[ CAS No. 81090-53-1 ]

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Cat. No.: {[proInfo.prAm]}
2D
Chemical Structure| 81090-53-1
Chemical Structure| 81090-53-1
Structure of 81090-53-1

Quality Control of [ 81090-53-1 ]

Purity: {[proInfo.showProBatch.pb_purity]}

Related Doc. of [ 81090-53-1 ]

SDS

Product Details of [ 81090-53-1 ]

CAS No. :81090-53-1MDL No. :MFCD00060104
Formula :C18H13Br2NBoiling Point :-
Linear Structure Formula :-InChI Key :-
M.W :403.11Pubchem ID :13594707
Synonyms :

Computed Properties of [ 81090-53-1 ]

TPSA : 3.2 H-Bond Acceptor Count : 1
XLogP3 : - H-Bond Donor Count : 0
SP3 : 0.00 Rotatable Bond Count : 3

Safety of [ 81090-53-1 ]

Signal Word:WarningClassN/A
Precautionary Statements:P261-P280-P305+P351+P338UN#:N/A
Hazard Statements:H302-H315-H317-H319-H335Packing Group:N/A
GHS Pictogram:

Application In Synthesis of [ 81090-53-1 ]

  • Upstream synthesis route of [ 81090-53-1 ]

[ 81090-53-1 ] Synthesis Path-Upstream   1~9

  • 1
  • [ 603-34-9 ]
  • [ 81090-53-1 ]
YieldReaction ConditionsOperation in experiment
99% With N-Bromosuccinimide In ethyl acetate at 20℃; for 24.00 h; Step 1: Synthesis of 4,4'-dibromotriphenylamine] [0479]A synthetic scheme of 4,4'-dibromotriphenylamine in Step 1 is shown in the following (K-I). [0480][0481]After 12 g (50 mmol) of triphenylamine was dissolved in a mixture solvent of 250 mL of ethyl acetate in a 500-mL conical flask, 18 g (100 mmol) of λT-bromo succinimide (abbreviation: NBS) was added to this solution. After that, this mixture was stirred at room temperature for 24 hours. After completion of the reaction, this mixture solution was washed with water, and magnesium sulfate was added thereto to remove moisture. This mixture solution was filtrated and the obtained filtrate was concentrated and dried to obtain 20 g of an objective white solid at a yield of 99 percent
99% With N-Bromosuccinimide In ethyl acetate at 20℃; for 24.00 h; After 12 g (50 mmol) of triphenylamine was dissolved in 250 mL of ethyl acetate in a 500-mL conical flask, 18 g (100 mmol) of iV-Bromosuccinimide (abbreviation: NBS) was added to this solution. After that, this mixture was stirred at room temperature for 24 hours to be reacted. After completion of the reaction, this mixture solution was washed with water, and magnesium sulfate was added thereto to remove moisture. This mixture solution was filtrated, and the obtained filtrate was concentrated and dried to obtain 20 g of an objective white solid at a yield of 99 percent. A synthesis scheme of Step 1 is shown in (b-4) given below.
Reference: [1] Patent: WO2009/72587, 2009, A1. Location in patent: Page/Page column 191
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[15] Journal of the American Chemical Society, 2017, vol. 139, # 32, p. 11073 - 11080
  • 2
  • [ 589-87-7 ]
  • [ 62-53-3 ]
  • [ 81090-53-1 ]
Reference: [1] RSC Advances, 2015, vol. 5, # 37, p. 28879 - 28884
[2] RSC Advances, 2014, vol. 4, # 32, p. 16385 - 16390
[3] New Journal of Chemistry, 2018, vol. 42, # 22, p. 18448 - 18457
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  • 3
  • [ 66-71-7 ]
  • [ 591-50-4 ]
  • [ 16292-17-4 ]
  • [ 81090-53-1 ]
Reference: [1] Patent: US2006/83945, 2006, A1
  • 4
  • [ 16292-17-4 ]
  • [ 104-15-4 ]
  • [ 637-88-7 ]
  • [ 81090-53-1 ]
Reference: [1] Patent: US6300502, 2001, B1
  • 5
  • [ 16292-17-4 ]
  • [ 637-88-7 ]
  • [ 81090-53-1 ]
Reference: [1] Bulletin of the Chemical Society of Japan, 1986, vol. 59, # 3, p. 803 - 808
[2] RSC Advances, 2014, vol. 4, # 65, p. 34332 - 34342
  • 6
  • [ 591-50-4 ]
  • [ 16292-17-4 ]
  • [ 81090-53-1 ]
Reference: [1] Journal of Materials Chemistry B, 2017, vol. 5, # 43, p. 8525 - 8531
  • 7
  • [ 4051-56-3 ]
  • [ 81090-53-1 ]
Reference: [1] Bulletin of the Chemical Society of Japan, 1986, vol. 59, # 3, p. 803 - 808
  • 8
  • [ 99234-92-1 ]
  • [ 81090-53-1 ]
Reference: [1] Bulletin of the Chemical Society of Japan, 1986, vol. 59, # 3, p. 803 - 808
  • 9
  • [ 603-35-0 ]
  • [ 81090-53-1 ]
Reference: [1] New Journal of Chemistry, 2016, vol. 40, # 12, p. 10246 - 10258
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