.0]hexane 2-oxide [ No CAS ]

Reference： [1]Tetrahedron Letters,2004,vol. 45,p. 2851 - 2854

30
[ 707-61-9 ]
(1R,2S,5S)-5-Methyl-2-phenyl-6-oxa-2-phospha-bicyclo[3.1.0]hexane 2-sulfide [ No CAS ]

Reference： [1]Tetrahedron Letters,2004,vol. 45,p. 2851 - 2854

31
[ 707-61-9 ]
(1S,3S)-3-Methyl-2-methylene-1-phenyl-1-thioxo-1λ⁵-phospholan-3-ol [ No CAS ]

Reference： [1]Tetrahedron Letters,2004,vol. 45,p. 2851 - 2854

32
[ 707-61-9 ]
1-phenyl-3-hydroxy-2-methylene-3-methylphospholane 1-oxide [ No CAS ]

Reference： [1]Tetrahedron Letters,2004,vol. 45,p. 2851 - 2854

33
[ 695-60-3 ]
[ 707-61-9 ]

Reference： [1]Journal of Heterocyclic Chemistry,2002,vol. 39,p. 69 - 75

34
[ 707-61-9 ]
4-methyl-1-(3-nitro-phenyl)-2,3-dihydro-phosphole 1-sulfide [ No CAS ]

Reference： [1]Journal of Heterocyclic Chemistry,2002,vol. 39,p. 69 - 75

35
[ 707-61-9 ]
threo-2-azido-3-hydroxy-3-methyl-1-phenyl-2-phospholene 1-oxide [ No CAS ]

Reference： [1]Carbohydrate Research,2001,vol. 336,p. 257 - 270

36
[ 707-61-9 ]
(+/-)-threo 2-azido-3-hydroxy-3-methyl-1-phenylphospholane 1-oxide [ No CAS ]